Syntheses, structures and luminescent properties of decorated lanthanide metal-organic frameworks of (E)-4,4′-(ethene-1,2-diyl)dibenzoic acids

CrystEngComm ◽  
2011 ◽  
Vol 13 (6) ◽  
pp. 1821-1830 ◽  
Author(s):  
Yu Li ◽  
Datong Song
CrystEngComm ◽  
2018 ◽  
Vol 20 (5) ◽  
pp. 615-623 ◽  
Author(s):  
Li-Xin You ◽  
Bai-Bei Zhao ◽  
Hui-Jie Liu ◽  
Shu-Ju Wang ◽  
Gang Xiong ◽  
...  

Nineteen Ln-MOFs with four different crystal structures were prepared and the luminescence was studied.


2015 ◽  
Vol 27 (15) ◽  
pp. 5332-5339 ◽  
Author(s):  
Qingxia Yao ◽  
Antonio Bermejo Gómez ◽  
Jie Su ◽  
Vlad Pascanu ◽  
Yifeng Yun ◽  
...  

2014 ◽  
Vol 14 (5) ◽  
pp. 2394-2400 ◽  
Author(s):  
Jian Zhang ◽  
Bing Zheng ◽  
Tingting Zhao ◽  
Guanghua Li ◽  
Qisheng Huo ◽  
...  

Sensors ◽  
2019 ◽  
Vol 19 (5) ◽  
pp. 1260 ◽  
Author(s):  
Germán E. Gomez ◽  
María dos Santos Afonso ◽  
Héctor A. Baldoni ◽  
Federico Roncaroli ◽  
Galo J. A. A. Soler-Illia

Since the first studies of luminescent sensors based on metal organic frameworks (MOFs) about ten years ago, there has been an increased interest in the development of specific sensors towards cations, anions, explosives, small molecules, solvents, etc. However, the detection of toxic compounds related to agro-industry and nuclear activity is noticeably scarce or even non-existent. In this work, we report the synthesis and characterization of luminescent lanthanide-based MOFs (Ln-MOFs) with diverse crystalline architectures obtained by solvothermal methods. The luminescent properties of the lanthanides, and the hypersensitive transitions of Eu3+ (5D0→7F2) and Tb3+ (5D4→7F5) intrinsically found in the obtained MOFs in particular, were evaluated and employed as chemical sensors for agrochemical and cationic species. The limit of detection (LOD) of Tb-PSA MOFs (PSA = 2-phenylsuccinate) was 2.9 ppm for [UO22+] and 5.6 ppm for [Cu2+]. The variations of the 4f–4f spectral lines and the quenching/enhancement effects of the Ln-MOFs in the presence of the analytes were fully analyzed and discussed in terms of a combinatorial “host–guest” vibrational and “in-silico” interaction studies.


2016 ◽  
Vol 45 (2) ◽  
pp. 646-656 ◽  
Author(s):  
Richard F. D'Vries ◽  
German E. Gomez ◽  
José H. Hodak ◽  
Galo J. A. A. Soler-Illia ◽  
Javier Ellena

Characterization and optical properties of a 1D coordination polymer and 2D and 3D Metal–Organic Frameworks obtained from lanthanide metals, 3-hydroxinaftalene-2,7-disulfonic acid.


2006 ◽  
Vol 45 (6) ◽  
pp. 2581-2587 ◽  
Author(s):  
Xiaodan Guo ◽  
Guangshan Zhu ◽  
Fuxing Sun ◽  
Zhongyue Li ◽  
Xiaojun Zhao ◽  
...  

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