scholarly journals Kinetics and solvent effects in the synthesis of ionic liquids: imidazolium

2009 ◽  
Vol 11 (5) ◽  
pp. 694 ◽  
Author(s):  
Jay C. Schleicher ◽  
Aaron M. Scurto
Keyword(s):  
Ionic Liquids ◽  
Solvent Effects

Deactivation of the Cobalt Catalyst for the Cyclotrimerization of Acetylenes in Ionic Liquids: Solvent Effects on the Mechanism and Thermal and Pressure Activation Parameters

2011 ◽  
Vol 30 (15) ◽  
pp. 3919-3922 ◽  
Author(s):  
Teresa Avilés ◽  
Susanna Jansat ◽  
Manuel Martínez ◽  
Francisco Montilla ◽  
Carlos Rodríguez
Keyword(s):  
Ionic Liquids ◽  
Solvent Effects ◽  
Cobalt Catalyst ◽  
Activation Parameters

Solvent effects of ionic liquids: investigation of ferrocenes as electrochemical probes

2010 ◽  
Vol 24 (4) ◽  
pp. 327-334 ◽  
Author(s):  
Claudia Bizzarri ◽  
Valeria Conte ◽  
Barbara Floris ◽  
Pierluca Galloni
Keyword(s):  
Ionic Liquids ◽  
Solvent Effects

Co-solvent effects for aromatic extraction with ionic liquids

2013 ◽  
Vol 180 ◽  
pp. 145-153 ◽  
Author(s):  
C.V. Manohar ◽  
Tamal Banerjee ◽  
Kaustubha Mohanty
Keyword(s):  
Ionic Liquids ◽  
Solvent Effects

Solvent effects in ionic liquids: empirical linear energy–density relationships

2012 ◽  
Vol 14 (28) ◽  
pp. 10041 ◽  
Author(s):  
A. Cerda-Monje ◽  
A. Aizman ◽  
R. A. Tapia ◽  
C. Chiappe ◽  
R. Contreras
Keyword(s):  
Ionic Liquids ◽  
Energy Density ◽  
Solvent Effects

Ionic liquid solvents: the importance of microscopic interactions in predicting organic reaction outcomes

2017 ◽  
Vol 89 (6) ◽  
pp. 745-757 ◽  
Author(s):  
Sinead T. Keaveney ◽  
Ronald S. Haines ◽  
Jason B. Harper
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Transition State ◽  
Physical Properties ◽  
Solvent Effects ◽  
Recent Progress ◽  
Comprehensive Understanding ◽  
Organic Reaction ◽  
Microscopic Interactions ◽  
Molecular Solvents

AbstractIonic liquids are attractive alternatives to molecular solvents as they have many favourable physical properties and can produce different organic reaction outcomes compared to molecular solvents. Thus far, interactions between the ionic liquid components and specific sites (such as charged centres, lone pairs and π systems) on the reagents and transition state have been identified as affecting reaction outcome; a comprehensive understanding of these interactions is necessary to allow prediction of ionic liquid solvent effects. This manuscript summarises our recent progress in the development of a framework for predicting the effect of an ionic liquid solvent on the outcome of organic processes. There will be a particular focus on the importance of the different interactions between the ionic liquid components and the species along the reaction coordinate that are responsible for the changes in reaction outcome observed in the cases described.

Understanding the effects of solvate ionic liquids as solvents on substitution processes

2019 ◽  
Vol 17 (41) ◽  
pp. 9243-9250 ◽  
Author(s):  
Karin S. Schaffarczyk McHale ◽  
Michaela J. Wong ◽  
Alicia K. Evans ◽  
Alyssa Gilbert ◽  
Ronald S. Haines ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Solvent Effects ◽  
Benzyl Bromide

The solvent effects of solvate ionic liquids have been compared to the effects of previously studied ‘typical’ ionic liquids for the SN2 reaction between pyridine and benzyl bromide and the SNAr reaction between ethanol and 1-fluoro-2,4-dinitrobenzene.

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