N-heterocyclic carbenes of iridium(I): ligand effects on the catalytic activity in transfer hydrogenation

Rhodium(III) Complexes Containing C4-Bound N-Heterocyclic Carbenes: Synthesis, Coordination Chemistry, and Catalytic Activity in Transfer Hydrogenation

Organometallics ◽

10.1021/om800110c ◽

2008 ◽

Vol 27 (13) ◽

pp. 3161-3171 ◽

Cited By ~ 82

Author(s):

Liangru Yang ◽

Anneke Krüger ◽

Antonia Neels ◽

Martin Albrecht

Keyword(s):

Catalytic Activity ◽

Coordination Chemistry ◽

Heterocyclic Carbenes ◽

Transfer Hydrogenation

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Synthesis and Catalytic Activity of Rhodium(I) and Iridium(I) 4,5-Dibrominated N-Heterocyclic Carbenes

10.26434/chemrxiv.7476347.v1 ◽

2018 ◽

Author(s):

Samantha Furfari ◽

Matthew Gyton ◽

Marcus Cole

Keyword(s):

Catalytic Activity ◽

Spectroscopic Data ◽

Heterocyclic Carbenes ◽

Transfer Hydrogenation ◽

Carbonyl Complexes ◽

Donor Capacity ◽

Catalytic Applications

The synthesis and characterisation of another example of an air-stable carbene is described, in addition to the preparation of rhodium and iridium olefin and carbonyl complexes. The spectroscopic data indicates that these air-stable carbenes do not display reduced sigma-donor capacity of the carbenic centre. The catalytic applications of these carbenes are explored in the hydrosilylation and transfer hydrogenation processes.

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ChemInform Abstract: Synthesis of Ru(II) Complexes Containing N-Heterocyclic Carbenes Functionalized with Secondary Donor Groups: Catalytic Activity Toward Enantioselective Transfer Hydrogenation.

ChemInform ◽

10.1002/chin.201349076 ◽

2013 ◽

Vol 44 (49) ◽

pp. no-no

Author(s):

Misato Yoshimura ◽

Ryo Kamisue ◽

Satoshi Sakaguchi

Keyword(s):

Catalytic Activity ◽

Heterocyclic Carbenes ◽

Transfer Hydrogenation

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Synthesis and Catalytic Activity of Rhodium(I) and Iridium(I) 4,5-Dibrominated N-Heterocyclic Carbenes

10.26434/chemrxiv.7476347 ◽

2018 ◽

Author(s):

Samantha Furfari ◽

Matthew Gyton ◽

Marcus Cole

Keyword(s):

Catalytic Activity ◽

Spectroscopic Data ◽

Heterocyclic Carbenes ◽

Transfer Hydrogenation ◽

Carbonyl Complexes ◽

Donor Capacity ◽

Catalytic Applications

The synthesis and characterisation of another example of an air-stable carbene is described, in addition to the preparation of rhodium and iridium olefin and carbonyl complexes. The spectroscopic data indicates that these air-stable carbenes do not display reduced sigma-donor capacity of the carbenic centre. The catalytic applications of these carbenes are explored in the hydrosilylation and transfer hydrogenation processes.

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Synthesis of Ru(II) complexes containing N-heterocyclic carbenes functionalized with secondary donor groups: Catalytic activity toward enantioselective transfer hydrogenation

Journal of Organometallic Chemistry ◽

10.1016/j.jorganchem.2013.04.028 ◽

2013 ◽

Vol 740 ◽

pp. 26-32 ◽

Cited By ~ 20

Author(s):

Misato Yoshimura ◽

Ryo Kamisue ◽

Satoshi Sakaguchi

Keyword(s):

Catalytic Activity ◽

Heterocyclic Carbenes ◽

Transfer Hydrogenation

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Ruthenium(II) complexes bearing pyridine-based tridentate and bidentate ligands: catalytic activity for transfer hydrogenation of aryl ketones

Applied Organometallic Chemistry ◽

10.1002/aoc.2901 ◽

2012 ◽

Vol 26 (12) ◽

pp. 663-670 ◽

Cited By ~ 25

Author(s):

Osman Dayan ◽

Serkan Dayan ◽

İbrahim Kani ◽

Bekir Çetinkaya

Keyword(s):

Catalytic Activity ◽

Transfer Hydrogenation ◽

Bidentate Ligands ◽

Aryl Ketones

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Synthesis and Structure of a Cationic Ruthenium(II) Complex and It's Catalytic Activity Towards Transfer Hydrogenation of Aldehydes and Ketones

SSRN Electronic Journal ◽

10.2139/ssrn.3639522 ◽

2020 ◽

Author(s):

Manish Bhattacharjee

Keyword(s):

Catalytic Activity ◽

Transfer Hydrogenation ◽

Aldehydes And Ketones

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Effect of the Para-substituent of the Tridentate Pyridine-based Ru(II) Complex upon the Catalytic Activity in Transfer Hydrogenation

Chinese Journal of Chemical Engineering ◽

10.1016/s1004-9541(09)60194-4 ◽

2011 ◽

Vol 19 (1) ◽

pp. 169-172

Author(s):

Gang YANG ◽

Dongling QING ◽

Hongfei GAO ◽

Nanping XU

Keyword(s):

Catalytic Activity ◽

Transfer Hydrogenation

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Palladium, iridium and ruthenium complexes with acyclic imino-N-heterocyclic carbenes and their application in aqua-phase Suzuki–Miyaura cross-coupling reaction and transfer hydrogenation

Dalton Transactions ◽

10.1039/c2dt31989f ◽

2012 ◽

Vol 41 (48) ◽

pp. 14557 ◽

Cited By ~ 46

Author(s):

Xu-Qing Guo ◽

Ya-Nong Wang ◽

Dong Wang ◽

Li-Hua Cai ◽

Zhen-Xia Chen ◽

...

Keyword(s):

Ruthenium Complexes ◽

Coupling Reaction ◽

Cross Coupling ◽

Heterocyclic Carbenes ◽

Transfer Hydrogenation ◽

Cross Coupling Reaction

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Constructing reactive Fe and Co complexes from isolated picolyl-functionalized N-heterocyclic carbenes

Dalton Transactions ◽

10.1039/c8dt02621a ◽

2018 ◽

Vol 47 (29) ◽

pp. 9889-9896 ◽

Cited By ~ 12

Author(s):

Qiuming Liang ◽

Nina Jiabao Liu ◽

Datong Song

Keyword(s):

Catalytic Activity ◽

Heterocyclic Carbenes

The Fe(ii) and Co(ii) complexes prepared from the isolated free carbene form of the picolyl-NHC ligands display excellent catalytic activity towards the hydrosilylation of ketones.

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