A radical-anion chain mechanism following dissociative electron transfer reduction of the model prostaglandin endoperoxide, 1,4-diphenyl-2,3-dioxabicyclo[2.2.1]heptane

2008 ◽  
Vol 6 (18) ◽  
pp. 3354 ◽  
Author(s):  
David C. Magri ◽  
Mark S. Workentin
Keyword(s):  
Electron Transfer ◽  
Radical Anion ◽  
Chain Mechanism ◽  
Dissociative Electron Transfer ◽  
Prostaglandin Endoperoxide

Efficient Homogeneous Radical-Anion Chain Reactions Initiated by Dissociative Electron Transfer to 3,3,6,6-Tetraaryl-1,2-dioxanes

2010 ◽  
Vol 16 (1) ◽  
pp. 178-188 ◽  
Author(s):  
Donald L. B. Stringle ◽  
David C. Magri ◽  
Mark S. Workentin
Keyword(s):  
Electron Transfer ◽  
Radical Anion ◽  
Dissociative Electron Transfer ◽  
Chain Reactions

Concerted double proton-transfer electron-transfer between catechol and superoxide radical anion

2017 ◽  
Vol 19 (38) ◽  
pp. 26179-26190 ◽  
Author(s):  
Jorge Quintero-Saumeth ◽  
David A. Rincón ◽  
Markus Doerr ◽  
Martha C. Daza
Keyword(s):  
Electron Transfer ◽  
Proton Transfer ◽  
Superoxide Anion ◽  
Radical Anion ◽  
Reaction Rate ◽  
Superoxide Radical ◽  
Superoxide Radical Anion ◽  
Double Proton Transfer

Catechol reacts with a superoxide anion via concerted double proton-transfer electron-transfer with a reaction rate that is dominated by tunneling.

Dual electron transfer pathways from the excited C60 radical anion: enhanced reactivities due to the photoexcitation of reaction intermediates

2015 ◽  
Vol 17 (46) ◽  
pp. 31030-31038 ◽  
Author(s):  
Mamoru Fujitsuka ◽  
Tatsuya Ohsaka ◽  
Tetsuro Majima
Keyword(s):  
Electron Transfer ◽  
Radical Anion ◽  
Reaction Intermediates ◽  
Electron Transfer Pathways

The excited C60 radical anion showed enhanced electron transfer.

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