Edge-directed [(M2)2L4] tetragonal metal–organic polyhedra decorated using a square paddle-wheel secondary building unit

2010 ◽  
Vol 46 (12) ◽  
pp. 2049 ◽  
Author(s):  
M. Jaya Prakash ◽  
Minhak Oh ◽  
Xinfang Liu ◽  
Kwi Nam Han ◽  
Gi Hun Seong ◽  
...  
Keyword(s):  
Secondary Building Unit ◽  
Paddle Wheel ◽  
Building Unit ◽  
Metal Organic

A double-walled triangular metal–organic macrocycle based on a [Cu2(COO)4] square paddle-wheel secondary building unit

2010 ◽  
Vol 39 (27) ◽  
pp. 6178 ◽  
Author(s):  
Xiaokai Song ◽  
Xinfang Liu ◽  
Minhak Oh ◽  
Myoung Soo Lah
Keyword(s):  
Secondary Building Unit ◽  
Paddle Wheel ◽  
Building Unit ◽  
Metal Organic

scholarly journals The Elusive Nitro-Functionalised Member of the IRMOF-9 Family

2019 ◽  
Vol 72 (10) ◽  
pp. 811 ◽  
Author(s):  
Luke Conte ◽  
Tian-You Zhou ◽  
Omid T. Qazvini ◽  
Lujia Liu ◽  
David R. Turner ◽  
...  
Keyword(s):  
Dicarboxylic Acid ◽  
Surface Area ◽  
Metal Organic Framework ◽  
Bet Surface Area ◽  
Solvothermal Reaction ◽  
X Ray Diffraction ◽  
Secondary Building Unit ◽  
Initial Product ◽  
Building Unit ◽  
Metal Organic

The solvothermal reaction of 2-nitro-[1,1′‐biphenyl]‐4,4′‐dicarboxylic acid (H2bpdcNO2) with Zn(NO3)2·6H2O in DMF solvent does not give a functionalised variant of IRMOF-9. Single-crystal X-ray diffraction analysis shows the major initial product of this reaction, WUF-21 (WUF=Wollongong University Framework), is a porous interpenetrated diamondoid metal–organic framework (MOF) with a secondary building unit that ‘doubly straps’ eight bridging bpdcNO2 ligands in a distorted tetrahedral shape around an unusual pentazinc core. A second porous MOF phase (WUF-23) containing a large and novel dodecazinc secondary building unit forms in the same reaction and eventually predominates in solutions containing formate anion, which arises from the hydrolysis of DMF. Doping the starting ligand with [1,1′‐biphenyl]‐4,4′‐dicarboxylic acid (H2bpdc) provides a facile way to grow nitro-functionalised IRMOF-9, hereafter denoted as WUF-22, where the dopant is carried through into the product. Activated WUF-22 is a microporous solid with an apparent Brunauer–Emmett–Teller (BET) surface area of 2497m2g−1, which matches well with geometric surface area calculations. The CO2 adsorption properties of WUF-22 are reported.

ROD-8, a rod MOF with a pyrene-cored tetracarboxylate linker: framework disorder, derived nets and selective gas adsorption

CrystEngComm ◽  
2014 ◽  
Vol 16 (28) ◽  
pp. 6291-6295 ◽  
Author(s):  
Ru-Jin Li ◽  
Mian Li ◽  
Xiao-Ping Zhou ◽  
Seik Weng Ng ◽  
Michael O'Keeffe ◽  
...  
Keyword(s):  
Benzoic Acid ◽  
Gas Adsorption ◽  
Metal Organic Framework ◽  
Secondary Building Unit ◽  
Building Unit ◽  
Metal Organic ◽  
Organic Framework

Reported here is a new CdII-based metal–organic framework (MOF), ROD-8, based on the rod secondary building unit (SBU) and tetratopic linker 1,3,6,8-tetrakis(p-benzoic acid)pyrene.

An unprecedented (3,4,14)-connected 3D metal–organic framework based on planar octanuclear lead(ii) clusters as a secondary building unit

CrystEngComm ◽  
2012 ◽  
Vol 14 (4) ◽  
pp. 1193-1196 ◽  
Author(s):  
Song-Liang Cai ◽  
Sheng-Run Zheng ◽  
Mei Pan ◽  
Jing-Bo Tan ◽  
Jun Fan ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Secondary Building Unit ◽  
Building Unit ◽  
Metal Organic ◽  
Organic Framework
Sign in / Sign up

Export Citation Format

Share Document