Organic synthesis using fused salt system. Preparation of a polytriphenylene

1966 ◽  
pp. 53
Author(s):  
G. K. Ostrum ◽  
D. D. Lawson ◽  
R. F. Landel ◽  
J. D. Ingham
Keyword(s):  
Organic Synthesis ◽  
Salt System ◽  
Fused Salt

Demixing in the Fused Salt System AgCl/CsNO3/CsCl

1989 ◽  
Vol 161 (Part_1_2) ◽  
pp. 239-243
Author(s):  
Rolf Edelmann ◽  
Konrad G. Weil
Keyword(s):  
Salt System ◽  
Fused Salt

Vapour pressures and activities in the reciprocal fused salt systems ZnCl2 + Na2SO4 and ZnSO4 + NaCl

1975 ◽  
Vol 28 (12) ◽  
pp. 2587 ◽  
Author(s):  
RG Anthony ◽  
H Bloom
Keyword(s):  
Zinc Chloride ◽  
Vapour Pressure ◽  
Reciprocal System ◽  
Covalent Bonding ◽  
Salt System ◽  
Log P ◽  
Complex Ions ◽  
Partial Molar Enthalpies ◽  
Salt Systems ◽  
Fused Salt

Zinc chloride vapour pressures, activities and partial molar energies have been determined in the reciprocal fused salt system: Zn,Na/Cl,SO4 over the range 770-900 K. The transpiration vapour pressure of pure ZnCl2 was first redetermined for the range 720-900 K and found to follow the equation (in which P� is in mmHg): �������������� Log P�ZnCl2 = (-8247�17)/T-5.033 log T + 26.213 � 0.006 Activities of ZnC1, in the reciprocal system differed greatly from ideality, the degree of departure varying with both composition and temperature. In general, at relatively high ZnCl, concentrations, observed activities were greater than ideal and ZnCl2 partial molar enthalpies were positive; this behaviour is believed to be largely caused by the effect of partial covalent bonding in pure ZnCl2. At low ZnCl2 concentrations, activities were much less than ideal and ZnCl2 partial molar enthalpies were negative; this other effect is believed to be caused by the formation of complex ions within this system.

Phase Equilibria in the Ternary Fused-Salt System LiF-BeF2,-UF4

1962 ◽  
Vol 45 (2) ◽  
pp. 79-83 ◽  
Author(s):  
L. V. JONES ◽  
D. E. ETTER ◽  
C. R. HUDGENS ◽  
A. A. HUFFMAN ◽  
T. B. RHINEHAMMER ◽  
...  
Keyword(s):  
Phase Equilibria ◽  
Salt System ◽  
Fused Salt

Phase Equilibria for the Ternary Fused-Salt System NaF-BeF2-UF4

1963 ◽  
Vol 46 (6) ◽  
pp. 279-283 ◽  
Author(s):  
J. F. EICHELBERGER ◽  
C. R. HUDGENS ◽  
L. V. JONES ◽  
G. PISH ◽  
T. B. RHINEHAMMER ◽  
...  
Keyword(s):  
Phase Equilibria ◽  
Salt System ◽  
Fused Salt

Activity models in the Na+,Zn2+/Cl-,SO42- reciprocal fused salt system

1976 ◽  
Vol 29 (1) ◽  
pp. 65
Author(s):  
RG Anthony ◽  
H Bloom
Keyword(s):  
Reasonable Agreement ◽  
Solution Model ◽  
Salt System ◽  
Exchange Equilibrium ◽  
Ionic Solution ◽  
Activity Models ◽  
Experimental Values ◽  
Fused Salt

The conformal ionic solution model has been applied to the charge asymmetrical, reciprocal fused salt system: Na+,Znz+/C1-,S042-. This model takes into account binary and ternary type interactions as well as the exchange equilibrium: ZnCl2 + Na2SO4 ↔ ZnSO4 + 2NaCl Calculated ZnCl2 activities are found to be in reasonable agreement with experimental values.

Fused-salt system ammonium chloride-sodium tetrachloroaluminate

1975 ◽  
Vol 14 (12) ◽  
pp. 2902-2906 ◽  
Author(s):  
William C. Laughlin ◽  
N. W. Gregory
Keyword(s):  
Ammonium Chloride ◽  
Salt System ◽  
Fused Salt
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