Specificity in the homogeneous metal-catalysed isotopic hydrogen exchange of polycyclic aromatic hydrocarbons. Evidence for complex formation between aromatic hydrocarbons and transition metals

1967 ◽  
pp. 1220
Author(s):  
J. L. Garnett ◽  
R. J. Hodges
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Complex Formation ◽  
Transition Metals ◽  
Aromatic Hydrocarbons ◽  
Hydrogen Exchange ◽  
Isotopic Hydrogen ◽  
Polycyclic Aromatic

Characterization of atmospheric particulates, particle-bound transition metals and polycyclic aromatic hydrocarbons of urban air in the centre of Athens (Greece)

Chemosphere ◽  
2006 ◽  
Vol 65 (5) ◽  
pp. 760-768 ◽  
Author(s):  
Athanasios Valavanidis ◽  
Konstantinos Fiotakis ◽  
Thomais Vlahogianni ◽  
Evangelos B. Bakeas ◽  
Styliani Triantafillaki ◽  
...  
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Transition Metals ◽  
Aromatic Hydrocarbons ◽  
Urban Air ◽  
Atmospheric Particulates ◽  
Polycyclic Aromatic

The Assessment of Contamination and Source of Polycyclic Aromatic Hydrocarbons from the Sediments of the Someş River

2019 ◽  
Vol 64 (1) ◽  
pp. 55-67
Author(s):  
Vlad Pӑnescu ◽  
◽  
Mihaela Cӑtӑlina Herghelegiu ◽  
Sorin Pop ◽  
Mircea Anton ◽  
...  
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Polycyclic Aromatic

1,1’-Biaceanthrylene and 2,2'-Biaceanthrylene: Models for Linking Larger Polycyclic Aromatic Hydrocarbons via Five-Membered Rings

2019 ◽  
Author(s):  
Yachu Du ◽  
Kyle Plunkett
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Polycyclic Aromatic Hydrocarbon ◽  
Aromatic Hydrocarbon ◽  
Electronic Properties ◽  
Aromatic Hydrocarbons ◽  
Model Systems ◽  
Redox Potentials ◽  
Dimer Model ◽  
Optical And Electronic Properties ◽  
Polycyclic Aromatic

We show that polycyclic aromatic hydrocarbon (PAH) chromophores that are linked between two five-membered rings can access planarized structures with reduced optical gaps and redox potentials. Two aceanthrylene chromophores were connected into dimer model systems with the chromophores either projected outward (2,2’-biaceanthrylene) or inward (1,1’-biaceanthrylene) and the optical and electronic properties were compared. Only the planar 2,2’-biaceanthrylene system showed significant reductions of the optical gaps (1 eV) and redox potentials in relation to the aceanthrylene monomer.<br>

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