scholarly journals Synthetic and crystallographic studies of bicyclo[3.3.1]nonane derivatives: from strong to weak hydrogen bonds and the stereochemistry of network formation

CrystEngComm ◽  
2012 ◽  
Vol 14 (1) ◽  
pp. 178-187 ◽  
Author(s):  
Carl-Johan Wallentin ◽  
Edvinas Orentas ◽  
Magnus T. Johnson ◽  
Nikoletta B. Báthori ◽  
Eugenijus Butkus ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Network Formation ◽  
Weak Hydrogen Bonds

Raman spectroscopy of weak hydrogen bonds in the liquid phase

1978 ◽  
Vol 47 ◽  
pp. 285-290 ◽  
Author(s):  
J.P. Perchard ◽  
C. Perchard ◽  
A. Burneau ◽  
J. Limouzi
Keyword(s):  
Raman Spectroscopy ◽  
Liquid Phase ◽  
Hydrogen Bonds ◽  
Weak Hydrogen Bonds

scholarly journals Weak Hydrogen Bonds in Some Six- and Five-atom Interactions: An AIM Topological Analysis

2013 ◽  
Vol 2 (6) ◽  
pp. 343-346 ◽  
Author(s):  
Francisco Sánchez-Viesca ◽  
Fernando Cortés ◽  
Reina Gómez ◽  
Martha Berros
Keyword(s):  
Hydrogen Bonds ◽  
Topological Analysis ◽  
Weak Hydrogen Bonds

scholarly journals catena-Poly[[[bis(acetonitrile-κN)(4,4′-dimethoxy-2,2′-bipyridine-κ2 N,N′)copper(II)]-μ-trifluoromethanesulfonato-κ2 O:O′] trifluoromethanesulfonate]

IUCrData ◽  
2020 ◽  
Vol 5 (10) ◽  
Author(s):  
Rafael A. Adrian ◽  
Diego R. Hernandez ◽  
Hadi D. Arman
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Metal Organic Frameworks ◽  
Starting Material ◽  
Compound A ◽  
Distorted Octahedral ◽  
Weak Hydrogen Bonds ◽  
Polymeric Chains ◽  
Metal Organic ◽  
Bipyridine Ligand

The central copper(II) atom of the title salt, {[Cu(CF3SO3)(CH3CN)2(C12H12N2O2)](CF3SO3)} n or [[Cu(CH3CN)2(diOMe-bpy)(CF3SO3)](CF3SO3)] n where diOMe-bpy is 4,4′-dimethoxy-2,2′-bipyridine, C12H12N2O2, is sixfold coordinated by the N atoms of the chelating bipyridine ligand, the N atoms of two acetonitrile molecules, and two trifluoromethanesulfonate O atoms in a tetragonally distorted octahedral shape. The formation of polymeric chains [Cu(CH3CN)2(diOMe-bpy)(CF3SO3)]+ n leaves voids for the non-coordinating trifluoromethanesulfonate anions that interact with the complex through weak hydrogen bonds. The presence of weakly coordinating ligands like acetonitrile and trifluoromethanesulfonate makes the title compound a convenient starting material for the synthesis of novel metal–organic frameworks.

scholarly journals Amide to amide interactions: from strong to weak hydrogen bonds in bis(quinoxaline-carboxamide) functionality

2011 ◽  
Vol 67 (a1) ◽  
pp. C388-C389
Author(s):  
C. A. Jiménez ◽  
N. Parra ◽  
P. I. Hidalgo ◽  
J. Belmar ◽  
J. Pasán ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Weak Hydrogen Bonds

Chlorido(dimethyl 2,2′-bipyridine-4,4′-dicarboxylate-κ2N,N′)(η5-pentamethylcyclopentadienyl)rhodium(III) chloride 1-hydroxypyrrolidine-2,5-dione disolvate

2013 ◽  
Vol 69 (6) ◽  
pp. 584-587
Author(s):  
Dharmalingam Sivanesan ◽  
Hyung Min Kim ◽  
Yoon Sungho
Keyword(s):  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Substitution Reaction ◽  
Three Dimensional ◽  
Title Complex ◽  
Rhodium Complex ◽  
Synthetic Route ◽  
Dimensional Network ◽  
Weak Hydrogen Bonds ◽  
Solvent Molecules

The title complex, [Rh(C10H15)Cl(C14H12N2O4)]Cl·2C4H5NO3, has been synthesized by a substitution reaction of the precursor [bis(2,5-dioxopyrrolidin-1-yl) 2,2′-bipyridine-4,4′-dicarboxylate]chlorido(pentamethylcyclopentadienyl)rhodium(III) chloride with NaOCH3. The RhIIIcation is located in an RhC5N2Cl eight-coordinated environment. In the crystal, 1-hydroxypyrrolidine-2,5-dione (NHS) solvent molecules form strong hydrogen bonds with the Cl−counter-anions in the lattice and weak hydrogen bonds with the pentamethylcyclopentadienyl (Cp*) ligands. Hydrogen bonding between the Cp* ligands, the NHS solvent molecules and the Cl−counter-anions form links in a V-shaped chain of RhIIIcomplex cations along thecaxis. Weak hydrogen bonds between the dimethyl 2,2′-bipyridine-4,4′-dicarboxylate ligands and the Cl−counter-anions connect the components into a supramolecular three-dimensional network. The synthetic route to the dimethyl 2,2′-bipyridine-4,4′-dicarboxylate-containing rhodium complex from the [bis(2,5-dioxopyrrolidin-1-yl) 2,2′-bipyridine-4,4′-dicarboxylate]rhodium(III) precursor may be applied to link Rh catalysts to the surface of electrodes.

Secondary Interactions in Gold(I) Complexes with Thione Ligands, 3. Three Ionic Dimesylamides [1, 2]

2004 ◽  
Vol 59 (11-12) ◽  
pp. 1429-1437 ◽  
Author(s):  
Friedrichsa Friedrichsa ◽  
Peter G. Jones
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Layer Structure ◽  
Chain Structure ◽  
Hydrogen Bond Donor ◽  
Weak Hydrogen Bonds ◽  
Ribbon Structure ◽  
A Chain ◽  
Aurophilic Interactions ◽  
Short Contacts

Three structures of the form bis(thione)gold(I) di(methanesulfonyl)amide [thione = imidazolidine- 2-thione, 1; 1-methyl-imidazolidine-2-thione, 2; thiazolidine-2-thione, 3] were determined; all crystallize with one formula unit in the asymmetric unit. Each N-H hydrogen bond donor forms one classical two-centre hydrogen bond with an anion acceptor. Compound 1 thereby forms a complex layer structure with a layer thickness of 10.17 Å ; the packing may be analysed in terms of thinner subunit layers consisting of interlinked, hydrogen-bonded chains and rings. Compound 2 forms a chain structure consisting of a series of “hairpin bends”, a common feature in the gold complexes of 1-alkyl-imidazolidine-2-thiones. Compound 3 forms a corrugated ribbon structure in which the central region consists of parallel S-Au-S axes linked by aurophilic interactions; the anions exercise a “clamping” function by forming hydrogen bonds at the periphery of the ribbons. Further short contacts can be classed as weak hydrogen bonds C-H ··· X, with X = N, O, S or Au.

scholarly journals Aggregation of coronene: the effect of carboxyl and amine functional groups

2021 ◽  
Author(s):  
C. F. O. Correia ◽  
J. M. C. Marques ◽  
M. Bartolomei ◽  
F. Pirani ◽  
E. Maçôas ◽  
...  
Keyword(s):  
Global Optimization ◽  
Hydrogen Bonds ◽  
Functional Groups ◽  
Weak Hydrogen Bonds ◽  
Amine Groups

Global optimization reveals that aggregation is enhanced for coronene substituted with carboxylic and amine groups, which is due to the influence of weak hydrogen bonds and stronger electrostatic contributions.

Sign in / Sign up

Export Citation Format

Share Document