The low temperature fluorine-19 nuclear magnetic resonance spectra of alkylthio- and arylthio-substituted fluorophosphoranes

1968 ◽  
pp. 1662 ◽  
Author(s):  
S. C. Peake ◽  
R. Schmutzler
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Low Temperature ◽  
Nuclear Magnetic Resonance Spectra ◽  
Magnetic Resonance Spectra ◽  
Nuclear Magnetic

NUCLEAR MAGNETIC RESONANCE SPECTRA OF SIX-MEMBERED ALCYCLIC RING COMPOUNDS AT LOW TEMPERATURE: IV. PARTIALLY DEUTERATED 1,2-trans-CHLOROIODOCYCLOHEXANE

1962 ◽  
Vol 40 (9) ◽  
pp. 1870-1874 ◽  
Author(s):  
E. Premuzic ◽  
L. W. Reeves
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Low Temperature ◽  
Proton Resonance ◽  
Resonance Signal ◽  
Ring Compounds ◽  
Nuclear Magnetic Resonance Spectra ◽  
Signal Intensities ◽  
Magnetic Resonance Spectra ◽  
Nuclear Magnetic

A 50/50 mole% mixture of 1-iodo-2-chloro-1,3,3-trideutero-, and 1-chloro-2-iodo-1,3,3-trideutero-cyclohexane has been synthesized. At −93 °C in a CS2 solution iodochlorocyclohexane shows resolution into diaxial and diequatorial halogen forms. Analysis of the adjacent proton resonance signal intensities shows that this compound exists 68±3 mole% in the diaxial halogan form. This is quite similar to 1,2-dibromocyclohexane, which has 70 mole% in the diaxial form, and is in contrast to 1,2-dichlorocyclohexane, which has a more stable diequatorial form.

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