Gas storage in porous metal–organic frameworks for clean energy applications

2010 ◽  
Vol 46 (1) ◽  
pp. 44-53 ◽  
Author(s):  
Shengqian Ma ◽  
Hong-Cai Zhou
Keyword(s):  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Clean Energy ◽  
Gas Storage ◽  
Energy Applications ◽  
Metal Organic

Porous metal-organic frameworks for gas storage and separation: Status and challenges

EnergyChem ◽  
2019 ◽  
Vol 1 (1) ◽  
pp. 100006 ◽  
Author(s):  
Hao Li ◽  
Libo Li ◽  
Rui-Biao Lin ◽  
Wei Zhou ◽  
Zhangjing Zhang ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Gas Storage ◽  
Metal Organic

Hierarchically porous metal–organic frameworks: rapid synthesis and enhanced gas storage

Soft Matter ◽  
2018 ◽  
Vol 14 (47) ◽  
pp. 9589-9598 ◽  
Author(s):  
Chongxiong Duan ◽  
Hang Zhang ◽  
Feier Li ◽  
Jing Xiao ◽  
Shaojuan Luo ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Gas Storage ◽  
Organic Amine ◽  
Rapid Synthesis ◽  
Hierarchically Porous ◽  
Adsorption Capacities ◽  
Metal Organic ◽  
Diffusion Rates ◽  
Enhanced Adsorption

A simple, rapid and versatile method was developed to increase the pore sizes and pore volumes of microporous MOFs (HKUST-1, ZIF-8, ZIF-67, and ZIF-90) by employing organic amine as the template. The resultant hierarchically porous HKUST-1 exhibited significantly enhanced adsorption capacities and faster diffusion rates for CH4 and CO2 gas storage.

Metal–organic frameworks as a platform for clean energy applications

EnergyChem ◽  
2020 ◽  
Vol 2 (2) ◽  
pp. 100027 ◽  
Author(s):  
Xinran Li ◽  
Xinchun Yang ◽  
Huaiguo Xue ◽  
Huan Pang ◽  
Qiang Xu
Keyword(s):  
Metal Organic Frameworks ◽  
Clean Energy ◽  
Energy Applications ◽  
Metal Organic

scholarly journals Predicting the Features of Methane Adsorption in Large Pore Metal-Organic Frameworks for Energy Storage

Nanomaterials ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 818 ◽  
Author(s):  
George Manos ◽  
Lawrence Dunne
Keyword(s):  
Gas Adsorption ◽  
Metal Organic Frameworks ◽  
Gas Storage ◽  
Methane Adsorption ◽  
Energy Applications ◽  
Adsorbed Gas ◽  
Theoretical Approaches ◽  
Large Pore ◽  
Metal Organic ◽  
Computer Simulation Studies

Currently, metal-organic frameworks (MOFs) are receiving significant attention as part of an international push to use their special properties in an extensive variety of energy applications. In particular, MOFs have exceptional potential for gas storage especially for methane and hydrogen for automobiles. However, using theoretical approaches to investigate this important problem presents various difficulties. Here we present the outcomes of a basic theoretical investigation into methane adsorption in large pore MOFs with the aim of capturing the unique features of this phenomenon. We have developed a pseudo one-dimensional statistical mechanical theory of adsorption of gas in a MOF with both narrow and large pores, which is solved exactly using a transfer matrix technique in the Osmotic Ensemble (OE). The theory effectively describes the distinctive features of adsorption of gas isotherms in MOFs. The characteristic forms of adsorption isotherms in MOFs reflect changes in structure caused by adsorption of gas and compressive stress. Of extraordinary importance for gas storage for energy applications, we find two regimes of Negative gas adsorption (NGA) where gas pressure causes the MOF to transform from the large pore to the narrow pore structure. These transformations can be induced by mechanical compression and conceivably used in an engine to discharge adsorbed gas from the MOF. The elements which govern NGA in MOFs with large pores are identified. Our study may help guide the difficult program of work for computer simulation studies of gas storage in MOFs with large pores.

Porous Metal–Organic Frameworks for Gas Storage and Separation: What, How, and Why?

2014 ◽  
Vol 5 (20) ◽  
pp. 3468-3479 ◽  
Author(s):  
Bin Li ◽  
Hui-Min Wen ◽  
Wei Zhou ◽  
Banglin Chen
Keyword(s):  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Gas Storage ◽  
Metal Organic

Energy-related applications of functional porous metal–organic frameworks

2010 ◽  
Vol 83 (1) ◽  
pp. 167-188 ◽  
Author(s):  
Shengqian Ma ◽  
Le Meng
Keyword(s):  
Fuel Cells ◽  
Gas Separation ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Functional Materials ◽  
Gas Storage ◽  
Current Status ◽  
The Past ◽  
Metal Organic ◽  
New Type

As a new type of functional materials, porous metal–organic frameworks (MOFs) have experienced tremendous development in the past decade. Their amenability to design, together with the functionalizable nanospace inside their frameworks, has afforded them great potential for various applications. In this review, we provide a brief summary of the current status of porous MOFs in energy-related applications, mainly, energy gas storage, CO2 capture, gas separation, catalysis, and fuel cells.

Methane storage in metal–organic frameworks

2014 ◽  
Vol 43 (16) ◽  
pp. 5657-5678 ◽  
Author(s):  
Yabing He ◽  
Wei Zhou ◽  
Guodong Qian ◽  
Banglin Chen
Keyword(s):  
Natural Gas ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Gas Storage ◽  
Methane Storage ◽  
Natural Gas Storage ◽  
Metal Organic

Porous metal–organic frameworks have been emerging as very promising materials for methane (natural gas) storage.

Synthesis, designing strategies and photocatalytic charge dynamics of Metal-Organic Frameworks (MOFs): A catalyzed Photo-degradation approach towards Organic Dyes

2021 ◽  
Author(s):  
Ayushi Singh ◽  
Ashish Kumar Singh ◽  
Jian-Qiang Liu ◽  
Abhinav Kumar
Keyword(s):  
Small Molecule ◽  
Coordination Polymers ◽  
Organic Dyes ◽  
Metal Organic Frameworks ◽  
Gas Storage ◽  
New Variety ◽  
Photo Degradation ◽  
Charge Dynamics ◽  
Potential Applications ◽  
Metal Organic

Metal-organic frameworks (MOFs) or coordination polymers (CPs) are regarded as new variety of materials that find potential applications in plethora of areas such as gas/small molecule absorption/separation, gas storage, membranes...

Sign in / Sign up

Export Citation Format

Share Document