Rhenium complexes of chromophore-appended dipicolylamine ligands: syntheses, spectroscopic properties, DNA binding and X-ray crystal structure

2008 ◽  
Vol 32 (12) ◽  
pp. 2140 ◽  
Author(s):  
Lucy A. Mullice ◽  
Rebecca H. Laye ◽  
Lindsay P. Harding ◽  
Niklaas J. Buurma ◽  
Simon J. A. Pope
Keyword(s):  
Crystal Structure ◽  
Dna Binding ◽  
Spectroscopic Properties ◽  
Rhenium Complexes ◽  
X Ray

Systhesis, Characterization and Spectroscopic Properties of (2E,6E)-2,6-Bis(2,3,4-tri-methoxy-benzylidene)cyclohexanone

2011 ◽  
Vol 396-398 ◽  
pp. 2338-2341
Author(s):  
Xing Chuan Wei ◽  
Zhi Li Liu ◽  
Kun Zhang ◽  
Zhi Yun Du ◽  
Xi Zheng
Keyword(s):  
Crystal Structure ◽  
Acetic Acid ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Spectroscopic Properties ◽  
Spectral Studies ◽  
Double Bonds ◽  
X Ray ◽  
Π Interactions ◽  
X Ray Crystallography

In this paper, (2E,6E)-2,6-Bis(2,3,4-tri-methoxy -benzylidene)cyclohexanone (omitted as tmbcho) (1) was obtained by the reaction of acetic acid, tetrahydrofuran, cyclohexanone and 2,3,4-tri-methoxy-benzaldehyde. Three non-classic hydrogen bonds were observed in the compound. X-ray crystallography shows that the crystal structure is stabilized by intermolecular C-H•••π interactions and it contains plenty of conjugated double bonds. The title compound was characterized by UV-vis and fluorescent spectral studies.

Monoolefincobalt(0)-Komplexe / Monoolefincobalt(0) Complexes

1988 ◽  
Vol 43 (10) ◽  
pp. 1256-1262 ◽  
Author(s):  
Hans-Friedrich Klein ◽  
Goetz Lull ◽  
Birgit Rodenhäuser ◽  
Gerhard Cordier ◽  
Helmut Paulus
Keyword(s):  
Crystal Structure ◽  
Carbon Monoxide ◽  
Valence State ◽  
Cobalt Atom ◽  
Spectroscopic Properties ◽  
X Ray ◽  
Mononuclear Cobalt ◽  
Structure Determinations

Mononuclear cobalt(o) complexes containing olefin and trimethylphosphane ligands Co(olefin)(PMe3)3 (olefin = C2H4 (1), C3H6 (2), cyclopentene (3), trans-1,2-diphenylethene (4), tetrafluorobenzo-bicyclo-(2.2.2)-octadiene (5)), are obtained from CoCl2 by reaction with magnesium in the presence of the ligands or by substitution of 3 with olefin. X-ray crystal structure determinations of 4 and 5 show a distorted tetrahedral arrangement of ligands around the cobalt atom. Chemical and spectroscopic properties are consistent with a paramagnetic valence state of the compounds in solution. By reaction with carbon monoxide a dicobalt complex is formed, while azobenzene gives paramagnetic Co(N2Ph2)(PMe3)2.

Diolefincobalt(0)-Komplexe / Diolefincobalt(0) Complexes

1984 ◽  
Vol 39 (5) ◽  
pp. 643-648 ◽  
Author(s):  
Hans-Friedrich Klein ◽  
Joachim Groß ◽  
Hubert Witty ◽  
Dietmar Neugebauer
Keyword(s):  
Crystal Structure ◽  
Structure Determination ◽  
Valence State ◽  
Cobalt Atom ◽  
Spectroscopic Properties ◽  
Dinuclear Complex ◽  
X Ray ◽  
Linear Dimer ◽  
Mononuclear Cobalt

Mononuclear cobalt(0) complexes containing diolefin and trimethylphosphane ligands Co(cycloocta-1,5-diene)(PMe3)2 and Co[(CH2=CHMe2Si)2O](PMe3)2 are obtained from CoCl2 by reaction with magnesium in the presence of the ligands or by substitution of cobalt(olefin)tris- (trimethylphosphane) with diolefin. Chemical and spectroscopic properties confirm the para- magnetic valence state of the compounds in solution. An X-Ray crystal structure determination of Co[(CH2=CHMe2Si)2O](PMe3)2 shows a tetrahedral arrangement of ligand functions around the cobalt atom. With butadiene a diamagnetic dinuclear complex [Co(C4H6)(PMe3)3]2 is obtained containing π-allyl co-ordination of two Co(PMe3)3 units to a linear dimer of butadiene

Darstellung und Struktur einiger η5 -Cyclopentadienyldicarbonyleisenbismut-Verbindungen Cp(CO)2 FeBiX2 mit fünffach koordiniertem Bismutatom/Synthesis and Structure of Some η5 -Cyclopentadienyldicarbonylironbismuth Compounds Cp(CO)2 FeBiX2 with Five-Coordinated Bismuth Atoms

1985 ◽  
Vol 40 (2) ◽  
pp. 258-262 ◽  
Author(s):  
Markus Wieber ◽  
Dieter Wirth ◽  
Christian Burschka
Keyword(s):  
Crystal Structure ◽  
Spectroscopic Properties ◽  
X Ray

Abstract The synthesis and the spectroscopic properties of the title compounds Cp(CO)2FeBiX2 (with X = SC(S)NEt 2 and SC(S)OMe) are described. The crystal structure of Cp(CO)2FeBi[SC(S)NEt2]2 was investigated by an X-ray analysis.

Synthesis, X-Ray Crystal Structure and Spectroscopic Properties of 1,2,3,4-Tetrahydro-2-(thenyl)-3-(N-thenylidine)-4-oxoquinazoline

2011 ◽  
Vol 41 (7) ◽  
pp. 986-990 ◽  
Author(s):  
Sumita Naskar ◽  
Subhendu Naskar ◽  
Alexander J. Blake ◽  
Haregewine Tadesse ◽  
Shyamal Kumar Chattopadhyay
Keyword(s):  
Crystal Structure ◽  
Spectroscopic Properties ◽  
X Ray
Sign in / Sign up

Export Citation Format

Share Document