scholarly journals Diastereoselective supramolecular ion-pairing between the TRISPHAT anion and pro-chiral heptamethine cyanine dyes

2009 ◽  
Vol 7 (15) ◽  
pp. 3086 ◽  
Author(s):  
Pierre-Antoine Bouit ◽  
Christophe Aronica ◽  
Laure Guy ◽  
Alexandre Martinez ◽  
Chantal Andraud ◽  
...  
Keyword(s):  
Ion Pairing ◽  
Cyanine Dyes

scholarly journals Continuous Symmetry Breaking Induced by Ion Pairing Effect in Heptamethine Cyanine Dyes: Beyond the Cyanine Limit

2010 ◽  
Vol 132 (12) ◽  
pp. 4328-4335 ◽  
Author(s):  
Pierre-Antoine Bouit ◽  
Christophe Aronica ◽  
Loïc Toupet ◽  
Boris Le Guennic ◽  
Chantal Andraud ◽  
...  
Keyword(s):  
Symmetry Breaking ◽  
Ion Pairing ◽  
Cyanine Dyes ◽  
Continuous Symmetry ◽  
Pairing Effect

A New Method for the Synthesis of Heptamethine Cyanine Dyes:  Synthesis of New Near Infrared Fluorescent Labels

1997 ◽  
Vol 62 (26) ◽  
pp. 9387-9387 ◽  
Author(s):  
Narasimhachari Narayanan ◽  
Lucjan Strekowski ◽  
Malgorzata Lipowska ◽  
Gabor Patonay
Keyword(s):  
Near Infrared ◽  
Cyanine Dyes ◽  
New Method ◽  
Fluorescent Labels

Ion Pairing and Dielectric Decrement in Glycosaminoglycan Brushes

2020 ◽  
Author(s):  
James Sterling ◽  
Wenjuan Jiang ◽  
Wesley M. Botello-Smith ◽  
Yun L. Luo
Keyword(s):  
Molecular Dynamics ◽  
Ion Pairs ◽  
Mean Field ◽  
Salt Bridge ◽  
Ion Pairing ◽  
Donnan Potential ◽  
Mean Field Models ◽  
Ion Exclusion ◽  
Dynamics Simulations ◽  
Contact Ion Pairs

Molecular dynamics simulations of hyaluronic acid and heparin brushes are presented that show important effects of ion-pairing, water dielectric decrease, and co-ion exclusion. Results show equilibria with electroneutrality attained through screening and pairing of brush anionic charges by cations. Most surprising is the reversal of the Donnan potential that would be expected based on electrostatic Boltzmann partitioning alone. Water dielectric decrement within the brush domain is also associated with Born hydration-driven cation exclusion from the brush. We observe that the primary partition energy attracting cations to attain brush electroneutrality is the ion-pairing or salt-bridge energy associated with cation-sulfate and cation-carboxylate solvent-separated and contact ion pairs. Potassium and sodium pairing to glycosaminoglycan carboxylates and sulfates consistently show similar abundance of contact-pairing and solvent-separated pairing. In these crowded macromolecular brushes, ion-pairing, Born-hydration, and electrostatic potential energies all contribute to attain electroneutrality and should therefore contribute in mean-field models to accurately represent brush electrostatics.

Synthesis, photosensitization and antimicrobial activity evaluation of some novel Merocyanine dyes

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Escherichia Coli ◽  
Staphylococcus Aureus ◽  
Antimicrobial Activity ◽  
Aspergillus Flavus ◽  
Elemental Analysis ◽  
Cyanine Dyes ◽  
Fungal Strains ◽  
Activity Evaluation ◽  
Visible Spectra ◽  
Merocyanine Dyes

Novel acyclic and cyclic merocyanine dyes derived from the nucleu of furo [(3,2-d) pyrazole; ( d 2 , 3 )imidazole]were prepared. The electronic visible absorptionspectra of all the synthesized new cyanine dyes were examined in 95% ethanolsolution to evaluate their photosensitization properties. Antibacterial andantifungal activities for some selected dyes were tested against various bacterialand fungal strains (Escherichia coli, Staphylococcus aureus, Aspergillus flavus andCandida albicans) to evaluate their antimicrobial activity. Structural identificationwas carried out via elemental analysis, visible spectra, IR and 1H NMRspectroscopic data.

Synthesis and in vitro evaluation of the antitumoral phototherapeutic potential of squaraine cyanine dyes derived from indolenine

2019 ◽  
Vol 167 ◽  
pp. 98-108 ◽  
Author(s):  
Eurico Lima ◽  
Octávio Ferreira ◽  
Vanessa S.D. Gomes ◽  
Adriana O. Santos ◽  
Renato E. Boto ◽  
...  
Keyword(s):  
Cyanine Dyes ◽  
In Vitro Evaluation

ChemInform Abstract: Cyanine Dyes (VI), (VII), (IX), (XI), (XIII), (XV) from 4-Methyl-6-hydroxyquinoline (I).

ChemInform ◽  
1988 ◽  
Vol 19 (43) ◽  
Author(s):  
I. L. MUSHKALO ◽  
O. A. IL'CHENKO ◽  
A. I. TOLMACHEV ◽  
B. M. GUTSULYAK
Keyword(s):  
Cyanine Dyes

Photoisomerization-induced patterning of ion-pairing materials based on anionic azobenzene and its complex with a fluorescent π-electronic system

2021 ◽  
Vol 57 (35) ◽  
pp. 4287-4290
Author(s):  
Ryohei Yamakado ◽  
Issei Kitamura ◽  
Mitsuo Hara ◽  
Shusaku Nagano ◽  
Takahiro Seki ◽  
...  
Keyword(s):  
Surface Tension ◽  
Mass Transport ◽  
Trace Amount ◽  
Ion Pairs ◽  
Ion Pairing ◽  
Electronic System ◽  
Large Mass ◽  
System P ◽  
The Difference

Large mass transport driven by the difference in the photoisomerization-induced surface tension was demonstrated in ion pairs, enabling fluorescence patterning using a trace amount of photoisomerized anions in complexation with a π-electronic system.

Pyrrole-bridged quinones: π-electronic systems that modulate electronic structures by tautomerism and deprotonation

2021 ◽  
Author(s):  
Shinya Sugiura ◽  
Hiromitsu Maeda
Keyword(s):  
Infrared Absorption ◽  
Electronic Structures ◽  
Near Infrared ◽  
Ion Pairing ◽  
Anion Binding ◽  
Electronic Systems

A new series of π-extended quinone derivatives containing a pyrrole bridge exhibited NH/OH-type tautomerization and anion binding along with deprotonation that induced near-infrared absorption and ion-pairing assemblies.

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