Self-assembly of a PdII neutral molecular rectangle via a new organometallic PdII2 molecular clip and oxygen donor linker

2009 ◽  
pp. 6701 ◽  
Author(s):  
Arun Kumar Bar ◽  
Bappaditya Gole ◽  
Sushobhan Ghosh ◽  
Partha Sarathi Mukherjee
2005 ◽  
Vol 44 (22) ◽  
pp. 7886-7894 ◽  
Author(s):  
Duckhyun Kim ◽  
Jong Hyub Paek ◽  
Moo-Jin Jun ◽  
Jin Yong Lee ◽  
Sang Ook Kang ◽  
...  
Keyword(s):  

2021 ◽  
Author(s):  
Guo Feng ◽  
Li Yin ◽  
Feng Jiang ◽  
Zhijun Yan ◽  
Jinlin Xu ◽  
...  

Abstract Ba0.7Sr0.3TiO3 ceramic fibers were synthesized via the precursor linear self-assembly nonhydrolytic sol-gel (NHSG) method, taking TiCl4 as the titanium source, anhydrous barium acetate and strontium acetate as the barium source and strontium source, anhydrous ethanol and glycol as the oxygen donor and solvent, respectively. The NHSG method promotes the formation of Ba–O–Ti and Sr–O–Ti through heterogeneous condensation. The bimolecular association structure of the reaction intermediate (chlorotitanium ethoxide) between ethanol and titanium tetrachloride facilitates the self-linear assembly of precursors. It also enables linear colloidal particle formation and excellent spinnability of the sol. The novel Ba0.7Sr0.3TiO3 ceramic fibers would promote the flexibility of electronic products.


2020 ◽  
Vol 56 (20) ◽  
pp. 3077-3080 ◽  
Author(s):  
Yoann Cotelle ◽  
Marie Hardouin-Lerouge ◽  
Elise Lemasson ◽  
Yohann Morille ◽  
David Canevet ◽  
...  

A glycoluril-based molecular clip incorporating tetrathiafulvalene sidewalls self-assembles with fullerene C60 in a 2 : 1 stoichiometry in solution.


2008 ◽  
Vol 8 (5) ◽  
pp. 1645-1653 ◽  
Author(s):  
Yitao Li ◽  
Xianggao Meng ◽  
Liping Cao ◽  
Yuzhou Wang ◽  
Guodong Yin ◽  
...  

2003 ◽  
Vol 07 (04) ◽  
pp. 249-254 ◽  
Author(s):  
Johannes A. A. W. Elemans ◽  
Roeland J. M. Nolte ◽  
Alan E. Rowan

The construction of a porphyrin array by a stepwise, hierarchical self-assembly process is described. Four molecular clip host molecules are complexed, in a solid state self-assembly process, to one porphyrin guest molecule. When dissolved in chloroform, the 4:1 host-guest complexes spontaneously self-assemble into an array in which the porphyrins are organized in a cofacial stack. The ensemble is stabilized by a combination of π-π interactions between the porphyrins and between the aromatic surfaces of the host molecules.


2003 ◽  
Vol 125 (46) ◽  
pp. 13950-13951 ◽  
Author(s):  
Neeladri Das ◽  
Partha Sarathi Mukherjee ◽  
Atta M. Arif ◽  
Peter J. Stang
Keyword(s):  

Author(s):  
D. Reis ◽  
B. Vian ◽  
J. C. Roland

Wall morphogenesis in higher plants is a problem still open to controversy. Until now the possibility of a transmembrane control and the involvement of microtubules were mostly envisaged. Self-assembly processes have been observed in the case of walls of Chlamydomonas and bacteria. Spontaneous gelling interactions between xanthan and galactomannan from Ceratonia have been analyzed very recently. The present work provides indications that some processes of spontaneous aggregation could occur in higher plants during the formation and expansion of cell wall.Observations were performed on hypocotyl of mung bean (Phaseolus aureus) for which growth characteristics and wall composition have been previously defined.In situ, the walls of actively growing cells (primary walls) show an ordered three-dimensional organization (fig. 1). The wall is typically polylamellate with multifibrillar layers alternately transverse and longitudinal. Between these layers intermediate strata exist in which the orientation of microfibrils progressively rotates. Thus a progressive change in the morphogenetic activity occurs.


Author(s):  
M. Kessel ◽  
R. MacColl

The major protein of the blue-green algae is the biliprotein, C-phycocyanin (Amax = 620 nm), which is presumed to exist in the cell in the form of distinct aggregates called phycobilisomes. The self-assembly of C-phycocyanin from monomer to hexamer has been extensively studied, but the proposed next step in the assembly of a phycobilisome, the formation of 19s subunits, is completely unknown. We have used electron microscopy and analytical ultracentrifugation in combination with a method for rapid and gentle extraction of phycocyanin to study its subunit structure and assembly.To establish the existence of phycobilisomes, cells of P. boryanum in the log phase of growth, growing at a light intensity of 200 foot candles, were fixed in 2% glutaraldehyde in 0.1M cacodylate buffer, pH 7.0, for 3 hours at 4°C. The cells were post-fixed in 1% OsO4 in the same buffer overnight. Material was stained for 1 hour in uranyl acetate (1%), dehydrated and embedded in araldite and examined in thin sections.


Author(s):  
Alan S. Rudolph ◽  
Ronald R. Price

We have employed cryoelectron microscopy to visualize events that occur during the freeze-drying of artificial membranes by employing real time video capture techniques. Artificial membranes or liposomes which are spherical structures within internal aqueous space are stabilized by water which provides the driving force for spontaneous self-assembly of these structures. Previous assays of damage to these structures which are induced by freeze drying reveal that the two principal deleterious events that occur are 1) fusion of liposomes and 2) leakage of contents trapped within the liposome [1]. In the past the only way to access these events was to examine the liposomes following the dehydration event. This technique allows the event to be monitored in real time as the liposomes destabilize and as water is sublimed at cryo temperatures in the vacuum of the microscope. The method by which liposomes are compromised by freeze-drying are largely unknown. This technique has shown that cryo-protectants such as glycerol and carbohydrates are able to maintain liposomal structure throughout the drying process.


Author(s):  
M. Sarikaya ◽  
J. T. Staley ◽  
I. A. Aksay

Biomimetics is an area of research in which the analysis of structures and functions of natural materials provide a source of inspiration for design and processing concepts for novel synthetic materials. Through biomimetics, it may be possible to establish structural control on a continuous length scale, resulting in superior structures able to withstand the requirements placed upon advanced materials. It is well recognized that biological systems efficiently produce complex and hierarchical structures on the molecular, micrometer, and macro scales with unique properties, and with greater structural control than is possible with synthetic materials. The dynamism of these systems allows the collection and transport of constituents; the nucleation, configuration, and growth of new structures by self-assembly; and the repair and replacement of old and damaged components. These materials include all-organic components such as spider webs and insect cuticles (Fig. 1); inorganic-organic composites, such as seashells (Fig. 2) and bones; all-ceramic composites, such as sea urchin teeth, spines, and other skeletal units (Fig. 3); and inorganic ultrafine magnetic and semiconducting particles produced by bacteria and algae, respectively (Fig. 4).


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