Crystal engineering with 1,3,5-triaza-7-phosphaadamantane (PTA): first PTA-driven 3D metal–organic frameworks

CrystEngComm ◽  
2011 ◽  
Vol 13 (21) ◽  
pp. 6329 ◽  
Author(s):  
Alexander M. Kirillov ◽  
Sabina W. Wieczorek ◽  
M. Fátima C. Guedes da Silva ◽  
Jerzy Sokolnicki ◽  
Piotr Smoleński ◽  
...  
Keyword(s):  
Crystal Engineering ◽  
Metal Organic Frameworks ◽  
Metal Organic

Classification and role of modulators on crystal engineering of metal organic frameworks (MOFs)

2021 ◽  
Vol 444 ◽  
pp. 214064
Author(s):  
Danni Jiang ◽  
Chao Huang ◽  
Jian Zhu ◽  
Ping Wang ◽  
Zhiming Liu ◽  
...  
Keyword(s):  
Crystal Engineering ◽  
Metal Organic Frameworks ◽  
Metal Organic

Multi-scale crystal engineering of metal organic frameworks

2016 ◽  
Vol 307 ◽  
pp. 147-187 ◽  
Author(s):  
Beatriz Seoane ◽  
Sonia Castellanos ◽  
Alla Dikhtiarenko ◽  
Freek Kapteijn ◽  
Jorge Gascon
Keyword(s):  
Crystal Engineering ◽  
Metal Organic Frameworks ◽  
Multi Scale ◽  
Metal Organic

ChemInform Abstract: Multi-Scale Crystal Engineering of Metal Organic Frameworks

ChemInform ◽  
2016 ◽  
Vol 47 (8) ◽  
pp. no-no
Author(s):  
Beatriz Seoane ◽  
Sonia Castellanos ◽  
Alla Dikhtiarenko ◽  
Freek Kapteijn ◽  
Jorge Gascon
Keyword(s):  
Crystal Engineering ◽  
Metal Organic Frameworks ◽  
Multi Scale ◽  
Metal Organic

scholarly journals Crystal engineering, structure–function relationships, and the future of metal–organic frameworks

CrystEngComm ◽  
2015 ◽  
Vol 17 (2) ◽  
pp. 229-246 ◽  
Author(s):  
Mark D. Allendorf ◽  
Vitalie Stavila
Keyword(s):  
Structure Function ◽  
Crystal Engineering ◽  
Metal Organic Frameworks ◽  
Engineering Structure ◽  
The Future ◽  
Metal Organic

After twenty years of vigorous R&D, where are MOFs headed?

Crystal Engineering Using a “Turtlebug” Algorithm: Ade NovoApproach to the Design of Binodal Metal–Organic Frameworks

2011 ◽  
Vol 11 (9) ◽  
pp. 3686-3693 ◽  
Author(s):  
G. L. McColm ◽  
W. E. Clark ◽  
M. Eddaoudi ◽  
L. Wojtas ◽  
M. Zaworotko
Keyword(s):  
Crystal Engineering ◽  
Metal Organic Frameworks ◽  
Metal Organic

Crystal engineering on superpolyhedral building blocks in metal–organic frameworks applied in gas adsorption

2015 ◽  
Vol 71 (6) ◽  
pp. 613-618 ◽  
Author(s):  
Ying-Pin Chen ◽  
Tian-Fu Liu ◽  
Stephen Fordham ◽  
Hong-Cai Zhou
Keyword(s):  
Surface Area ◽  
Crystal Engineering ◽  
Gas Adsorption ◽  
Metal Organic Frameworks ◽  
Supercritical Drying ◽  
Building Blocks ◽  
Structural Features ◽  
Open Channels ◽  
Bet Surface Area ◽  
Metal Organic

Two metal–organic frameworks [PCN-426(Ni) and PCN-427(Cu)] have been designed and synthesized to investigate the structure predictability using a SBB (supermolecular building blocks) approach. Tetratopic ligands featuring 120° angular carboxylate moieties were coordinated with a [Ni3(μ3-O)] cluster and a [Cu2O2] unit, respectively. As topologically predicted, 4-connected networks with square coordination adopted the nbo net for the Ni-MOF and ssb net for the Cu-MOF. PCN-426(Ni) was augmented with 12-connected octahedral SBBs, while PCN-427(Cu) was constructed with tetragonal open channels. After a CO2 supercritical drying procedure, the PCN-426(Ni) possessed a Brunauer–Emmett–Teller (BET) surface area as high as 3935 m2 g−1 and impressively high N2 uptake of 1500 cm3 g−1. This work demonstrates the generalization of the SBB strategy, finding an alternative to inconvenient synthetic processes to achieve the desired structural features.

Noble metal-free integrated UiO-66-PANI-Co3O4 catalyst for visible-light-induced H2 production

2019 ◽  
Vol 55 (96) ◽  
pp. 14494-14497 ◽  
Author(s):  
Ajay K. Singh ◽  
Spandana Gonuguntla ◽  
Bhushan Mahajan ◽  
Ujjwal Pal
Keyword(s):  
Charge Carrier ◽  
Visible Light ◽  
Noble Metal ◽  
Crystal Engineering ◽  
Metal Organic Frameworks ◽  
H2 Production ◽  
Electron Hole ◽  
Metal Free ◽  
Metal Organic

The discriminate etching chemistry (crystal engineering) of metal–organic frameworks (MOFs) offers promising opportunities for tailoring electron–hole separation, and charge-carrier utilization plays a central role in photocatalysis.

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