Suzuki–Miyaura cross-coupling coupling reactions with low catalyst loading: a green and sustainable protocol in pure water

2011 ◽  
Vol 40 (13) ◽  
pp. 3116 ◽  
Author(s):  
Aziz Fihri ◽  
Denis Luart ◽  
Christophe Len ◽  
Abderrahim Solhy ◽  
Carole Chevrin ◽  
...  
Keyword(s):  
Pure Water ◽  
Cross Coupling ◽  
Catalyst Loading ◽  
Coupling Reactions ◽  
Low Catalyst Loading

Cross-coupling reactions catalyzed by an N-heterocyclic carbene–Pd(ii) complex under aerobic and CuI-free conditions

RSC Advances ◽  
2014 ◽  
Vol 4 (57) ◽  
pp. 30447-30452 ◽  
Author(s):  
Hongfei Lu ◽  
Lin Wang ◽  
Feifei Yang ◽  
Runze Wu ◽  
Wei Shen
Keyword(s):  
Cross Coupling ◽  
Catalytic Reactions ◽  
Catalyst Loading ◽  
Coupling Reactions ◽  
Heck Reactions ◽  
Cross Coupling Reactions ◽  
Low Catalyst Loading

The catalytic reactions proceed with good yields with a low catalyst loading (1 mol%) under aerobic and CuI-free conditions for Sonogashira and Heck reactions.

scholarly journals A Self-Assembling NHC-Pd-Loaded Calixarene as a Potent Catalyst for the Suzuki-Miyaura Cross-Coupling Reaction in Water

Molecules ◽  
2020 ◽  
Vol 25 (6) ◽  
pp. 1459
Author(s):  
Arnaud Peramo ◽  
Ibrahim Abdellah ◽  
Shannon Pecnard ◽  
Julie Mougin ◽  
Cyril Martini ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Palladium Complexes ◽  
Water Soluble ◽  
Catalyst Loading ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Self Assembling ◽  
Cross Coupling Reaction ◽  
Low Catalyst Loading

Nanoformulated calix[8]arenes functionalized with N-heterocyclic carbene (NHC)-palladium complexes were found to be efficient nano-reactors for Suzuki-Miyaura cross-coupling reactions of water soluble iodo- and bromoaryl compounds with cyclic triol arylborates at low temperature in water without any organic co-solvent. Combined with an improved one-step synthesis of triol arylborates from boronic acid, this remarkably efficient new tool provided a variety of 4′-arylated phenylalanines and tyrosines in good yields at low catalyst loading with a wide functional group tolerance.

A Novel Class of Amide-Derived Air-Stable P,O-Ligands for Suzuki Cross-Coupling at Low Catalyst Loading.

ChemInform ◽  
2004 ◽  
Vol 35 (23) ◽  
Author(s):  
Wei-Min Dai ◽  
Yannain Li ◽  
Ye Zhang ◽  
Kwong Wah Lai ◽  
Jinlong Wu
Keyword(s):  
Cross Coupling ◽  
Catalyst Loading ◽  
Low Catalyst Loading

scholarly journals Copper-catalyzed aerobic decarboxylative coupling between cyclic α-amino acids and diverse C–H nucleophiles with low catalyst loading

RSC Advances ◽  
2018 ◽  
Vol 8 (29) ◽  
pp. 16202-16206 ◽  
Author(s):  
Jing Guo ◽  
Ying Xie ◽  
Qiao-Lei Wu ◽  
Wen-Tian Zeng ◽  
Albert S. C. Chan ◽  
...  
Keyword(s):  
Amino Acids ◽  
Cross Coupling ◽  
Catalyst Loading ◽  
Ligand Free ◽  
Decarboxylative Coupling ◽  
Low Catalyst Loading

An aerobic decarboxylative cross-coupling of α-amino acids was realized using 1 mol% Cu2(OH)2CO3 catalyst under ligand free conditions.

A highly efficient precatalytic system (XPhos-PdG2) for the Suzuki–Miyaura cross-coupling of 7-chloro-1H-pyrrolo[2,3-c]pyridine employing low catalyst loading

2019 ◽  
Vol 23 (3) ◽  
pp. 697-707 ◽  
Author(s):  
Bhaskaran Savitha ◽  
Eeda Koti Reddy ◽  
D. Parthasarathi ◽  
Rajeesh Pakkath ◽  
Ranjith Pakkath Karuvalam ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Catalyst Loading ◽  
Highly Efficient ◽  
Low Catalyst Loading

PdCuCeO–TPAB: a new catalytic system for quasi-heterogeneous Suzuki–Miyaura cross-coupling reactions under ligand-free conditions in water

2017 ◽  
Vol 41 (22) ◽  
pp. 13560-13566 ◽  
Author(s):  
Philani P. Mpungose ◽  
Neo I. Sehloko ◽  
Glenn E. M. Maguire ◽  
Holger B. Friedrich
Keyword(s):  
Catalytic System ◽  
Pure Water ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Highly Active ◽  
Ligand Free

PdCuCeO was applied for Suzuki–Miyaura coupling in pure water. The catalyst was highly active (TOF > 3000 h−1) and could be reused.

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