Use of a simple surface-active initiator in controlled/living free-radical miniemulsion polymerization under AGET and ARGET ATRP conditions

2008 ◽  
pp. 4807 ◽  
Author(s):  
François Stoffelbach ◽  
Nebewia Griffete ◽  
Chuong Bui ◽  
Bernadette Charleux
Keyword(s):  
Free Radical ◽  
Miniemulsion Polymerization ◽  
Arget Atrp ◽  
Surface Active ◽  
Active Initiator ◽  
Simple Surface

Synthesis and use of a surface-active initiator in emulsion polymerization under AGET and ARGET ATRP conditions

2010 ◽  
Vol 34 (1) ◽  
pp. 163-170 ◽  
Author(s):  
Chuanjie Cheng ◽  
Jinbing Shu ◽  
Shanshan Gong ◽  
Liang Shen ◽  
Yongluo Qiao ◽  
...  
Keyword(s):  
Emulsion Polymerization ◽  
Arget Atrp ◽  
Surface Active ◽  
Active Initiator

Light induced micelle to vesicle transition in an aqueous solution of a surface active ionic liquid

RSC Advances ◽  
2015 ◽  
Vol 5 (92) ◽  
pp. 75806-75809 ◽  
Author(s):  
Shaoxiong Shi ◽  
Tianxiang Yin ◽  
Xiaoyi Tao ◽  
Weiguo Shen
Keyword(s):  
Aqueous Solution ◽  
Ionic Liquid ◽  
Surface Active Ionic Liquid ◽  
Surface Active ◽  
Simple Surface

A new simple surface active ionic liquid displayed reversible micelle–vesicle transition under alternative UV/vis irradiation without additives.

Nitroxide-mediated living free radical miniemulsion polymerization of styrene

2000 ◽  
Vol 155 (1) ◽  
pp. 1-14 ◽  
Author(s):  
T. Prodpran ◽  
V.L. Dimonie ◽  
E.D. Sudol ◽  
M.S. El-Aasser
Keyword(s):  
Free Radical ◽  
Miniemulsion Polymerization

Controlled Free-Radical Miniemulsion Polymerization of Styrene Using Degenerative Transfer

1999 ◽  
Vol 32 (22) ◽  
pp. 7354-7360 ◽  
Author(s):  
Muriel Lansalot ◽  
Céline Farcet ◽  
Bernadette Charleux ◽  
Jean-Pierre Vairon ◽  
Rosangela Pirri
Keyword(s):  
Free Radical ◽  
Miniemulsion Polymerization

Nitroxide-Mediated Living Free Radical Miniemulsion Polymerization of Styrene

2001 ◽  
Vol 34 (3) ◽  
pp. 481-488 ◽  
Author(s):  
Gaofeng Pan ◽  
E. David Sudol ◽  
Victoria L. Dimonie ◽  
Mohamed S. El-Aasser
Keyword(s):  
Free Radical ◽  
Miniemulsion Polymerization

scholarly journals Macroinitiators on the basis of new peroxide surface active monomers

2007 ◽  
Vol 1 (2) ◽  
pp. 83-86
Author(s):  
Ananiy Kohut ◽  
◽  
Roman Fleychuk ◽  
Orest Hevus ◽  
Stanislav Voronov ◽  
...  
Keyword(s):  
High Temperature ◽  
Free Radical ◽  
Surface Active Properties ◽  
Surface Active ◽  
Alkyl Peroxide

The surface active properties of new peroxide maleic monomers were investigated. The regularities of their copolymerization with styrene were studied. Peroxide polymers containing ditertiary alkyl peroxide groups in side substituents of backbone as the prospective high-temperature free radical macroinitiators were synthesized.

Stable free radical miniemulsion polymerization

2000 ◽  
Vol 155 (1) ◽  
pp. 31-38 ◽  
Author(s):  
Paula J. MacLeod ◽  
Richard Barber ◽  
Peter G. Odell ◽  
Barkev Keoshkerian ◽  
Michael K. Georges
Keyword(s):  
Free Radical ◽  
Miniemulsion Polymerization ◽  
Stable Free Radical

Surfactant Concentration Effects on Nitroxide-Mediated Living Free Radical Miniemulsion Polymerization of Styrene

2002 ◽  
Vol 35 (18) ◽  
pp. 6915-6919 ◽  
Author(s):  
Gaofeng Pan ◽  
E. David Sudol ◽  
Victoria L. Dimonie ◽  
Mohamed S. El-Aasser
Keyword(s):  
Free Radical ◽  
Surfactant Concentration ◽  
Miniemulsion Polymerization ◽  
Concentration Effects

Reversible Addition–Fragmentation Chain Transfer (RAFT) Polymerization in Miniemulsion Based on In Situ Surfactant Generation

2011 ◽  
Vol 64 (8) ◽  
pp. 1033 ◽  
Author(s):  
S. R. Simon Ting ◽  
Eun Hee Min ◽  
Per B. Zetterlund
Keyword(s):  
Potassium Hydroxide ◽  
Colloidal Stability ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Miniemulsion Polymerization ◽  
High Energy ◽  
Reversible Addition ◽  
Raft Agent ◽  
Surface Active

Reversible addition–fragmentation chain transfer (RAFT) polymerization of styrene has been implemented in aqueous miniemulsion based on the in situ surfactant generation approach using oleic acid and potassium hydroxide in the absence of high energy mixing. The best results were obtained using the RAFT agent 3-benzylsulfanyl thiocarbonyl sufanylpropionic acid (BSPAC), most likely as a result of the presence of a carboxylic acid functionality in the RAFT agent that renders it surface active and thus imparts increased colloidal stability. Stable final miniemulsions were obtained with no coagulum with particle diameters less than 200 nm. The results demonstrate that the RAFT miniemulsion polymerization of styrene employing the low energy in situ surfactant method is challenging, but that a system that proceeds predominantly by a miniemulsion mechanism can be achieved under carefully selected conditions.

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