A highly efficient kinetic resolution of Morita–Baylis–Hillman adducts achieved by N–Ar axially chiral Pd-complexes catalyzed asymmetric allylation

2011 ◽  
Vol 47 (48) ◽  
pp. 12813 ◽  
Author(s):  
Feijun Wang ◽  
Shengke Li ◽  
Mingliang Qu ◽  
Mei-Xin Zhao ◽  
Lian-Jun Liu ◽  
...  
Keyword(s):  
Kinetic Resolution ◽  
Asymmetric Allylation ◽  
Highly Efficient ◽  
Axially Chiral ◽  
Pd Complexes

First Stereoselective Total Synthesis of (3S,7R)-De-O-methylbotryosphaeriodiplodin

2019 ◽  
Vol 14 (1) ◽  
pp. 1934578X1901400
Author(s):  
Jhillu S. Yadav ◽  
Chitteti Divya Vani ◽  
Mule Chowdeswari ◽  
K. Ananthalakshmi ◽  
N. Bhasker ◽  
...  
Keyword(s):  
Total Synthesis ◽  
Macrocyclic Lactone ◽  
Kinetic Resolution ◽  
Asymmetric Allylation ◽  
Stille Coupling ◽  
Ring Closing Metathesis ◽  
Highly Efficient ◽  
Key Steps

A simple and highly efficient first stereoselective total synthesis of a benzofused macrocyclic lactone, ( 3S,7R)-de- O-methylbotryosphaeriodiplodin has been accomplished utilizing Jacobson's kinetic resolution, Marouka asymmetric allylation, Stille coupling, and ring-closing metathesis (RCM) reactions as key steps.

Atroposelective Transfer Hydrogenation of Biaryl Aminals via Dynamic Kinetic Resolution. Synthesis of Axially Chiral Diamines

ACS Catalysis ◽  
2021 ◽  
pp. 4117-4124
Author(s):  
José A. Carmona ◽  
Carlos Rodríguez-Franco ◽  
Joaquín López-Serrano ◽  
Abel Ros ◽  
Javier Iglesias-Sigüenza ◽  
...  
Keyword(s):  
Kinetic Resolution ◽  
Transfer Hydrogenation ◽  
Dynamic Kinetic Resolution ◽  
Axially Chiral ◽  
Chiral Diamines
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