Inorganic anion induced supramolecular architectures and luminescent properties of flexible bis(pyridyl) based ionic salts

CrystEngComm ◽  
2011 ◽  
Vol 13 (22) ◽  
pp. 6632 ◽  
Author(s):  
Zhao-Peng Deng ◽  
Hui-Ling Qi ◽  
Li-Hua Huo ◽  
Hui Zhao ◽  
Shan Gao
2012 ◽  
Vol 66 (1) ◽  
Author(s):  
Jin-Ting Tan ◽  
Wen-Jie Zhao ◽  
San-Ping Chen ◽  
Xia Li ◽  
Ying-Li Lu ◽  
...  

AbstractTwo complexes, {[Cd6(o-dppd)2(µ2-Cl)6(µ3-Cl)2(DMF)2(H2O)2Cl2]·DMF·CH3OH}n (I) (DMF = N,N-dimethylformamide; o-dppdH = 1,3-di(pyridin-2-yl)propane-1,3-dione) and [Cu4(o-dppd)2(OAc)4(OH)2]·4H2O (II), were synthesised and characterised by single-crystal X-ray diffraction, elemental analysis, IR, solid fluorescence and TGA. The results showed that complex I had a rodshaped polynuclear chain with hexacoordinating Cd atoms bridged by oxygen, µ2-Cl and µ3-Cl; complex II was a tetranuclear oligomer. In general, supramolecular architectures are constructed through hydrogen-bonding and π-π stacking interactions. I shows luminescence.


2014 ◽  
Vol 9 (1) ◽  
pp. 60-63 ◽  
Author(s):  
Lin Xing ◽  
Lianghui Qu ◽  
Qing He ◽  
Tong B. Tang ◽  
Linfeng Yang

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