Synthesis of biodegradable chiral polyesters by asymmetric enzymatic polymerization and their formulation into microspheres

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Abstract The work presented here focuses on the, incorporation of an engineered polysaccharide polymer, α-1,3-glucan, derived from the enzymatic polymerization of sucrose, as a performance-enhancing additive for commercial, latex-based wood adhesives used in wood bonding applications. Adhesive performance was measured on hard maple (Acer saccharum) using ASTM Standard Method D-905. Dynamic mechanical analysis and solid-state nuclear magnetic resonance spectroscopy were the characterization techniques used to assess the properties of room-temperature–cured adhesive films. Significant increases in shear stress were observed for these formulated latex adhesives containing the polysaccharide polymer.


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