Transformation of polymerization of polar vinyl monomers by discrete and hybrid metal catalysts

2009 ◽  
pp. 8784 ◽  
Author(s):  
Eugene Y.-X. Chen
Keyword(s):  
Metal Catalysts ◽  
Vinyl Monomers

Coordination polymerization of renewable butyrolactone-based vinyl monomers by lanthanide and early metal catalysts

2010 ◽  
Vol 39 (29) ◽  
pp. 6710 ◽  
Author(s):  
Garret M. Miyake ◽  
Stacie E. Newton ◽  
Wesley R. Mariott ◽  
Eugene Y.-X. Chen
Keyword(s):  
Metal Catalysts ◽  
Vinyl Monomers ◽  
Coordination Polymerization

Palladium Promoted Copolymerization of Carbon Monoxide with Polar or Nonpolar Olefinic Monomers

2020 ◽  
Vol 24 ◽  
Author(s):  
Yanlin Zong ◽  
Qiankun Li ◽  
Hongliang Mu ◽  
Zhongbao Jian
Keyword(s):  
Carbon Monoxide ◽  
Physical Properties ◽  
Vinyl Monomers ◽  
Pd Catalysts ◽  
Catalytic Systems

Abstract:: The copolymers of carbon monoxide (CO) and olefins, namely polyketones, are a family of widely used materi-als. In the catalytic preparation of these materials, palladium(II) catalysts represent the most successful catalytic systems. The production of both alternating and non-alternating polyketones has been achieved, with great difference in their physical properties. Herein, a variety of palladium(II) catalysts employed for the copolymerization of CO with various olefinic mon-omers such as ethylene, α-olefins, styrene and polar vinyl monomers are fully summarized. The influence of important fac-tors such as solvents and counterions on specific copolymerization, is also discussed. This review aims to enlighten the de-sign of new Pd catalysts with improved properties, as well as the development of new polyketone materials.

Formaldehyde Synthesis over Foam Metal Catalysts

2016 ◽  
Vol 14 (999) ◽  
pp. 1-1
Author(s):  
Alexey Pestryakov ◽  
Valerii Lunin
Keyword(s):  
Metal Catalysts ◽  
Foam Metal ◽  
Formaldehyde Synthesis
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