Gold single-crystal electrode surface modified with self-assembled monolayers for electron tunneling with bilirubin oxidase

2008 ◽  
Vol 10 (46) ◽  
pp. 6928 ◽  
Author(s):  
Masato Tominaga ◽  
Mai Ohtani ◽  
Isao Taniguchi
Keyword(s):  
Single Crystal ◽  
Electrode Surface ◽  
Electron Tunneling ◽  
Self Assembled Monolayers ◽  
Bilirubin Oxidase ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Single Crystal Electrode ◽  
Surface Modified

Coupling to Lysine-13 Promotes Electron Tunneling through Carboxylate-Terminated Alkanethiol Self-Assembled Monolayers to Cytochromec

2003 ◽  
Vol 107 (37) ◽  
pp. 9947-9949 ◽  
Author(s):  
Katsumi Niki ◽  
W. Reef Hardy ◽  
Michael G. Hill ◽  
H. Li ◽  
James R. Sprinkle ◽  
...  
Keyword(s):  
Electron Tunneling ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

scholarly journals Electron tunneling through alkanedithiol self-assembled monolayers in large-area molecular junctions

2007 ◽  
Vol 104 (27) ◽  
pp. 11161-11166 ◽  
Author(s):  
H. B. Akkerman ◽  
R. C. G. Naber ◽  
B. Jongbloed ◽  
P. A. van Hal ◽  
P. W. M. Blom ◽  
...  
Keyword(s):  
Electron Tunneling ◽  
Molecular Junctions ◽  
Self Assembled Monolayers ◽  
Large Area ◽  
Assembled Monolayers ◽  
Self Assembled

scholarly journals Effects of Polarized Organosilane Self-Assembled Monolayers on Organic Single-Crystal Field-Effect Transistors

2005 ◽  
Vol 871 ◽  
Author(s):  
J. Takey ◽  
T. Nishikaw ◽  
T. Takenobu ◽  
H. Shimotani ◽  
S. Kobayashi ◽  
...  
Keyword(s):  
Single Crystal ◽  
Crystal Field ◽  
Field Effect ◽  
Field Effect Transistors ◽  
Self Assembled Monolayers ◽  
Crystal Field Effect ◽  
Organic Single Crystal ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Circuit Components

AbstractOrganosilane self-assembled monolayers, embedded in organic single-crystal field-effect transistors, significantly affect subthreshold properties in the transfer characteristics. The monolayer of either polarized or nearly unpolarized molecules is deposited on a SiO2/doped Si substrate before softly attaching a rubrene thin single crystal to form the “laminated crystal” transistors. As a result of effective passivation of the SiO2 surface, the device has achieved a subthreshold swing as low as 0.11 V/decade. It is also demonstrated that threshold gate voltage is shifted by polarization of the monolayers, indicating that threshold of the device is adjustable by the choice of silane materials. Both of the functions are closely associated with low-power applications such as logic-circuit components.

scholarly journals Corrosion Protection of AA7075 Aluminium Alloy by Trimethoxy-Silanes Self-Assembled Monolayers

2013 ◽  
Vol 2013 ◽  
pp. 1-9 ◽  
Author(s):  
Rodrigo S. Neves ◽  
Daiane P. B. Silva ◽  
Artur J. Motheo
Keyword(s):  
Aluminium Alloy ◽  
Electrochemical Impedance ◽  
Protective Coatings ◽  
Reduction Reaction ◽  
Self Assembled Monolayers ◽  
Organic Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Surface Modified ◽  
Trimethoxy Silane

This study presents electrochemical data concerning the aluminium alloy AA7075 surface modified by self-assembled monolayers (SAMs) of octadecyl-trimethoxy-silane and propyl-trimethoxy-silane. Polarisation curves have shown SAMs blocking effect, as they partially block the oxygen reduction reaction and displace the corrosion potential to positive values. Electrochemical impedance spectroscopy experiments have suggested that the protective effect comes from the oxide layer stabilization by the organic monolayers, which block the corroding species diffusion to the surface. These results show the potential of using methoxy-silanes SAMs as corrosion protective coatings; however, they are also indicative of the superior octadecyl-trimethoxy-silane protective characteristics.

Cross-platform characterization of electron tunneling in molecular self-assembled monolayers

2005 ◽  
Vol 5 (3) ◽  
pp. 213-217 ◽  
Author(s):  
Takhee Lee ◽  
Wenyong Wang ◽  
J.J. Zhang ◽  
J. Su ◽  
J.F. Klemic ◽  
...  
Keyword(s):  
Electron Tunneling ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Cross Platform ◽  
Self Assembled
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