Rearrangement of an unsaturated epoxy-ester to a cyclopropane compound

1967 ◽  
pp. 984 ◽  
Author(s):  
H. B. S. Conacher ◽  
F. D. Gunstone
Author(s):  
Muhammad Faheem Maqsood ◽  
Mohsin Ali Raza ◽  
Zaeem Ur Rehman ◽  
Muhammad Abid ◽  
Aqil Inam ◽  
...  

2006 ◽  
Vol 56 (2-3) ◽  
pp. 131-134 ◽  
Author(s):  
V.C. Malshe ◽  
Gulzar Waghoo
Keyword(s):  

Author(s):  
Jan W. Gooch
Keyword(s):  

1966 ◽  
Vol 39 (9) ◽  
pp. 448-453
Author(s):  
Seiichi TAKAHASHI ◽  
Takaaki ^|^Ocirc;MURA
Keyword(s):  

e-Polymers ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 636-650
Author(s):  
Xuyong Chen ◽  
Xiaorui Li ◽  
Kai Yang ◽  
Qian Zhang ◽  
Hui Zhu ◽  
...  

AbstractEpoxy resin is widely used in metal surface protection, because of corrosion resistance and adhesion. However, it’s water solubility, oxygen, and water impermeability are not enough. In this paper, linoleic acid (LOFA) and epoxy resin (E20) were used to synthesize epoxy ester (EL) and grafted with phosphonate esterified acrylic resin (AR-P) to prepare acrylic grafted epoxy ester (EL@AR-P). After modification, water solubility and film-forming property were improved, and the oxygen transmission rate (OTR) and water vapor transmission rate (WVTR) decreased. At the addition of PM-2 at 2%, the OTR, WVTR, and water-uptake rate decreased by 12.9%, 25.0%, and 12.1%, respectively. Subsequently, the modified material was subjected to electrochemical impedance spectroscopy. The low-frequency impedance of EL@AR-P2 is three times higher than EL@AR-P0. After 16 days of immersion, the low-frequency impedance of EL@AR-P2 is 20 times higher than EL@AR-P. Energy dispersive spectrometer and X-ray photoelectron spectroscopy results showed that the P elements were concentrated on the substrate surface and found the presence of P–O–Fe bonds, demonstrating that the phosphonate groups were migrated to the substrate surface to form a chelate layer with the substrate and enhancing the coating adhesion and corrosion resistance. This paper modifies the molecular structure of epoxy resin, which is expected to be an excellent material for anti-corrosion coatings.


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