Gold–platinum bimetallic clusters for aerobic oxidation of alcohols under ambient conditions

2008 ◽  
pp. 2031 ◽  
Author(s):  
Hiroyuki Miyamura ◽  
Ryosuke Matsubara ◽  
Shū Kobayashi
Keyword(s):  
Aerobic Oxidation ◽  
Bimetallic Clusters ◽  
Ambient Conditions ◽  
Oxidation Of Alcohols ◽  
Gold Platinum

scholarly journals A Bio-Inspired Lanthanum-Ortho Quinone Catalyst for Aerobic Oxidation of Alcohol

2020 ◽  
Author(s):  
Ruipu Zhang ◽  
Long Zhang ◽  
Ming-Tian Zhang ◽  
Sanzhong Luo
Keyword(s):  
Aerobic Oxidation ◽  
Earth Metal ◽  
Open Shell ◽  
Oxidation Catalysis ◽  
Oxidation Catalyst ◽  
Oxidation Reactions ◽  
Reductive Activation ◽  
Ambient Conditions ◽  
Semiquinone Radicals ◽  
Oxidation Of Alcohols

<p>Oxidation reactions are fundamental transformations in organic synthesis and chemical industry. With oxygen or air as terminal oxidant, aerobic oxidation catalysis provides the most sustainable and economic oxidation processes. Most aerobic oxidation catalysis employs redox metal as its active center. While nature provides non-redox metal strategy as in pyrroloquinoline quinone (PQQ)-dependent methanol dehydrogenases (MDH), such an effective chemical version is unknown. Inspired by the recently discovered rare earth metal-dependent enzyme Ln-MDH, here we show that an open-shell semi-quinone anionic radical species in complexing with lanthanum could serve as a very efficient aerobic oxidation catalyst under ambient conditions. In this catalyst, the lanthanum metal serves only as a Lewis acid promoter and the redox process occurs exclusively on the semiquinone ligand. The catalysis is initiated by 1e<sup>-</sup>-reduction of lanthanum-activated <i>ortho</i>-quinone to a semiquinone-lanthanum complex La(<b>SQ<sup>-.</sup></b>)<sub>2</sub>, which undergoes a coupled O-H/C-H dehydrogenation for aerobic oxidation of alcohols with up to 330 h<sup>-1</sup> TOF. This study suggests a possible functional mode of semiquinone radicals, widely observed with quinoproteins in Nature. Moreover, this unique reductive activation strategy as well as the resulted radical anion as redox ligand creates a new turning point in the development of efficient aerobic oxidation catalysis.</p>

A facile and efficient synthesis of polystyrene/gold–platinum composite particles and their application for aerobic oxidation of alcohols in water

2015 ◽  
Vol 51 (36) ◽  
pp. 7721-7724 ◽  
Author(s):  
Yunxing Li ◽  
Yan Gao ◽  
Cheng Yang
Keyword(s):  
Catalytic Activity ◽  
Aerobic Oxidation ◽  
Composite Particles ◽  
High Catalytic Activity ◽  
Efficient Synthesis ◽  
Mild Conditions ◽  
Oxidation Of Alcohols ◽  
Effective Synthesis ◽  
Gold Platinum

Herein a facile and effective synthesis of the polystyrene/gold–platinum composite particles with high catalytic activity and good recyclability for aerobic oxidation of 1-phenylethanol under mild conditions is reported.

scholarly journals A Bio-Inspired Lanthanum-Ortho Quinone Catalyst for Aerobic Oxidation of Alcohol

2020 ◽  
Author(s):  
Ruipu Zhang ◽  
Long Zhang ◽  
Ming-Tian Zhang ◽  
Sanzhong Luo
Keyword(s):  
Aerobic Oxidation ◽  
Earth Metal ◽  
Open Shell ◽  
Oxidation Catalysis ◽  
Oxidation Catalyst ◽  
Oxidation Reactions ◽  
Reductive Activation ◽  
Ambient Conditions ◽  
Semiquinone Radicals ◽  
Oxidation Of Alcohols

<p>Oxidation reactions are fundamental transformations in organic synthesis and chemical industry. With oxygen or air as terminal oxidant, aerobic oxidation catalysis provides the most sustainable and economic oxidation processes. Most aerobic oxidation catalysis employs redox metal as its active center. While nature provides non-redox metal strategy as in pyrroloquinoline quinone (PQQ)-dependent methanol dehydrogenases (MDH), such an effective chemical version is unknown. Inspired by the recently discovered rare earth metal-dependent enzyme Ln-MDH, here we show that an open-shell semi-quinone anionic radical species in complexing with lanthanum could serve as a very efficient aerobic oxidation catalyst under ambient conditions. In this catalyst, the lanthanum metal serves only as a Lewis acid promoter and the redox process occurs exclusively on the semiquinone ligand. The catalysis is initiated by 1e<sup>-</sup>-reduction of lanthanum-activated <i>ortho</i>-quinone to a semiquinone-lanthanum complex La(<b>SQ<sup>-.</sup></b>)<sub>2</sub>, which undergoes a coupled O-H/C-H dehydrogenation for aerobic oxidation of alcohols with up to 330 h<sup>-1</sup> TOF. This study suggests a possible functional mode of semiquinone radicals, widely observed with quinoproteins in Nature. Moreover, this unique reductive activation strategy as well as the resulted radical anion as redox ligand creates a new turning point in the development of efficient aerobic oxidation catalysis.</p>

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