X-ray photoelectron spectroscopy of pyrrolidinium-based ionic liquids: cation–anion interactions and a comparison to imidazolium-based analogues

2011 ◽  
Vol 13 (33) ◽  
pp. 15244 ◽  
Author(s):  
Shuang Men ◽  
Kevin R. J. Lovelock ◽  
Peter Licence
Keyword(s):  
Ionic Liquids ◽  
Photoelectron Spectroscopy ◽  
X Ray

scholarly journals Influence of Ionic Liquids Assisted Synthesis on Morphology and Photocatalytic Properties of Bi4O5Br2

Proceedings ◽  
2019 ◽  
Vol 16 (1) ◽  
pp. 26
Author(s):  
Patrycja Wilczewska ◽  
Aleksandra Bielicka-Giełdoń ◽  
Agnieszka Fiszka Borzyszkowska ◽  
Aleksandra Pieczyńska ◽  
Ewa Maria Siedlecka
Keyword(s):  
Ionic Liquids ◽  
Photoelectron Spectroscopy ◽  
Photocatalytic Properties ◽  
X Ray Diffraction ◽  
Sem Images ◽  
New Thought ◽  
X Ray ◽  
Chromium Vi ◽  
Ft Ir ◽  
Adsorption Desorption

A series of Bi4O5Br2 photocatalysts were prepared via an innovation method of synthesis with ionic liquids (ILs). The crystal structures were investigated by X-ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FT-IR). The Field Emission Scanning Electron Microscope (FE-SEM) images illustrated the unique structure of prepared photocatalysts. The photocatalysts were also characterized by N2 adsorption-desorption analysis, X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectra (UV-vis/DRS) and photoluminescence spectra (PL). The role of ILs in synthesis of Bi4O5Br2 on morphology and photocatalytic properties were investigated. Rhodamine B, 5-fluorouracil and chromium (VI) were used as the model micropollutants to evaluated adsorption capacity, photooxidation and photoreduction ability of prepared Bi4O5Br2 under artificial solar light. This work provided a new thought for enhanced photocatalytic activity of bismuth oxybromide photocatalysts.

Investigation of Tribological Behavior of Al–Si Alloy Against Steel Lubricated With Ionic Liquids of 1-Diethylphosphonyl-n-propyl-3- Alkylimidazolium Tetrafluoroborate

2008 ◽  
Vol 130 (3) ◽  
Author(s):  
Zonggang Mu ◽  
Xiaoxuan Wang ◽  
Shuxiang Zhang ◽  
Yongmin Liang ◽  
Meng Bao ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Photoelectron Spectroscopy ◽  
Friction And Wear ◽  
Room Temperature ◽  
Test Results ◽  
Tribological Test ◽  
X Ray ◽  
Imidazolium Cations ◽  
Metal Fluorides ◽  
Worn Surface

A series of room temperature ionic liquids bearing with phosphonyl groups on the imidazolium cations, namely, 1-(3′-O,O-diethylphosphonyl-n-propyl)-3-alkylimidazolium tetrafluoroborate, were prepared and their physical properties were determined. They were also evaluated as promising lubricants for the contacts of aluminum on steel by using a SRV test rig. The tribological test results show that the synthetic ionic liquids exhibit better friction-reducing and antiwear abilities than the unsubstituted ionic liquid of 1-ethyl-3-hexylimidazolium tetrafluoroborate (coded as L206) and phosphazene (X-1P). Both the anions and the side substitutes attached to the imidazolium cations affect the tribological performance of lubricants. The scanning electron microscopy, energy-dispersive x-ray analysis, and x-ray photoelectron spectroscopy analyses of the worn surfaces show that complicated tribochemical reactions are involved in the sliding process. The anion decomposition and chemical adsorption of cation took place on the worn surface of aluminum alloy during the sliding process. As a result of the generation of boundary lubrication films which are composed of metal fluorides, B2O3, BN, nitrogen oxide, and FePO4 help to effectively reduce the friction and wear of the contacts.

Ionic liquids in vacuo; solution-phase X-ray photoelectron spectroscopy

2005 ◽  
pp. 5633 ◽  
Author(s):  
Emily F. Smith ◽  
Ignacio J. Villar Garcia ◽  
David Briggs ◽  
Peter Licence
Keyword(s):  
Ionic Liquids ◽  
Photoelectron Spectroscopy ◽  
Solution Phase ◽  
X Ray

Cyclic Thiouronium Ionic Liquids: Physicochemical Properties and their Electronic Structure Probed by X-Ray Induced Photoelectron Spectroscopy

2012 ◽  
Vol 18 (27) ◽  
pp. 8288-8291 ◽  
Author(s):  
Nicola Taccardi ◽  
Inga Niedermaier ◽  
Florian Maier ◽  
Hans-Peter Steinrück ◽  
Peter Wasserscheid
Keyword(s):  
Electronic Structure ◽  
Ionic Liquids ◽  
Physicochemical Properties ◽  
Photoelectron Spectroscopy ◽  
X Ray
Sign in / Sign up

Export Citation Format

Share Document