Effects of double-layer polarization and counterion condensation on the electrophoresis of polyelectrolytes

Soft Matter ◽  
2011 ◽  
Vol 7 (2) ◽  
pp. 396-411 ◽  
Author(s):  
Li-Hsien Yeh ◽  
Jyh-Ping Hsu
Keyword(s):  
Double Layer ◽  
Counterion Condensation

Electric condensation of divalent counterions by humic acid nanoparticles

2016 ◽  
Vol 13 (1) ◽  
pp. 76 ◽  
Author(s):  
Herman P. van Leeuwen ◽  
Raewyn M. Town
Keyword(s):  
Humic Acid ◽  
Charge Density ◽  
Double Layer ◽  
Ion Pairs ◽  
Ion Pairing ◽  
Counterion Condensation ◽  
Counterion Binding ◽  
Satisfactory Description ◽  
Poisson Boltzmann ◽  
Very High

Environmental context Humic acids are negatively charged soft nanoparticles that play a governing role in the speciation of many ionic and molecular compounds in the environment. The charge density in the humic acid nanoparticle can be very high and the binding of divalent cations such as Ca2+ appears to go far beyond traditional ion pairing or Poisson–Boltzmann electrostatics. A two-state approach, combining counterion condensation in the intraparticulate double layer and classical Donnan partitioning in the bulk of the particle, provides a satisfactory description of the physicochemical speciation. Abstract Experimental data for divalent counterion binding by soil humic acid nanoparticles are set against ion distributions as ensuing from continuous Poisson–Boltzmann electrostatics and a two-state condensation approach. The results demonstrate that Poisson–Boltzmann massively underestimates the extent of binding of Ca2+ by humic acid, and that electric condensation of these counterions within the soft nanoparticulate body must be involved. The measured stability of the Ca2+–humic acid associate is also much greater than that predicted for ion pairing between single Ca2+ ions and monovalent negative humic acid sites, which also points to extensive electrostatic cooperativity within the humic acid particle. At sufficiently high pH, the charge density inside the humic acid entity may indeed become so high that the bulk particle attains a very high and practically flat potential profile throughout. At this limit, all the intraparticulate Ca2+ is at approximately the same electrostatic potential and the status of individual ion pairs has become immaterial. A two-state model, combining counterion condensation in the charged intraparticulate part of the double layer at the particle–medium interface and Donnan partitioning in the uncharged bulk of the humic acid particle, seems to lead the way to adequate modelling of the divalent counterion binding for various particle sizes and different ionic strengths.

Excluded volume driven counterion condensation inside nanotubes in a concave electrical double layer model

2005 ◽  
Vol 67 (1) ◽  
pp. 91-99 ◽  
Author(s):  
Klemen Bohinc ◽  
Jan Gimsa ◽  
Veronika Kralj-Iglič ◽  
Tomaž Slivnik ◽  
Aleš Iglič
Keyword(s):  
Double Layer ◽  
Electrical Double Layer ◽  
Excluded Volume ◽  
Counterion Condensation ◽  
Layer Model ◽  
Double Layer Model

Cracking at the fold in double layer coated paper: the influence of latex and starch composition

TAPPI Journal ◽  
2019 ◽  
Vol 18 (2) ◽  
pp. 93-99
Author(s):  
SEYYED MOHAMMAD HASHEMI NAJAFI ◽  
DOUGLAS BOUSFIELD, ◽  
MEHDI TAJVIDI
Keyword(s):  
Mechanical Properties ◽  
Double Layer ◽  
Starch Content ◽  
Single Layer ◽  
Double Layers ◽  
Coated Paper ◽  
Coated Papers ◽  
Coating Layers ◽  
Scanned Images ◽  
Packaging Paper

Cracking at the fold of publication and packaging paper grades is a serious problem that can lead to rejection of product. Recent work has revealed some basic mechanisms and the influence of various parameters on the extent of crack area, but no studies are reported using coating layers with known mechanical properties, especially for double-coated systems. In this study, coating layers with different and known mechanical properties were used to characterize crack formation during folding. The coating formulations were applied on two different basis weight papers, and the coated papers were folded. The binder systems in these formulations were different combinations of a styrene-butadiene latex and mixtures of latex and starch for two different pigment volume concentrations (PVC). Both types of papers were coated with single and double layers. The folded area was scanned with a high-resolution scanner while the samples were kept at their folded angle. The scanned images were analyzed within a constant area. The crack areas were reported for different types of papers, binder system and PVC values. As PVC, starch content, and paper basis weight increased, the crack area increased. Double layer coated papers with high PVC and high starch content at the top layer had more cracks in comparison with a single layer coated paper, but when the PVC of the top layer was low, cracking area decreased. No measurable cracking was observed when the top layer was formulated with a 100% latex layer.

A Survey on Crypto-Steganographic Schemes and A Use Case in Healthcare System

2019 ◽  
Vol 1 (2) ◽  
pp. 25-33
Author(s):  
Mei Ling Phang ◽  
Swee Huay Heng
Keyword(s):  
Social Networking ◽  
Information Sharing ◽  
Healthcare System ◽  
Double Layer ◽  
21St Century ◽  
Electronic Devices ◽  
Third Party ◽  
Use Case ◽  
Comparison Analysis ◽  
Information Assets

Information sharing has become prevalent due to the expansion of social networking in this 21st century. However, electronic devices are vulnerable to various kinds of attacks. Information might be disclosed, modified and accessed by an unauthorised third party which consequently leads to the breach of confidentiality, integrity and availability of the information. Therefore, it is of utmost importance to employ the technology of cryptography and steganography to protect information assets. Cryptography and steganography have weaknesses when they are working alone. Therefore, crypto-steganography, the combination of cryptography and steganography are introduced to overcome the weaknesses in order to provide a double layer of security and protection. This paper provides a general overview of steganography and cryptography as well as a comparison analysis of different crypto-steganographic schemes. A secure crypto-steganographic system for healthcare is then developed with the implementation and integration of the secure crypto-steganographic scheme proposed by Juneja and Sandhu. This healthcare system enables users to store and deliver message in a more secure way while achieving the main goals of both cryptography and steganography.

Electrode for Electric Double Layer Capacitor Made of Carbonized and Activated Cotton Cloth

2014 ◽  
Vol 134 (5) ◽  
pp. 360-361
Author(s):  
Masumi Fukuma ◽  
Takayuki Uchida ◽  
Yukito Fukushima ◽  
Jinichi Ogawa ◽  
Katsumi Yoshino
Keyword(s):  
Double Layer ◽  
Electric Double Layer ◽  
Cotton Cloth ◽  
Electric Double Layer Capacitor ◽  
Double Layer Capacitor
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