Metal flux through consuming interfaces in ligand mixtures: boundary conditions do not influence the lability and relative contributions of metal species

Zeshi Zhang; Davide Alemani; Jacques Buffle; Raewyn M. Town; Kevin J. Wilkinson

doi:10.1039/c1cp20705a

Metal flux through consuming interfaces in ligand mixtures: boundary conditions do not influence the lability and relative contributions of metal species

Physical Chemistry Chemical Physics ◽

10.1039/c1cp20705a ◽

2011 ◽

Vol 13 (39) ◽

pp. 17606 ◽

Cited By ~ 6

Author(s):

Zeshi Zhang ◽

Davide Alemani ◽

Jacques Buffle ◽

Raewyn M. Town ◽

Kevin J. Wilkinson

Keyword(s):

Boundary Conditions ◽

Metal Species ◽

Metal Flux

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Effect of oxygen-to-metal flux ratio on incorporation of metal species into quaternary BeMgZnO grown by plasma-assisted molecular beam epitaxy

Journal of Crystal Growth ◽

10.1016/j.jcrysgro.2017.03.028 ◽

2017 ◽

Vol 467 ◽

pp. 145-149 ◽

Cited By ~ 8

Author(s):

M. Toporkov ◽

M.B. Ullah ◽

D.O. Demchenko ◽

V. Avrutin ◽

H. Morkoç ◽

...

Keyword(s):

Molecular Beam Epitaxy ◽

Molecular Beam ◽

Flux Ratio ◽

Metal Species ◽

Metal Flux ◽

Effect Of Oxygen

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Production and STEM examination of controlled-size silver clusters

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100075488 ◽

1983 ◽

Vol 41 ◽

pp. 338-339

Author(s):

M. A. Listvan ◽

R. P. Andres

Keyword(s):

Cluster Size ◽

Metal Clusters ◽

Experimental Parameter ◽

Carbon Films ◽

Metal Species ◽

Silver Clusters ◽

Free Jet ◽

Size Dependent ◽

Cluster Properties ◽

Controllable Size

Knowledge of the function and structure of small metal clusters is one goal of research in catalysis. One important experimental parameter is cluster size. Ideally, one would like to produce metal clusters of regulated size in order to characterize size-dependent cluster properties.A source has been developed which is capable of producing microscopic metal clusters of controllable size (in the range 5-500 atoms) This source, the Multiple Expansion Cluster Source, with a Free Jet Deceleration Filter (MECS/FJDF) operates as follows. The bulk metal is heated in an oven to give controlled concentrations of monomer and dimer which were expanded sonically. These metal species were quenched and condensed in He and filtered to produce areosol particles of a controlled size as verified by mass spectrometer measurements. The clusters were caught on pre-mounted, clean carbon films. The grids were then transferred in air for microscopic examination. MECS/FJDF was used to produce two different sizes of silver clusters for this study: nominally Ag6 and Ag50.

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Use of the Magnetostatic Analogue In Electromagnetic Lens Engineering

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100068795 ◽

1970 ◽

Vol 28 ◽

pp. 360-361

Author(s):

John W. Coleman

Keyword(s):

Boundary Conditions ◽

High Performance ◽

Force Fields ◽

Optical Design ◽

Direct Conversion ◽

Design Engineering ◽

Design Data ◽

Scalar Potentials ◽

Geometric Elements ◽

At Will

In the design engineering of high performance electromagnetic lenses, the direct conversion of electron optical design data into drawings for reliable hardware is oftentimes difficult, especially in terms of how to mount parts to each other, how to tolerance dimensions, and how to specify finishes. An answer to this is in the use of magnetostatic analytics, corresponding to boundary conditions for the optical design. With such models, the magnetostatic force on a test pole along the axis may be examined, and in this way one may obtain priority listings for holding dimensions, relieving stresses, etc..The development of magnetostatic models most easily proceeds from the derivation of scalar potentials of separate geometric elements. These potentials can then be conbined at will because of the superposition characteristic of conservative force fields.

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