An oximate-based hexanuclear mixed-valence MnIII4MnII2 edge-sharing bitetrahedral core with an St = 5 spin ground state

2008 ◽  
pp. 4885 ◽  
Author(s):  
Sumit Khanra ◽  
Thomas Weyhermüller ◽  
Phalguni Chaudhuri
Keyword(s):  
Ground State ◽  
Mixed Valence ◽  
Spin Ground State

A molecular ferromagnet with Tc = 3.3 K and an high spin ground state in trinuclear oxo-centred mixed-valence carboxylates

Polyhedron ◽  
1996 ◽  
Vol 15 (5-6) ◽  
pp. 1041-1044 ◽  
Author(s):  
Zhang Shi-Wei ◽  
Wei Yong-Ge ◽  
Liu Qun ◽  
Shao Mei-Cheng ◽  
Zhou Wen-Sheng
Keyword(s):  
High Spin ◽  
Ground State ◽  
Mixed Valence ◽  
Spin Ground State

A Mixed-Valence [MnIIMnIIIMnII] Complex of a Linear Phenol-bis(pyrazole) Ligand with anS= 3 Spin Ground State

2008 ◽  
Vol 2008 (24) ◽  
pp. 3871-3876 ◽  
Author(s):  
Leoní A. Barrios ◽  
Guillem Aromí ◽  
Joan Ribas ◽  
Jorge Salinas Uber ◽  
Olivier Roubeau ◽  
...  
Keyword(s):  
Ground State ◽  
Mixed Valence ◽  
Spin Ground State

scholarly journals Inversion of donor–acceptor roles in photoinduced intervalence charge transfers

2019 ◽  
Vol 55 (53) ◽  
pp. 7659-7662 ◽  
Author(s):  
Bruno M. Aramburu-Trošelj ◽  
Paola S. Oviedo ◽  
Ivana Ramírez-Wierzbicki ◽  
Luis M. Baraldo ◽  
Alejandro Cadranel
Keyword(s):  
Electron Donor ◽  
Electron Acceptor ◽  
Ground State ◽  
Mixed Valence ◽  
Donor Acceptor

Upon MLCT photoexcitation, {(tpy)Ru} becomes the electron acceptor in the mixed valence {(tpy˙−)RuIII−δ-NC-MII+δ} moiety, reversing its role as the electron donor in the ground-state mixed valence analogue.

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