One-step electrochemical deposition of Prussian Blue–multiwalled carbon nanotube nanocomposite thin-film: preparation, characterization and evaluation for H2O2sensing

2010 ◽  
Vol 20 (8) ◽  
pp. 1532-1537 ◽  
Author(s):  
Dan Du ◽  
Minghui Wang ◽  
Yuehua Qin ◽  
Yuehe Lin
Keyword(s):  
Thin Film ◽  
Carbon Nanotube ◽  
Prussian Blue ◽  
Electrochemical Deposition ◽  
Multiwalled Carbon Nanotube ◽  
Nanocomposite Thin Film ◽  
Multiwalled Carbon ◽  
Thin Film Preparation ◽  
One Step ◽  
Film Preparation

scholarly journals Multiwalled Carbon Nanotube for One-Step Cleanup of 21 Mycotoxins in Corn and Wheat Prior to Ultraperformance Liquid Chromatography–Tandem Mass Spectrometry Analysis

Toxins ◽  
2018 ◽  
Vol 10 (10) ◽  
pp. 409 ◽  
Author(s):  
Dongmei Jiang ◽  
Dizhe Wei ◽  
Liuqing Wang ◽  
Shuai Ma ◽  
Yuanfang Du ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Liquid Chromatography ◽  
Carbon Nanotube ◽  
Tandem Mass Spectrometry ◽  
Multiwalled Carbon Nanotube ◽  
Tandem Mass ◽  
Multiwalled Carbon ◽  
Chromatography Tandem Mass Spectrometry ◽  
Liquid Chromatography Tandem Mass ◽  
One Step

One-step solid-phase extraction (SPE) using a multiwalled carbon nanotube (MWCNT) for simultaneous analysis of 21 mycotoxins, including nine trichothecenes, zearalenone (ZEN) and its derivatives, four aflatoxins, and two ochratoxins, in corn and wheat was developed. Several key parameters affecting the performance of the one-step SPE procedure—types of MWCNT, combinations with five sorbents (octadecylsilyl (C18), hydrophilic–lipophilic balance (HLB), mixed-mode cationic exchange (MCX), silica gel, and amino-propyl (NH2)), and filling amounts of the MWCNTs—were thoroughly investigated. The combination of 20 mg carboxylic MWCNT and 200 mg C18 was proven to be the most effective, allowing the quantification of all analyzed mycotoxins in corn and wheat. Under the optimized cleanup procedure prior to ultraperformance liquid chromatography–tandem mass spectrometry (UPLC–MS/MS) analysis, the method was validated by analyzing samples spiked at the limit of quantification (LOQ), two-times LOQ, and 10-times LOQ. Satisfactory linearity (r2 ≥ 0.9910), high sensitivity (LOQ in different ranges of 0.5–25 μg L−1), good recovery (75.6–110.3%), and acceptable precision (relative standard deviation (RSD), 0.3–10.7%) were obtained. The applicability of the method was further confirmed using raw samples of corn and wheat. In conclusion, the established method was rapid, simple and reliable for simultaneous analysis of 21 mycotoxins in corn and wheat.

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