Self-assembled decanuclear NaI2MnII4MnIII4 complexes: from discrete clusters to 1-D and 2-D structures, with the MnII4MnIII4 unit displaying a large spin ground state and probable SMM behaviour

2011 ◽  
Vol 40 (45) ◽  
pp. 12201 ◽  
Author(s):  
Stuart K. Langley ◽  
Nicholas F. Chilton ◽  
Boujemaa Moubaraki ◽  
Keith S. Murray
Keyword(s):  
Ground State ◽  
Self Assembled ◽  
Large Spin ◽  
Spin Ground State

Strong Ferromagnetic Interactions in[V8O14(H−2taci)2]: An Unprecedented Large Spin Ground State for a Vanadyl Cluster

2004 ◽  
Vol 43 (26) ◽  
pp. 3436-3439 ◽  
Author(s):  
Kaspar Hegetschweiler ◽  
Bernd Morgenstern ◽  
Jon Zubieta ◽  
Pamela J. Hagrman ◽  
Nicola Lima ◽  
...  
Keyword(s):  
Ground State ◽  
Ferromagnetic Interactions ◽  
Large Spin ◽  
Spin Ground State

Molecular nanoclusters as magnetic refrigerants: The case of Fe14 with very large spin ground-state

Polyhedron ◽  
2005 ◽  
Vol 24 (16-17) ◽  
pp. 2573-2578 ◽  
Author(s):  
Marco Evangelisti ◽  
Andrea Candini ◽  
Alberto Ghirri ◽  
Marco Affronte ◽  
Stergios Piligkos ◽  
...  
Keyword(s):  
Ground State ◽  
Large Spin ◽  
Spin Ground State

Manganese clusters derived from 2-pyridylcyanoxime: new topologies and a large spin ground state in pyridyloximate chemistry

2013 ◽  
Vol 42 (34) ◽  
pp. 12334 ◽  
Author(s):  
Laura Alcazar ◽  
Beatriz Cordero ◽  
Jordi Esteban ◽  
Vassilis Tangoulis ◽  
Mercè Font-Bardia ◽  
...  
Keyword(s):  
Ground State ◽  
Manganese Clusters ◽  
Large Spin ◽  
Spin Ground State

Strong Ferromagnetic Interactions in[V8O14(H−2taci)2]: An Unprecedented Large Spin Ground State for a Vanadyl Cluster

2004 ◽  
Vol 116 (26) ◽  
pp. 3518-3521 ◽  
Author(s):  
Kaspar Hegetschweiler ◽  
Bernd Morgenstern ◽  
Jon Zubieta ◽  
Pamela J. Hagrman ◽  
Nicola Lima ◽  
...  
Keyword(s):  
Ground State ◽  
Ferromagnetic Interactions ◽  
Large Spin ◽  
Spin Ground State

DFT Computational Rationalization of an Unusual Spin Ground State in an Mn12 Single-Molecule Magnet with a Low-Symmetry Loop Structure

2005 ◽  
Vol 117 (6) ◽  
pp. 919-923 ◽  
Author(s):  
Dolos Foguet-Albiol ◽  
Ted A. O'Brien ◽  
Wolfgang Wernsdorfer ◽  
Brian Moulton ◽  
Michael J. Zaworotko ◽  
...  
Keyword(s):  
Single Molecule ◽  
Ground State ◽  
Loop Structure ◽  
Single Molecule Magnet ◽  
Low Symmetry ◽  
Spin Ground State

Targeted construction of azido-bridged Ni4complexes with decisive effect of µ-1,3-azide torsion on the spin ground state

2006 ◽  
pp. 3458-3465 ◽  
Author(s):  
Serhiy Demeshko ◽  
Guido Leibeling ◽  
Sebastian Dechert ◽  
Franc Meyer
Keyword(s):  
Ground State ◽  
Decisive Effect ◽  
Spin Ground State

Possibility for an intermediate-spin ground state in the charge-transfer materialSrCoO3

1995 ◽  
Vol 51 (17) ◽  
pp. 11501-11506 ◽  
Author(s):  
R. H. Potze ◽  
G. A. Sawatzky ◽  
M. Abbate
Keyword(s):  
Charge Transfer ◽  
Ground State ◽  
Intermediate Spin ◽  
Spin Ground State

Giant Heterometallic Cu17Mn28Cluster withTdSymmetry and High-Spin Ground State

2007 ◽  
Vol 129 (5) ◽  
pp. 1014-1015 ◽  
Author(s):  
Wen-Guo Wang ◽  
Ai-Ju Zhou ◽  
Wei-Xiong Zhang ◽  
Ming-Liang Tong ◽  
Xiao-Ming Chen ◽  
...  
Keyword(s):  
High Spin ◽  
Ground State ◽  
Spin Ground State

scholarly journals Controlled Synthesis, Characterization and Magnetic Properties of Unsymmetrical Heterodinuclear CuIIMII (M = Co, Mn and Cd) Complexes in Alkoxo Bridged Acyclic Ligand Environment

2020 ◽  
Vol 32 (9) ◽  
pp. 2284-2292
Author(s):  
DIPESH GHOSH
Keyword(s):  
Ground State ◽  
Spectral Studies ◽  
Controlled Synthesis ◽  
Site Specificity ◽  
Magnetic Studies ◽  
X Ray ◽  
X Ray Crystallography ◽  
Synthetic Procedure ◽  
Binucleating Ligands ◽  
Spin Ground State

This work reports the syntheses of heterodinuclear Cu(II)-Co(II), Cu(II)-Mn(II) and Cu(II)-Cd(II) complexes following a convenient single-pot synthetic procedure using the two asymmetric binucleating ligands. Site-specificity offered by one of the ligands' arms towards Cu(I) center has been successfully exploited here, avoiding all sorts of impending scrambling reactions. X-ray crystallography and ESImass spectral studies have been used to prove the exclusivity of these products. Magnetic studies at variable temperatures (4-300 K) have been proved inadequate to assign any spin-ground state for Cu(II)-Co(II) and Cu(II)-Mn(II) compounds.

Sign in / Sign up

Export Citation Format

Share Document