An unsymmetrical coordination environment leading to two slow relaxation modes in a Dy2 single-molecule magnet

2011 ◽  
Vol 47 (39) ◽  
pp. 10993 ◽  
Author(s):  
Po-Heng Lin ◽  
Wen-Bin Sun ◽  
Mang-Fei Yu ◽  
Guang-Ming Li ◽  
Peng-Fei Yan ◽  
...  
Keyword(s):  
Single Molecule ◽  
Slow Relaxation ◽  
Coordination Environment ◽  
Single Molecule Magnet ◽  
Relaxation Modes

scholarly journals Field-Induced Slow Relaxation in a Monometallic Manganese(III) Single-Molecule Magnet

2014 ◽  
Vol 54 (1) ◽  
pp. 13-15 ◽  
Author(s):  
Gavin A. Craig ◽  
Jonathan J. Marbey ◽  
Stephen Hill ◽  
Olivier Roubeau ◽  
Simon Parsons ◽  
...  
Keyword(s):  
Single Molecule ◽  
Slow Relaxation ◽  
Single Molecule Magnet

scholarly journals Butterfly hysteresis and slow relaxation of the magnetization in (Et4N)3Fe2F9: manifestations of a single-molecule magnet

2002 ◽  
Vol 358 (5-6) ◽  
pp. 413-418 ◽  
Author(s):  
Ralph Schenker ◽  
Michael N. Leuenberger ◽  
Grégory Chaboussant ◽  
Hans U. Güdel ◽  
Daniel Loss
Keyword(s):  
Single Molecule ◽  
Slow Relaxation ◽  
Single Molecule Magnet

By Design: A Macrocyclic 3d–4f Single-Molecule Magnet with Quantifiable Zero-Field Slow Relaxation of Magnetization

2013 ◽  
Vol 52 (6) ◽  
pp. 3236-3240 ◽  
Author(s):  
Humphrey L. C. Feltham ◽  
Rodolphe Clérac ◽  
Liviu Ungur ◽  
Liviu F. Chibotaru ◽  
Annie K. Powell ◽  
...  
Keyword(s):  
Single Molecule ◽  
Slow Relaxation ◽  
Zero Field ◽  
Single Molecule Magnet

Modulating single-molecule magnet behavior towards multiple magnetic relaxation processes through structural variation in Dy4 clusters

2018 ◽  
Vol 5 (8) ◽  
pp. 1876-1885 ◽  
Author(s):  
Wen-Min Wang ◽  
Xiao-Min Kang ◽  
Hai-Yun Shen ◽  
Zhi-Lei Wu ◽  
Hong-Ling Gao ◽  
...  
Keyword(s):  
Schiff Base ◽  
Single Molecule ◽  
Schiff Base Ligand ◽  
Magnetic Relaxation ◽  
Structural Variation ◽  
Slow Relaxation ◽  
Relaxation Processes ◽  
Magnetic Studies ◽  
Single Molecule Magnet

Three Dy4 clusters based on a flexible and attractive Schiff base ligand HL have been synthesized, and they showed different tetranuclear core arrangements. Magnetic studies reveal that clusters 1–3 display distinct slow relaxation of magnetization.

Tetranuclear lanthanide complexes showing magnetic refrigeration and single molecule magnet behavior

2019 ◽  
Vol 43 (21) ◽  
pp. 8067-8074 ◽  
Author(s):  
Hong Yu ◽  
Jia-Xing Yang ◽  
Ju-Qing Han ◽  
Peng-Fei Li ◽  
Yin-Ling Hou ◽  
...  
Keyword(s):  
Single Molecule ◽  
Lanthanide Complexes ◽  
Magnetic Refrigeration ◽  
Slow Relaxation ◽  
Single Molecule Magnet

Four tetranuclear lanthanide complexes were fabricated and characterized. 1 exhibits cryogenic magnetic refrigeration property and 3 displays slow relaxation of the magnetization.

A series of [2 × 2] square grid LnIII4 clusters: a large magnetocaloric effect and single-molecule-magnet behavior

2019 ◽  
Vol 43 (19) ◽  
pp. 7419-7426 ◽  
Author(s):  
Wen-Min Wang ◽  
Xian-Zhen Li ◽  
Li Zhang ◽  
Jia-Li Chen ◽  
Jun-Hua Wang ◽  
...  
Keyword(s):  
Schiff Base ◽  
Magnetocaloric Effect ◽  
Single Molecule ◽  
Schiff Base Ligand ◽  
Relaxation Behavior ◽  
Slow Relaxation ◽  
Magnetic Studies ◽  
Single Molecule Magnet ◽  
Square Grid

Four new [2 × 2] square grid LnIII4 clusters were successfully synthesized by employing a multidentate chelating Schiff base ligand. Magnetic studies showed that cluster 1 displays a larger magnetocaloric effect (−ΔSm = 34.46 J kg−1 K−1 for ΔH = 7.0 T at 2.0 K), while 3 exhibits slow relaxation behavior under a zero dc field, with ΔE/kB of 42.76 K and τ0 of 1.02 × 10−6 s.

scholarly journals Investigation of the slow relaxation of the magnetization dynamics in homoleptic ene-diamido organodysprosium(iii) complexes with K+/arene interactions

CrystEngComm ◽  
2020 ◽  
Vol 22 (25) ◽  
pp. 4260-4267 ◽  
Author(s):  
Jérôme Long ◽  
Aleksei O. Tolpygin ◽  
Anton V. Cherkasov ◽  
Konstantin A. Lyssenko ◽  
Yannick Guari ◽  
...  
Keyword(s):  
Single Molecule ◽  
Slow Relaxation ◽  
Magnetization Dynamics ◽  
Single Molecule Magnet

Two new Dy3+ homoleptic ate-complexes based on different ene-diamido ligands [K(THF)2][Dy(DAD2R)2] (DAD = [2,6-iPr2C6H3N–CRCR–NC6H3iPr2-2,6], R = H, Me) show K+/arene interactions and single-molecule magnet behavior.

A remarkable energy barrier for spin reversal in a field induced dinuclear ytterbium single molecule magnet

2021 ◽  
Vol 50 (39) ◽  
pp. 13666-13670
Author(s):  
Arpan Mondal ◽  
Sanjit Konar
Keyword(s):  
Single Molecule ◽  
Energy Barrier ◽  
Slow Relaxation ◽  
Single Molecule Magnets ◽  
Single Molecule Magnet ◽  
Crystal Fields ◽  
Spin Reversal

Strong equatorial and weak axial crystal fields enhance the energy barrier for slow relaxation of magnetization in Yb-based single molecule magnets.

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