The effect of coordinating and non-coordinating additives on the transport properties in ionic liquid electrolytes for lithium batteries

2011 ◽  
Vol 13 (10) ◽  
pp. 4632 ◽  
Author(s):  
Paul M. Bayley ◽  
A. S. Best ◽  
D. R. MacFarlane ◽  
M. Forsyth
2009 ◽  
Vol 11 (33) ◽  
pp. 7202 ◽  
Author(s):  
Paul M. Bayley ◽  
George H. Lane ◽  
Nathalie M. Rocher ◽  
Bronya R. Clare ◽  
Adam S. Best ◽  
...  

2015 ◽  
Vol 176 ◽  
pp. 301-310 ◽  
Author(s):  
Kisoo Yoo ◽  
Anirudh Deshpande ◽  
Soumik Banerjee ◽  
Prashanta Dutta

2013 ◽  
Vol 234 ◽  
pp. 277-284 ◽  
Author(s):  
Ninu Madria ◽  
T.A. Arunkumar ◽  
Nanditha G. Nair ◽  
Avinash Vadapalli ◽  
Yue-Wern Huang ◽  
...  

2020 ◽  
Vol 12 (21) ◽  
pp. 23774-23780
Author(s):  
Fengrui Zhang ◽  
Yiyang Sun ◽  
Zhicheng Wang ◽  
Daosong Fu ◽  
Jing Li ◽  
...  

2015 ◽  
Author(s):  
Kisoo Yoo ◽  
Prashanta Dutta ◽  
Soumik Banerjee

A mathematical model is developed for transport of ionic components to study the performance of ionic liquid based lithium batteries. The mathematical model is based on a univalent ternary electrolyte frequently encountered in ionic liquid electrolytes used for lithium batteries. Owing to the very high concentration of components in ionic liquid, the transport of lithium ions are described by the mutual diffusion phenomena using Maxwell-Stefan diffusivity. The model is used to study a lithium ion battery where the cations and anions of ionic liquid are mppy+ and TFSI-. The electric performance results predicted by the model are in good agreement with experimental data. We also studied the effect of load current density on the performance of lithium ion battery using this model. Numerical results indicate that low rate of lithium ion transport causes lithium depleted zone in the porous cathode regions as the load current density increases. This lithium depleted region is responsible for lower specific capacity in lithium-ion cells. The model presented in this study can be used for optimum design of ionic liquid electrolytes for lithium-ion and lithium-air batteries.


2015 ◽  
Vol 6 (12) ◽  
pp. 7274-7283 ◽  
Author(s):  
Feng Wu ◽  
Qizhen Zhu ◽  
Renjie Chen ◽  
Nan Chen ◽  
Yan Chen ◽  
...  

The ionic liquid-based electrolyte containing ring-like Pyr1,2O1TFSI and chain-like DMS exhibits good overall performance in lithium-ion batteries.


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