Spectroscopic characterization of Fe-doped synthetic chrysotile by EPR, DRS and magnetic susceptibility measurements

Elena Borghi; Manlio Occhiuzzi; Elisabetta Foresti; Isidoro Giorgio Lesci; Norberto Roveri

doi:10.1039/b915182f

Spectroscopic characterization of Fe-doped synthetic chrysotile by EPR, DRS and magnetic susceptibility measurements

Physical Chemistry Chemical Physics ◽

10.1039/b915182f ◽

2010 ◽

Vol 12 (1) ◽

pp. 227-238 ◽

Cited By ~ 25

Author(s):

Elena Borghi ◽

Manlio Occhiuzzi ◽

Elisabetta Foresti ◽

Isidoro Giorgio Lesci ◽

Norberto Roveri

Keyword(s):

Magnetic Susceptibility ◽

Spectroscopic Characterization

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Magnetic and Mössbauer Spectroscopic Characterization of EuNi2Sb2

Zeitschrift für Naturforschung B ◽

10.1515/znb-2011-1114 ◽

2011 ◽

Vol 66 (11) ◽

pp. 1179-1182 ◽

Cited By ~ 1

Author(s):

Inga Schellenberg ◽

Matthias Eul ◽

Rainer Pöttgen

Keyword(s):

Magnetic Susceptibility ◽

Magnetic Moment ◽

Spectroscopic Characterization ◽

Hyperfine Fields ◽

Arc Melting ◽

Divalent Europium ◽

Spectral Components ◽

Experimental Magnetic Moment ◽

Magnetically Ordered

ThCr2Si2-type EuNi2Sb2 (I4/mmm, a = 438.1(1), c = 1068.1(4) pm) was synthesized by arc-melting of the elements. Magnetic susceptibility measurements show Curie- Weiss behavior with an experimental magnetic moment of 8.03(1) μB/Eu atom, indicating stable divalent europium. EuNi2Sb2 orders antiferromagnetically at TN = 5.8(1) K. A 151 Eu Mössbauer spectrum at 4.2 K shows two spectral components with hyperfine fields of 19.1 and 12.9 T, indicative of different magnetically ordered domains

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On the Magnetic and Mössbauer Spectroscopic Characterization of EuPd2Sb2

Zeitschrift für Naturforschung B ◽

10.1515/znb-2010-0104 ◽

2010 ◽

Vol 65 (1) ◽

pp. 18-22 ◽

Cited By ~ 10

Author(s):

Inga Schellenberg ◽

Matthias Eul ◽

Rainer Pöttgen

Keyword(s):

Magnetic Susceptibility ◽

Hyperfine Field ◽

Magnetic Moment ◽

Spectroscopic Characterization ◽

Induction Melting ◽

Temperature Dependent ◽

Field Splitting ◽

Divalent Europium ◽

Experimental Magnetic Moment

The CaBe2Ge2-type antimonide EuPd2Sb2 (P4/nmm, a = 462.43(7), c = 1056.1(2) pm) was synthesized by induction melting of the elements in a sealed tantalum tube. Temperature-dependent magnetic susceptibility measurements have revealed Curie-Weiss behavior with an experimental magnetic moment of 7.93(1) μB/Eu atom, indicating stable divalent europium. EuPd2Sb2 orders antiferromagnetically at TN = 4.5(2) K as is also evident from almost full hyperfine field splitting (Bh = 19.5 T) in the 151Eu Mössbauer spectrum at 4.2 K

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Synthesis, Spectroscopic characterization of Co(II), Ni(II) and Cu(II) complexes with 2-meracapto-5-(2,4-dinitrophenyl)- 1,3,4-oxadiazole or 2-meracapto-5-((4-(dimethylamino)benzylidene)amino)-1,3,4-thiadiazole ligands

Oriental Journal Of Chemistry ◽

10.13005/ojc/3404011 ◽

2018 ◽

Vol 34 (4) ◽

pp. 1787-1794 ◽

Cited By ~ 3

Author(s):

Saleh A. Ahmed ◽

Ahmed S. M. Al-Janabi

Keyword(s):

Magnetic Susceptibility ◽

Nitrogen Atom ◽

Thiol Group ◽

Spectroscopic Characterization ◽

Molar Conductivity ◽

Metal Salts ◽

Visible Spectroscopy ◽

Nmr Data ◽

Uv Visible

New Co(II), Ni(II) and Cu(II) complexes with 2-meracapto-5-(2,4-dinitrophenyl)-1,3,4-oxadiazole (IpotH) or 2-meracapto-5-((4-(dimethylamino)benzylidene)amino)-1,3,4-thiadiazole (daptH) ligands, were prepared by treatment two moles of thione ligands with one mole of metal salts in EtOH/Acetone and H2O as a solvents, to afforded octahedral complexes of the types [MX2(k2-IpotH)2] (Where M = Co, Cu, X= Cl and M= Ni , X= NO3 ) or [MX2(k2-daptH)2] (Where M = Co, Cu, X= Cl and M= Ni , X= NO3 ). The thione ligands bonded through the nitrogen atom of heterocylic and sulfur atom of thiol group. The prepared ligands and its complexes were characterization by elemental analysis (CHNM), IR spectroscopy , molar conductivity, magnetic susceptibility, UV-Visible spectroscopy and 1H NMR data.

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