P-Heterocyclic carbenes as effective catalysts for the activation of single and multiple bonds. A theoretical study

2010 ◽  
Vol 34 (8) ◽  
pp. 1760 ◽  
Author(s):  
Markus Rullich ◽  
Ralf Tonner ◽  
Gernot Frenking
Keyword(s):  
Theoretical Study ◽  
Heterocyclic Carbenes ◽  
Multiple Bonds

Theoretical study of the mechanism for the sequential N–O and N–N bond cleavage within N2O adducts of N-heterocyclic carbenes by a vanadium(iii) complex

2016 ◽  
Vol 45 (3) ◽  
pp. 1047-1054 ◽  
Author(s):  
Robert Robinson ◽  
Miranda F. Shaw ◽  
Robert Stranger ◽  
Brian F. Yates
Keyword(s):  
Theoretical Study ◽  
Bond Cleavage ◽  
Heterocyclic Carbenes

The addition of N-heterocyclic carbene (NHC) increases the activity of N2O towards cleavage of both the N–O and N–N bonds.

Ligand Properties of Boron-Substituted Five-, Six-, and Seven-Membered Heterocyclic Carbenes: A Theoretical Study

2013 ◽  
Vol 32 (11) ◽  
pp. 3238-3248 ◽  
Author(s):  
Ashwini K. Phukan ◽  
Ankur Kanti Guha ◽  
Satyajit Sarmah
Keyword(s):  
Theoretical Study ◽  
Heterocyclic Carbenes

Theoretical Study of HmGaPHn. Characteristics of Gallium−Phosphorus Multiple Bonds

1999 ◽  
Vol 103 (26) ◽  
pp. 5152-5160 ◽  
Author(s):  
Timothy J. Dudley ◽  
William W. Brown ◽  
Mark R. Hoffmann
Keyword(s):  
Theoretical Study ◽  
Multiple Bonds

Metal free catalytic hydroboration of multiple bonds in methanol using N-heterocyclic carbenes under open atmosphere

2013 ◽  
Vol 11 (37) ◽  
pp. 6350 ◽  
Author(s):  
Kun Wen ◽  
Jinbo Chen ◽  
Feng Gao ◽  
Pinaki S. Bhadury ◽  
Erkang Fan ◽  
...  
Keyword(s):  
Heterocyclic Carbenes ◽  
Multiple Bonds ◽  
Open Atmosphere ◽  
Metal Free

New Trends in the Development of C-P Bond Forming Reactions

2021 ◽  
Vol 25 ◽  
Author(s):  
Vadim D. Romanenko
Keyword(s):  
Heterocyclic Carbenes ◽  
The State ◽  
Organic Substrates ◽  
Elemental Phosphorus ◽  
Multiple Bonds ◽  
Bond Forming ◽  
Phosphorus Containing ◽  
Direct Functionalization ◽  
Synthetic Approaches ◽  
State Of Art

: This article provides reviews related to some innovative (“non-classical”) synthetic strategies for the formation of CP bonds developed during the last decades. It provides examples of the most important milestones in this field, highlighting the state-of-art of functional phosphorus-containing molecules. Among these are the direct functionalization of organic substrates through chlorine-free reactions with elemental phosphorus, syntheses based on phosphinidene (RP) transfer, phosphorylating methodology employing multiple bonds containing P(III) compounds, reactions with stable heterocyclic carbenes, and synthetic approaches using phosphaethynolate and bis(trichlorosilyl)phosphide salts.

One-Electron Oxidation of a Disilicon(0) Compound: An Experimental and Theoretical Study of [Si2]+Trapped by N-Heterocyclic Carbenes

2015 ◽  
Vol 21 (35) ◽  
pp. 12509-12516 ◽  
Author(s):  
Marius I. Arz ◽  
Martin Straßmann ◽  
Andreas Meyer ◽  
Gregor Schnakenburg ◽  
Olav Schiemann ◽  
...  
Keyword(s):  
Theoretical Study ◽  
Heterocyclic Carbenes

Trapping CO2by Adduct Formation with Nitrogen Heterocyclic Carbenes (NHCs): A Theoretical Study

2017 ◽  
Vol 23 (44) ◽  
pp. 10604-10609 ◽  
Author(s):  
Ibon Alkorta ◽  
M. Merced Montero-Campillo ◽  
José Elguero
Keyword(s):  
Theoretical Study ◽  
Adduct Formation ◽  
Heterocyclic Carbenes ◽  
Nitrogen Heterocyclic
Sign in / Sign up

Export Citation Format

Share Document