Enzyme activation and catalysis: characterisation of the vibrational modes of substrate and product in protochlorophyllide oxidoreductase

2011 ◽  
Vol 13 (6) ◽  
pp. 2307-2313 ◽  
Author(s):  
Olga A. Sytina ◽  
Maxime T. Alexandre ◽  
Derren J. Heyes ◽  
C. Neil Hunter ◽  
Bruno Robert ◽  
...  
Keyword(s):  
Enzyme Activation ◽  
Vibrational Modes ◽  
Protochlorophyllide Oxidoreductase

Anomalous vibrational modes in acetanilide as studied by inelastic neutron scattering

1992 ◽  
Vol 2 (10) ◽  
pp. 1929-1939 ◽  
Author(s):  
Mariette Barthes ◽  
Juegen Eckert ◽  
Susanna W. Johnson ◽  
Jacques Moret ◽  
Basil I. Swanson ◽  
...  
Keyword(s):  
Neutron Scattering ◽  
Inelastic Neutron Scattering ◽  
Inelastic Neutron ◽  
Vibrational Modes

Fe-N-C Artificial Enzyme: Activation of Oxygen for Dehydrogenation and Monoxygenation of Organic Substrates under Mild Condition and Cancer Therapeutic Application

2018 ◽  
Author(s):  
Fei He ◽  
Li Mi ◽  
Yanfei Shen ◽  
Toshiyuki Mori ◽  
Songqin Liu ◽  
...  
Keyword(s):  
Mild Condition ◽  
Enzyme Activation ◽  
Artificial Enzymes ◽  
Organic Substrates ◽  
Artificial Enzyme ◽  
Therapeutic Application ◽  
Highly Efficient ◽  
Activation Of Oxygen

Developing highly efficient artificial enzymes that directly employ O<sub>2</sub> as terminal oxidant has long been pursued but has rarely achieved yet. We report Fe-N-C has unusual enzyme-like activity in both dehydrogenation and monoxygenation of organic substrates with ~100% selectivity by direct using O<sub>2</sub>.

Complex formation and kinematic coupling: C2H4.PtCl3

1988 ◽  
Vol 53 (10) ◽  
pp. 2377-2384 ◽  
Author(s):  
Roman Řeřicha ◽  
Björg N. Cyvin ◽  
Jon Brunvoll ◽  
Sven J. Cyvin
Keyword(s):  
Complex Formation ◽  
Crystallographic Data ◽  
System Modelling ◽  
Vibrational Modes ◽  
Normal Coordinate ◽  
Kinematic Coupling ◽  
Fundamental Frequencies

Normal coordinate analyses including calculations of PED's were performed for C2H4.PtCl3 system modelling Zeise's anion, [(C2H4)PtCl3]-. The wedgewise distorsion of the C2H4 ligand known from the crystallographic data for Zeise's salt, was taken into account. Under these circumstances it was found that the kinematic couplings between the internal ligand and complex framework vibrational modes are rather small. The reliability of some existing assignments of the fundamental frequencies of Zeise's anion is discussed.

Asymptotics of the eigenmodes and stability of an elastic structure with general feedback matrix

2019 ◽  
Vol 84 (5) ◽  
pp. 873-911 ◽  
Author(s):  
Marianna A Shubov ◽  
Laszlo P Kindrat
Keyword(s):  
Initial Boundary ◽  
Initial Boundary Value Problem ◽  
Control Input ◽  
Vibrational Modes ◽  
Boundary Feedback ◽  
Feedback Matrix ◽  
Dissipative Boundary ◽  
Initial Boundary Value ◽  
The Right ◽  
Euler Bernoulli Beam

Abstract The distribution of natural frequencies of the Euler–Bernoulli beam subject to fully non-dissipative boundary conditions is investigated. The beam is clamped at the left end and equipped with a 4-parameter ($\alpha ,\beta ,k_1,k_2$) linear boundary feedback law at the right end. The $2 \times 2$ boundary feedback matrix relates the control input (a vector of velocity and its spatial derivative at the right end), to the output (a vector of shear and moment at the right end). The initial boundary value problem describing the dynamics of the beam has been reduced to the first order in time evolution equation in the state Hilbert space equipped with the energy norm. The dynamics generator has a purely discrete spectrum (the vibrational modes) denoted by $\{\nu _n\}_{n\in \mathbb {Z}^{\prime}}$. The role of the control parameters is examined and the following results have been proven: (i) when $\beta \neq 0$, the set of vibrational modes is asymptotically close to the vertical line on the complex $\nu$-plane given by the equation $\Re \nu = \alpha + (1-k_1k_2)/\beta$; (ii) when $\beta = 0$ and the parameter $K = (1-k_1 k_2)/(k_1+k_2)$ is such that $\left |K\right |\neq 1$ then the following relations are valid: $\Re (\nu _n/n) = O\left (1\right )$ and $\Im (\nu _n/n^2) = O\left (1\right )$ as $\left |n\right |\to \infty$; (iii) when $\beta =0$, $|K| = 1$, and $\alpha = 0$, then the following relations are valid: $\Re (\nu _n/n^2) = O\left (1\right )$ and $\Im (\nu _n/n) = O\left (1\right )$ as $\left |n\right |\to \infty$; (iv) when $\beta =0$, $|K| = 1$, and $\alpha>0$, then the following relations are valid: $\Re (\nu _n/\ln \left |n\right |) = O\left (1\right )$ and $\Im (\nu _n/n^2) = O\left (1\right )$ as $\left |n\right |\to \infty$.

Polar optical vibrational modes in quantum dots

1994 ◽  
Vol 49 (19) ◽  
pp. 13704-13711 ◽  
Author(s):  
E. Roca ◽  
C. Trallero-Giner ◽  
M. Cardona
Keyword(s):  
Quantum Dots ◽  
Vibrational Modes

Coupling of vibrational modes of adsorbates: Application to field-induced shifts for CO and CN on Cu(100)

1987 ◽  
Vol 36 (15) ◽  
pp. 8169-8172 ◽  
Author(s):  
P. S. Bagus ◽  
C. J. Nelin ◽  
K. Hermann ◽  
M. R. Philpott
Keyword(s):  
Vibrational Modes
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