Unusual face-to-face π–π stacking interactions within an indigo-pillared M3(tpt)-based triangular metalloprism

2008 ◽  
pp. 6110 ◽  
Author(s):  
Jing-Yun Wu ◽  
Che-Hao Chang ◽  
P. Thanasekaran ◽  
Chen-Chuan Tsai ◽  
Tien-Wen Tseng ◽  
...  
Keyword(s):  
Stacking Interactions ◽  
Face To Face ◽  
Π Stacking

Synthesis and crystal structure of a novel prochiral ketoimine: (E)-acetophenoneO-diphenylphosphoryl oxime

2015 ◽  
Vol 71 (3) ◽  
pp. 181-184
Author(s):  
Sean H. Majer ◽  
Joseph M. Tanski
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Stacking Interactions ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Face To Face ◽  
Π Stacking

A novel activated prochiral ketoimine, (E)-acetophenoneO-diphenylphosphoryl oxime, C20H18NO2P, with an electron-withdrawing substituent on the imine N atom similar to other prochiral ketoimines, has been synthesized and the X-ray crystal stucture determined. The molecules pack together in the solid stateviaweak intermolecular C—H...O interactions and both face-to-face and edge-to-face π-stacking interactions.

Unexpected Substituent Effects in Face-to-Face π-Stacking Interactions

2003 ◽  
Vol 107 (41) ◽  
pp. 8377-8379 ◽  
Author(s):  
Mutasem Omar Sinnokrot ◽  
C. David Sherrill
Keyword(s):  
Substituent Effects ◽  
Stacking Interactions ◽  
Face To Face ◽  
Π Stacking

Formation of dimers of inclusion cryptand/paraquat complexes driven by dipole–dipole and face-to-face π-stacking interactions

2004 ◽  
pp. 2670-2671 ◽  
Author(s):  
Feihe Huang ◽  
Liang Zhou ◽  
Jason W. Jones ◽  
Harry W. Gibson ◽  
Mehdi Ashraf-Khorassani
Keyword(s):  
Stacking Interactions ◽  
Face To Face ◽  
Π Stacking

The engineering of stilbazolium/iodocuprate hybrids with optical/electrical performances by modulating inter-molecular charge transfer among H-aggregated chromophores

2020 ◽  
Vol 7 (6) ◽  
pp. 1451-1466 ◽  
Author(s):  
Wei Wu ◽  
Xiang-Ling Lin ◽  
Qian Liu ◽  
Yan He ◽  
You-Ren Huang ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Stacking Interactions ◽  
Face To Face ◽  
Electrical Bistability ◽  
Π Stacking ◽  
Molecular Charge

Good electrical bistability performances in stilbazolium/iodocuprate hybrids stem from the better face-to-face π⋯π stacking interactions induced by the substituents with appropriate lengths and electronic natures.

Long-Living Emitting Electrochemical Cells Based on Supramolecular π-π Interactions

2009 ◽  
Vol 1197 ◽  
Author(s):  
Rubén D. Costa ◽  
Enrique Ortí ◽  
Stefan Graber ◽  
Markus Neuburger ◽  
Catherine E. Hausecroft ◽  
...  
Keyword(s):  
Electrochemical Cells ◽  
Stacking Interactions ◽  
Light Emitting ◽  
Stacking Interaction ◽  
Face To Face ◽  
Π Interactions ◽  
Π Stacking ◽  
Π Stacking Interaction

AbstractThe complex [Ir(ppy)2(dpbpy)][PF6] (Hppy = 2-phenylpyridine, dpbpy = 6,6'-diphenyl-2,2'-bipyridine) has been prepared and evaluated as an electroluminescent component for light-emitting electrochemical cells (LECs). The complex exhibits two intramolecular face-to-face π-stacking interactions and long-lived LECs have been constructed; the device characteristics are not significantly improved in comparison to analogous LECs with 6-phenyl-2,2'-bipyridine with only one π-stacking interaction.

scholarly journals 2-(5-Fluoro-1-methyl-2-oxoindolin-3-ylidene)-N-[4-(methylsulfanyl)phenyl]hydrazine-1-carbothioamide

IUCrData ◽  
2017 ◽  
Vol 2 (5) ◽  
Author(s):  
Zeliha Atioğlu ◽  
Zekiye Şeyma Sevinçli ◽  
Nilgün Karalı ◽  
Mehmet Akkurt ◽  
Cem Cüneyt Ersanlı
Keyword(s):  
Hydrogen Bonds ◽  
Stacking Interactions ◽  
Phenyl Hydrazine ◽  
Face To Face ◽  
Planar Conformation ◽  
Π Stacking ◽  
Plane Face ◽  
Title Molecule

The title molecule, C17H15FN4OS2, obtained from 5-fluoro-1-methyl-1H-indol-2,3-dione, and 3-[4-(methylsulfanyl)phenyl]thiosemicarbazide, has an essentially planar conformation (r.m.s deviation for all non-H atoms = 0.116 Å). Intramolecular N—H...N and N—H...O hydrogen bonds generateS(5) andS(6) ring motifs, respectively. In the crystal, C—H...S hydrogen bonds occur between layers of molecules parallel to the (10-1) plane. Face-to-face π–π stacking interactions are also observed.

scholarly journals Crystal structure of (2,11-diaza[3.3](2,6)pyridinophane-κ4N,N′,N′′,N′′′)(1,6,7,12-tetraazaperylene-κ2N1,N12)ruthenium(II) bis(hexafluoridophosphate) acetonitrile 1.422-solvate

2014 ◽  
Vol 70 (10) ◽  
pp. 265-268 ◽  
Author(s):  
Thomas Brietzke ◽  
Falko Otto Rottke ◽  
Alexandra Kelling ◽  
Uwe Schilde ◽  
Hans-Jürgen Holdt
Keyword(s):  
Complex Cation ◽  
Three Dimensional ◽  
Distorted Octahedral Geometry ◽  
Stacking Interactions ◽  
Acetonitrile Molecule ◽  
Face To Face ◽  
Π Stacking ◽  
Centroid Distance ◽  
Distorted Octahedral ◽  
Solvent Molecules

In the title compound, [Ru(C14H16N4)(C16H8N4)](PF6)2·1.422CH3CN, discrete dimers of complex cations, [Ru(L–N4H2)tape]2+are formed {L–N4H2= 2,11-diaza[3.3](2,6)pyridinophane; tape = 1,6,7,12-tetraazaperylene}, held together by π–π stacking interactionsviathe tape ligand moieties with a centroid–centroid distance of 3.49 (2) Å, assisted by hydrogen bonds between the non-coordinating tape ligand α,α′-diimine unit and the amine proton of a 2,11-diaza[3.3](2,6)-pyridinophane ligand of the opposite complex cation. The combination of these interactions leads to an unusual nearly face-to-face π–π stacking mode. Additional weak C—H...N, C—H...F, N—H...F and P—F...π-ring (tape, py) (with F...centroid distances of 2.925–3.984 Å) interactions are found, leading to a three-dimensional architecture. The RuIIatom is coordinated in a distorted octahedral geometry, particularly manifested by the Namine—Ru—Namineangle of 153.79 (10)°. The counter-charge is provided by two hexafluoridophosphate anions and the asymmetric unit is completed by acetonitrile solvent molecules of crystallization. Disorder was observed for both the hexafluoridophosphate anions as well as the acetonitrile solvate molecules, with occupancies for the major moieties of 0.801 (6) for one of the PF6anions, and a shared occupancy of 0.9215 (17) for the second PF6anion and a partially occupied acetonitrile molecule. A second CH3CN molecule is fully occupied, but 1:1 disordered across a crystallographic inversion center.

scholarly journals Diiodido[methyl 2-(quinolin-8-yloxy)acetate-κN]mercury(II)

2012 ◽  
Vol 68 (8) ◽  
pp. m1057-m1057
Author(s):  
Yu-Hong Wang ◽  
Qin Zhong ◽  
Rui-Feng Song
Keyword(s):  
Coordination Sphere ◽  
Mononuclear Complex ◽  
Stacking Interactions ◽  
Crystal Face ◽  
Face To Face ◽  
Acetate Ligand ◽  
Π Stacking ◽  
Centroid Distance

In the title mononuclear complex, [HgI2(C12H11NO3)], the HgIIion has a distorted trigonal–planar coordination sphere defined by two I−anions and the N atom of a methyl 2-(quinolin-8-yloxy)acetate ligand. In the crystal, face-to-face π–π stacking interactions, with a centroid–centroid distance of 3.563 (9) Å, are observed.

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