scholarly journals Three-dimensional AlN microroses and their enhanced photoluminescence properties

2008 ◽  
pp. 5221 ◽  
Author(s):  
Weiwei Lei ◽  
Jian Zhang ◽  
Dan Liu ◽  
Pinwen Zhu ◽  
Qiliang Cui ◽  
...  
2015 ◽  
Vol 98 (5) ◽  
pp. 1562-1566 ◽  
Author(s):  
Jun Li ◽  
Zhengwen Yang ◽  
Bo Shao ◽  
Jiayan Liao ◽  
Shenfeng Lai ◽  
...  

2008 ◽  
Vol 18 (30) ◽  
pp. 3543 ◽  
Author(s):  
Xianfeng Yang ◽  
Ian D. Williams ◽  
Jian Chen ◽  
Jing Wang ◽  
Huifang Xu ◽  
...  

2013 ◽  
Vol 684 ◽  
pp. 274-278
Author(s):  
Huang Yu Chen ◽  
Ru Yuan Yang ◽  
Shoou Jinn Chang

A Eu3+ activated YInGe2O7phosphor was synthesized by solid-state reaction and lithium carbonate was added to change the morphology and photoluminescence properties. Scanning electron microscopy showed large particle size and necking shape were obtained as the concentrations of Li+ ions increase. In the PL studies, the excitation spectrum of YInGe2O7:Eu3+ phosphors exhibited a broad band in the UV region centered at about 272 nm attributed to charge transfer state (CTS) band, which has a little shift after Li+ ion was added. As the Li+ ion concentration increased, the photoluminescence intensity of the red emission at 620 nm of Eu3+ ions was enhanced, and the optimized concentration of of added Li+ ion is 0.05. The results showed that addition of Li+ ion allows YInGe2O7:Eu3+ phosphors emitting relatively pure red light.


2006 ◽  
Vol 18 (3) ◽  
pp. 367-370 ◽  
Author(s):  
H.-C. Chen ◽  
C.-W. Wang ◽  
S.-W. Lee ◽  
L.-J. Chen

Author(s):  
Dan Zhao ◽  
Yanyan An ◽  
Tingting Guo ◽  
Juanzhi Yan ◽  
Danmei Song

Hydrothermal reaction of Mn2+ with the ditopic ligand 2,5-bis(1H-1,2,4-triazol-1-yl)benzoic acid (Hdtba) resulted in the complex poly[aqua[μ3-2,5-bis(1H-1,2,4-triazol-1-yl)benzoato-κ3 N 4:N 4′:O]chloridomanganese(II)] monohydrate], {[Mn(C11H7N6O2)Cl(H2O)]·H2O} n , (I). Coordination polymer I has been characterized by X-ray diffraction, IR spectroscopy, elemental analysis, thermogravimetry and susceptibility measurements. The topology of I corresponds to a three-dimensional (3,6)-conn net linked by {Mn2Cl2(COO)2} building blocks and dtba− anions. Significant antiferromagnetic exchange is observed within the dinuclear {Mn2Cl2(COO)2} subunits. A fit of the susceptibility data resulted in the magnetic parameters g = 1.93 and J = −1.52. Studies of the photoluminescence properties revealed that I represents a promising luminescence sensor for sensitively detecting dichromate ions in aqueous solution. The associated photochemical detection mechanism was studied in detail.


2015 ◽  
Vol 68 (5) ◽  
pp. 742 ◽  
Author(s):  
Qing-Guo Meng ◽  
Lin-Tong Wang ◽  
Ji-Tao Lu ◽  
Xin Wang ◽  
Wei Lu ◽  
...  

Four metal–organic coordination polymers, [Cd2(dna)2(2,2′-bpy)2]n (1), {[Cd4(dna)4(im)3]·5H2O}n (2), {[Cd2(dna)2(4,4′-bpy)(H2O)2]·2EtOH}n (3), and {[Cd4(dna)4(1,3-dpp)4(H2O)4]·2H2O}n (4) (H2dna = 4,6-dimethyl-5-nitroisophthalic acid; 2,2′-bpy = 2,2′-bipyridine; im = imidazole; 4,4′-bpy = 4,4′-bipyridine; 1,3-dpp = 1,3-di(4-pyridyl)propane; and EtOH = ethanol, have been solvothermally synthesized and characterized. Compound 1 displays a one-dimensional (1D) ladder structure and the neighbouring ladders are further stabilized by π···π interactions to form a two-dimensional (2D) layer. Compound 2 forms a 2D layer based on infinite 1D [Cd2(COO)4]n chain and the im ligands act as terminal ligands, preventing expansion of the dimensionality. Compound 3 features a 2D 44-sql layer based on binuclear [Cd2(COO)4] secondary building units as 4-connected nodes, and is further linked to be an unusual three-dimensional (3D) supramolecular architecture by hydrogen bonds involving the coordinated water molecules, carboxylate groups, and lattice ethanol molecules. Compound 4 possesses a 2-fold interpenetrated dia net. The diverse structures and topologies of compounds 1–4 indicate that the N-containing ligands have significant effects on the formation of the final network structures. In addition, the thermal stabilities, structure comparison, and photoluminescence properties of the complexes have been investigated.


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