Isoprene polymerization with aminopyridinato ligand supported rare-earth metal complexes. Switching of the regio- and stereoselectivity

2010 ◽  
Vol 46 (33) ◽  
pp. 6150 ◽  
Author(s):  
Yi Yang ◽  
Kui Lv ◽  
Lingfang Wang ◽  
Yang Wang ◽  
Dongmei Cui
Keyword(s):  
Rare Earth ◽  
Metal Complexes ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Rare Earth Metal Complexes ◽  
Isoprene Polymerization

Anilido-oxazoline-ligated rare-earth metal complexes: synthesis, characterization and highly cis-1,4-selective polymerization of isoprene

2019 ◽  
Vol 48 (11) ◽  
pp. 3583-3592 ◽  
Author(s):  
Yu Pan ◽  
Wenqiang Li ◽  
Ning-Ning Wei ◽  
Yat-Ming So ◽  
Yang Li ◽  
...  
Keyword(s):  
Rare Earth ◽  
Metal Complexes ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Catalytic Performance ◽  
Strong Fluorescence ◽  
Rare Earth Metal Complexes ◽  
Isoprene Polymerization

Anilido-oxazoline-ligated rare-earth metal complexes show strong fluorescence emissions and good catalytic performance on isoprene polymerization with high cis-1,4-selectivity.

Rare-earth alkyl complexes supported by formamidinate ligands: synthesis, structure, and catalytic activity for isoprene polymerization

2014 ◽  
Vol 43 (18) ◽  
pp. 6842-6847 ◽  
Author(s):  
Liping Guo ◽  
Xiancui Zhu ◽  
Shuangliu Zhou ◽  
Xiaolong Mu ◽  
Yun Wei ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Rare Earth ◽  
Metal Complexes ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Alkyl Complexes ◽  
Highly Active ◽  
Rare Earth Metal Complexes ◽  
Isoprene Polymerization

Monoalkyl rare-earth metal complexes could be highly active catalysts for 1,4-regioselective polymerization of isoprene in the presence of cocatalysts.

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