Synthesis, structure and hydrogen adsorption of a novel porous metal–organic framework, Mn9(btt)2(HCOO)12·0.7DMF·0.9H2O, where btt = 1,3,5-benzenetristetrazolate

CrystEngComm ◽  
2010 ◽  
Vol 12 (10) ◽  
pp. 3033 ◽  
Author(s):  
Ju-Hsiou Liao ◽  
Wan-Ting Chen ◽  
Cherng-Shiaw Tsai ◽  
Ching-Chun Yang ◽  
Chih-Chieh Wang
Keyword(s):  
Hydrogen Adsorption ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
Organic Framework

Mn(II)-Based Porous Metal–Organic Framework Showing Metamagnetic Properties and High Hydrogen Adsorption at Low Pressure

2011 ◽  
Vol 51 (1) ◽  
pp. 674-679 ◽  
Author(s):  
Zheng-Bo Han ◽  
Rui-Yun Lu ◽  
Yan-Fang Liang ◽  
Yan-Ling Zhou ◽  
Qing Chen ◽  
...  
Keyword(s):  
Hydrogen Adsorption ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Low Pressure ◽  
High Hydrogen ◽  
Metal Organic ◽  
Organic Framework

Synthesis and hydrogen adsorption properties of a new iron based porous metal-organic framework

2011 ◽  
Vol 36 (5) ◽  
pp. 3586-3592 ◽  
Author(s):  
Dan Lupu ◽  
Ovidiu Ardelean ◽  
Gabriela Blanita ◽  
Gheorghe Borodi ◽  
Mihaela D. Lazar ◽  
...  
Keyword(s):  
Hydrogen Adsorption ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Adsorption Properties ◽  
Metal Organic ◽  
Iron Based ◽  
Organic Framework

scholarly journals Synthesis, structural characterization, and carbon dioxide and hydrogen adsorption of a new three-dimensional metal organic framework Zn(BTC)4

2021 ◽  
pp. 174751982110035
Author(s):  
Jing Yan ◽  
Jiashun Gong ◽  
Li Song
Keyword(s):  
Carbon Dioxide ◽  
Thermogravimetric Analysis ◽  
Storage Capacity ◽  
Hydrogen Adsorption ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Porous Metal ◽  
X Ray Diffraction ◽  
Metal Organic ◽  
Organic Framework

A novel three-dimensional porous metal organic framework Zn(BTC)4 (BTC = benzene-1,3,5-tricarboxylic acid) is synthesized by the solvothermal method. This structure is characterized by single-crystal X-ray diffraction, scanning electron microscopy, and thermogravimetric analysis. This metal organic framework crystallizes in a monoclinic (P2(1)/n, V = 1795.7(2) Å3, Z = 4, Dc = 1.449 mg/cm3, α = 90.00°, β = 97.2200(10)°, γ = 90.00°, a = 9.5077(5) Å, b = 16.3950(16) Å, c = 11.6119(9) Å). The thermogravimetric analysis shows the material can be stabilized up to 350 °C, then the skeleton collapses between 350~510 °C. A luminescence test shows that the material gives out strong emission at 384 and 462 nm. The hydrogen storage capacity of this metal organic framework is 2.01 wt% at 77 K and a pressure of 10 bar. The carbon dioxide storage capacity of this metal organic framework is 4.17 mmol/g at 298 K and a pressure of 10 bar.

Peculiarities of high-pressure hydrogen adsorption on Pt catalyzed Cu-BTC metal–organic framework

2021 ◽  
Vol 23 (7) ◽  
pp. 4277-4286
Author(s):  
S. V. Chuvikov ◽  
E. A. Berdonosova ◽  
A. Krautsou ◽  
J. V. Kostina ◽  
V. V. Minin ◽  
...  
Keyword(s):  
High Pressure ◽  
High Pressures ◽  
Hydrogen Adsorption ◽  
Metal Organic Framework ◽  
Pt Catalyst ◽  
Metal Organic ◽  
Pt Catalyzed ◽  
Pressure Hydrogen ◽  
Organic Framework

Pt-Catalyst plays a key role in hydrogen adsorption by Cu-BTC at high pressures.

Multifunctionality in an Ion-Exchanged Porous Metal–Organic Framework

2021 ◽  
Vol 143 (3) ◽  
pp. 1365-1376
Author(s):  
Sérgio M. F. Vilela ◽  
Jorge A. R. Navarro ◽  
Paula Barbosa ◽  
Ricardo F. Mendes ◽  
Germán Pérez-Sánchez ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
Organic Framework

Unusual pore structure and sorption behaviour in a hexanodal zinc–organic framework material

2014 ◽  
Vol 50 (14) ◽  
pp. 1678-1681 ◽  
Author(s):  
Jinjie Qian ◽  
Feilong Jiang ◽  
Linjie Zhang ◽  
Kongzhao Su ◽  
Jie Pan ◽  
...  
Keyword(s):  
Pore Structure ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Sorption Behaviour ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

A highly porous metal–organic framework structurally consists of three topological kinds of 3-connected 1,3,5-benzenetricarboxylate ligands, Zn2(COO)4, Zn3O(COO)6 and Zn4O(COO)6 SBUs, featuring a new 3,3,3,4,4,6-c hexanodal topology.

High-Throughput Aided Synthesis of the Porous Metal−Organic Framework-Type Aluminum Pyromellitate, MIL-121, with Extra Carboxylic Acid Functionalization

2010 ◽  
Vol 49 (21) ◽  
pp. 9852-9862 ◽  
Author(s):  
Christophe Volkringer ◽  
Thierry Loiseau ◽  
Nathalie Guillou ◽  
Gérard Férey ◽  
Mohamed Haouas ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
High Throughput ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
Organic Framework

A Solar Assistant Dehumidifier Based on Porous Metal-Organic Framework

2021 ◽  
Vol 896 ◽  
pp. 13-20
Author(s):  
Xiao Yu Wen
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Modern Architecture ◽  
Activated Alumina ◽  
Additional Energy ◽  
Humidity Control ◽  
Energy Inputs ◽  
Metal Organic ◽  
High Regeneration ◽  
Organic Framework

As an important factor to measure environmental comfort, humidity control is very important. However, previous dehumidification methods have many defects, such as condensation and adsorbents, which often require a lot of energy. The growing requirements of an indoor environment can stem from the development of living levels and technology. Humidity, as an important factor to measure environmental comfort, affects living and production, and indoor humidity control is an indispensable part of modern architecture. However, there are many defects in the previous dehumidification methods, such as condensation dehumidification, which often requires a lot of energy. Traditional adsorbents (such as zeolite silica and activated alumina) have problems with fragile structures or high regeneration temperatures. In this paper, an indoor dehumidification device based on the porous metal-organic framework {MOF-801, Zr6O4(OH)4(Fumarate)6}, can realize the indoor dehumidification process only by using a small amount of solar energy (1 kilowatt per square meter). The device is expected to remove 0.2113 kg/h of moisture per square meter MOF-801, only needs a few additional energy inputs.

Sign in / Sign up

Export Citation Format

Share Document