Metal-carboxylate coordination polymers with redox-active moiety of tetrathiafulvalene (TTF)

2011 ◽  
Vol 40 (9) ◽  
pp. 1977 ◽  
Author(s):  
Qin-Yu Zhu ◽  
Jin-Po Wang ◽  
Yu-Rong Qin ◽  
Zheng Shi ◽  
Qiong-Hua Han ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Metal Carboxylate ◽  
Active Moiety ◽  
Redox Active

Transition metal carboxylate coordination polymers with amide-bridged polypyridine co-ligands: assemblies and properties

CrystEngComm ◽  
2015 ◽  
Vol 17 (21) ◽  
pp. 3887-3907 ◽  
Author(s):  
Ju-Wen Zhang ◽  
Xiao-Min Kan ◽  
Xiao-Li Li ◽  
Jian Luan ◽  
Xiu-Li Wang
Keyword(s):  
Transition Metal ◽  
Coordination Polymers ◽  
Metal Carboxylate

Steric and Electronic Effects of Ligand Substitution on Redox-Active Fe4S4-Based Coordination Polymers

2021 ◽  
Author(s):  
Omar Salinas ◽  
Jiaze Xie ◽  
Robert Papoular ◽  
Noah Horwitz ◽  
Erik Elkaim ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Ligand Substitution ◽  
Molecular Materials ◽  
Electronic Effects ◽  
Redox Active ◽  
And Function ◽  
Structure Properties

One of the notable advantages of molecular materials is the ability to precisely tune structure, properties, and function via molecular substitutions. While many studies have demonstrated this principle with classic...

scholarly journals Cover Feature: Octaboraneyl Complexes of Nickel: Monomers for Redox‐Active Coordination Polymers (Chem. Eur. J. 49/2020)

2020 ◽  
Vol 26 (49) ◽  
pp. 11063-11063
Author(s):  
Marcus W. Drover ◽  
Maeve C. Dufour ◽  
Lindsay A. Lesperance‐Nantau ◽  
Rayni P. Noriega ◽  
Kirill Levin ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Redox Active

Trinuclear Complexes and Coordination Polymers of Redox-Active Guanidino-Functionalized Aromatic (GFA) Compounds with a Triphenylene Core

2014 ◽  
Vol 53 (18) ◽  
pp. 9876-9896 ◽  
Author(s):  
Anna Lebkücher ◽  
Christoph Wagner ◽  
Olaf Hübner ◽  
Elisabeth Kaifer ◽  
Hans-Jörg Himmel
Keyword(s):  
Coordination Polymers ◽  
Trinuclear Complexes ◽  
Redox Active

Syntheses, structures and magnetic properties of nine coordination polymers based on terphenyl-tetracarboxylic acid ligands

2017 ◽  
Vol 46 (2) ◽  
pp. 430-444 ◽  
Author(s):  
Xinhui Zhou ◽  
Qianqian Chen ◽  
Baolin Liu ◽  
Liang Li ◽  
Tao Yang ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymers ◽  
Metal Carboxylate ◽  
Tetracarboxylic Acid ◽  
Ferromagnetic Interactions ◽  
Weak Ferromagnetic

Nine coordination polymers based on dinuclear metal units/metal-carboxylate chains and 1,1′:4′,1′′-terphenyl-2′,4,4′′,5′-tetracarboxylic acid have been synthesized and structurally characterized. Complexes 2 and 9 show the weak ferromagnetic interactions.

scholarly journals Steric and Electronic Effects of Ligand Substitution on Redox-Active Fe4S4-Based Coordination Polymers

2021 ◽  
Author(s):  
Omar Salinas ◽  
Jiaze Xie ◽  
Robert J. Papoular ◽  
Noah E. Horwitz ◽  
Erik Elkaim ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Photoelectron Spectroscopy ◽  
Electronic Effects ◽  
Iron Sulfur Clusters ◽  
Iron Sulfur ◽  
Redox Active ◽  
Metal Organic ◽  
Uv Visible ◽  
And Function ◽  
Fine Tune

<div>One of the notable advantages of molecular materials is the ability to precisely tune structure, properties, and function via molecular substitutions. While many studies have demonstrated this principle with classic carboxylate‐based coordination polymers, there are comparatively fewer examples where systematic changes to sulfur‐based coordination polymers have been investigated. Here we present such a study on 1D coordination chains of redox‐active</div><div>iron-sulfur clusters linked by methylated 1,4‐benzene‐dithiolates. A series of new iron-sulfur based coordination polymers were synthesized with either 2,5‐dimethyl‐1,4‐benzenedithiol (DMBDT) or 2,3,5,6‐tetramethyl‐1,4‐benzenedithiol. The structures of these compounds have been characterized based on synchrotron Xray</div><div>powder diffraction while their chemical and physical properties have been characterized by techniques including X‐ray photoelectron spectroscopy, cyclic voltammetry and UV–visible spectroscopy. Methylation results in the general trend of increasing electron‐richness in the series, but the tetramethyl version exhibits unexpected properties arising from steric constraints. All these results highlight how substitutions on organic linkers can modulate electronic factors to fine‐tune the electronic structures of metal‐organic materials.</div>

ChemInform Abstract: Transition Metal Carboxylate Coordination Polymers with Amide-Bridged Polypyridine Co-Ligands: Assemblies and Properties

ChemInform ◽  
2015 ◽  
Vol 46 (36) ◽  
pp. no-no
Author(s):  
Ju-Wen Zhang ◽  
Xiao-Min Kan ◽  
Xiao-Li Li ◽  
Jian Luan ◽  
Xiu-Li Wang
Keyword(s):  
Transition Metal ◽  
Coordination Polymers ◽  
Metal Carboxylate
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