Facile synthesis of ultra-small monodisperse ceria nanocrystals at room temperature and their catalytic activity under visible light

2010 ◽  
Vol 20 (12) ◽  
pp. 2381 ◽  
Author(s):  
Yatendra S. Chaudhary ◽  
Snigdha Panigrahi ◽  
Simantini Nayak ◽  
Biswarup Satpati ◽  
Sarama Bhattacharjee ◽  
...  
2020 ◽  
Vol 11 (12) ◽  
pp. 2080-2088
Author(s):  
Yingjie Wang ◽  
Mengqi Wang ◽  
Liangjiu Bai ◽  
Lifen Zhang ◽  
Zhenping Cheng ◽  
...  

Well-defined PNVP block copolymers with more-activated monomers were synthesized by a single RAFT polymerization method under irradiation with visible light at room temperature.


2011 ◽  
Vol 76 (9) ◽  
pp. 1191-1198 ◽  
Author(s):  
Bahador Karami ◽  
Saeed Khodabakhshi

Convenient and simple procedures for the synthesis of phenazine and quinoxaline derivatives were developed via a reaction of ophenylenediamines and 1,2-dicarbonyl compounds. In addition, the synthesis of two new derivatives of 1,4-benzo diazine derivatives and the catalytic activity of magnesium sulfate heptahydrate (MgSO4?7H2O) in the room temperature condensation of o-phenylenediamines and 1,2- dicarbonyl compounds in ethanol as solvent are reported. This method has many appealing attributes, such as excellent yields, short reactions times, and simple work-up procedures.


2020 ◽  
Vol 1 (1) ◽  
pp. 37-42
Author(s):  
Subramanian Thirumeni ◽  
Choumini Balasanthiran ◽  
Grigoriy Sereda

Aims: Test the hypothesis that the catalytic activity of TiO2 nanoparticles towards a liquidphase or mechanoactivated multicomponent reaction can be tuned by visible light and the shape of nanoparticles. Background: Catalytic multicomponent reactions have been proven to be excellent synthetic approaches to a series of biologically relevant compounds including 2-amino-4H-benzo[b]pyrans. However, the potential photocatalytic activity and structural diversity of nanostructured catalysts remained underutilized in the design of new catalytic systems. Objective: Harness the photocatalytic potential and diverse morphology of TiO2 particles as catalysts for the liquid phase and mechanoactivated multicomponent organic reactions. Results: Catalytic activity of TiO2 nanoparticles towards multicomponent synthesis of 2-amino-4Hbenzo[ b]pyrans is increased by visible light. The nanorod-shaped TiO2 nanoparticles have shown substantially higher catalytic activity towards mechanoactivated multicomponent synthesis of 2- amino-4H-benzo[b]pyrans than their spherically-shaped counterparts. Conclusion: : An efficient methodology for the synthesis of 2-amino-4H-benzo[b]pyrans under ambient light condition has been developed using TiO2 nanorods (high aspect ratio anatase nanocrystals) as photocatalyst. This simple method furnished the corresponding terahydrobenzopyrans in high yields via three component reaction of aldehyde, malononitrile, and dimidone under solvent free reaction conditions at room temperature. The reaction takes 8-10 min at room temperature under ambient light condition and the catalyst can be reused multiple times. Utilization of light and the nanorod morphology of the catalyst through mechanoactivation has been applied for the -first time to the synthetic technique of multicomponent reactions. The synthetic procedures for 2-amino-4Hbenzo[ b]pyrans have been improved.


RSC Advances ◽  
2013 ◽  
Vol 3 (33) ◽  
pp. 13646 ◽  
Author(s):  
Yipeng Zang ◽  
Liping Li ◽  
Ying Zuo ◽  
Haifeng Lin ◽  
Guangshe Li ◽  
...  

2017 ◽  
Vol 41 (7) ◽  
pp. 2793-2799 ◽  
Author(s):  
Guangyin Fan ◽  
Xiaojing Li ◽  
Yuling Ma ◽  
Yun Zhang ◽  
Jiangtao Wu ◽  
...  

Magnetic recyclable PtyCo1−y/Ti3C2X2 (X = O, F) catalyst exhibits excellent catalytic performance for the hydrolysis of AB at room temperature.


2015 ◽  
Vol 3 (10) ◽  
pp. 5474-5481 ◽  
Author(s):  
Jingjing Li ◽  
Yunlong Xie ◽  
Yijun Zhong ◽  
Yong Hu

We demonstrated a facile reaction route, visible-light induced reduction followed by an anion exchange, to prepare one-dimensional (1D) Z-scheme Ag2CO3/Ag/AgBr ternary heterostructured nanorods (HNRs) with tunable chemical compositions at room temperature. The as-obtained 1D Ag2CO3/Ag/AgBr HNRs exhibit significantly enhanced photostability and photocatalytic activity.


RSC Advances ◽  
2014 ◽  
Vol 4 (28) ◽  
pp. 14786-14790 ◽  
Author(s):  
Liang Wang ◽  
Jing Cao ◽  
Jian-wei Wang ◽  
Qun Chen ◽  
Ai-jun Cui ◽  
...  

An efficient and green dimeric BODIPY-catalyzed sulfide oxidation under visible light is described.


ChemInform ◽  
2014 ◽  
Vol 45 (47) ◽  
pp. no-no
Author(s):  
Liang Wang ◽  
Jing Cao ◽  
Jian-wei Wang ◽  
Qun Chen ◽  
Ai-jun Cui ◽  
...  

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