Structural diversity through ligand flexibility: two novel metal–organic nets via ligand-to-ligand cross-linking of “paddlewheels”

2010 ◽  
Vol 46 (46) ◽  
pp. 8734 ◽  
Author(s):  
Wenge Qiu ◽  
Jason A. Perman ◽  
Łukasz Wojtas ◽  
Mohamed Eddaoudi ◽  
Michael J. Zaworotko
Keyword(s):  
Structural Diversity ◽  
Cross Linking ◽  
Metal Organic

scholarly journals Recent Advances in the Application of Metal–Organic Frameworks for Polymerization and Oligomerization Reactions

Catalysts ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1441
Author(s):  
Fangyu Ren ◽  
Pengfei Ji
Keyword(s):  
Metal Organic Framework ◽  
Chemical Properties ◽  
Value Added ◽  
Structural Diversity ◽  
Future Design ◽  
Catalytic Active Site ◽  
Metal Organic ◽  
Templating Effect ◽  
Structural Aspects ◽  
And Chemical Properties

Polymers have become one of the major types of materials that are essential in our daily life. The controlled synthesis of value-added polymers with unique mechanical and chemical properties have attracted broad research interest. Metal–organic framework (MOF) is a class of porous material with immense structural diversity which offers unique advantages for catalyzing polymerization and oligomerization reactions including the uniformity of the catalytic active site, and the templating effect of the nano-sized channels. We summarized in this review the important recent progress in the field of MOF-catalyzed and MOF-templated polymerizations, to reveal the chemical principle and structural aspects of these systems and hope to inspire the future design of novel polymerization systems with improved activity and specificity.

Mechanical Properties of a Metal–Organic Framework formed by Covalent Cross-Linking of Metal–Organic Polyhedra

2018 ◽  
Vol 141 (2) ◽  
pp. 1045-1053 ◽  
Author(s):  
Garima Lal ◽  
Maziar Derakhshandeh ◽  
Farid Akhtar ◽  
Denis M. Spasyuk ◽  
Jian-Bin Lin ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Metal Organic Framework ◽  
Cross Linking ◽  
Metal Organic ◽  
Organic Framework

Structural Diversity of Zirconium Metal–Organic Frameworks and Effect on Adsorption of Toxic Chemicals

2020 ◽  
Vol 142 (51) ◽  
pp. 21428-21438
Author(s):  
Yongwei Chen ◽  
Xuan Zhang ◽  
Mohammad Rasel Mian ◽  
Florencia A. Son ◽  
Kun Zhang ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Structural Diversity ◽  
Toxic Chemicals ◽  
Metal Organic ◽  
Zirconium Metal

Design and synthesis of capped-paddlewheel-based porous coordination cages

2019 ◽  
Vol 55 (64) ◽  
pp. 9527-9530 ◽  
Author(s):  
Gregory R. Lorzing ◽  
Eric J. Gosselin ◽  
Brian S. Lindner ◽  
Rameswar Bhattacharjee ◽  
Glenn P. A. Yap ◽  
...  
Keyword(s):  
Structural Diversity ◽  
Design And Synthesis ◽  
Coordination Cages ◽  
Metal Organic

A novel cluster capping strategy is employed to leverage the structural diversity of metal–organic cages toward the isolation of porous cages.

Polymorphous Indium Metal–Organic Frameworks Based on a Ferrocene Linker: Redox Activity, Porosity, and Structural Diversity

2020 ◽  
Vol 59 (14) ◽  
pp. 9969-9978 ◽  
Author(s):  
Jannik Benecke ◽  
Erik Svensson Grape ◽  
Alexander Fuß ◽  
Stephan Wöhlbrandt ◽  
Tobias A. Engesser ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Structural Diversity ◽  
Redox Activity ◽  
Metal Organic ◽  
Indium Metal
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