Functionalization of silicon surfaces with catalytically active Pd complexes and application to the aerobic oxidation of benzylic alcohols

2007 ◽  
pp. 4280 ◽  
Author(s):  
Kenji Hara ◽  
Shinobu Tayama ◽  
Hidekazu Kano ◽  
Takuya Masuda ◽  
Satoru Takakusagi ◽  
...  
Keyword(s):  
Aerobic Oxidation ◽  
Silicon Surfaces ◽  
Benzylic Alcohols ◽  
Catalytically Active ◽  
Pd Complexes

ChemInform Abstract: Functionalization of Silicon Surfaces with Catalytically Active Pd Complexes and Application to the Aerobic Oxidation of Benzylic Alcohols.

ChemInform ◽  
2008 ◽  
Vol 39 (9) ◽  
Author(s):  
Kenji Hara ◽  
Shinobu Tayama ◽  
Hidekazu Kano ◽  
Takuya Masuda ◽  
Satoru Takakusagi ◽  
...  
Keyword(s):  
Aerobic Oxidation ◽  
Silicon Surfaces ◽  
Benzylic Alcohols ◽  
Catalytically Active ◽  
Pd Complexes

Selective Aerobic Oxidation of Benzylic Alcohols Catalyzed by Carbon‐Based Catalysts: A Nonmetallic Oxidation System

2010 ◽  
Vol 49 (2) ◽  
pp. 436-440 ◽  
Author(s):  
Yongbo Kuang ◽  
Nazrul M. Islam ◽  
Yuta Nabae ◽  
Teruaki Hayakawa ◽  
Masa‐aki Kakimoto
Keyword(s):  
Aerobic Oxidation ◽  
Benzylic Alcohols ◽  
Selective Aerobic Oxidation ◽  
Oxidation System ◽  
Carbon Based

AIBN/NaBr-promoted aerobic oxidation of benzylic alcohols via a radical process

2016 ◽  
Vol 14 (2) ◽  
pp. 577-581 ◽  
Author(s):  
Chengkou Liu ◽  
Zheng Fang ◽  
Zhao Yang ◽  
Qingwen Li ◽  
Shiyu Guo ◽  
...  
Keyword(s):  
Aerobic Oxidation ◽  
Alcohol Oxidation ◽  
Radical Mechanism ◽  
Radical Process ◽  
Benzylic Alcohols ◽  
First Time ◽  
Oxidation System

A new aerobic alcohol oxidation system of AIBN/NaBr was described for the first time. Moreover, a radical mechanism was assumed and confirmed.

A remarkable effect of ionic liquids in transition-metal-free aerobic oxidation of benzylic alcohols

2011 ◽  
Vol 52 (41) ◽  
pp. 5392-5394 ◽  
Author(s):  
Yoshiro Oda ◽  
Koji Hirano ◽  
Tetsuya Satoh ◽  
Susumu Kuwabata ◽  
Masahiro Miura
Keyword(s):  
Ionic Liquids ◽  
Transition Metal ◽  
Aerobic Oxidation ◽  
Remarkable Effect ◽  
Benzylic Alcohols ◽  
Metal Free

Studies on Iron-Catalyzed Aerobic Oxidation of Benzylic Alcohols to Carboxylic Acids

Synthesis ◽  
2018 ◽  
Vol 50 (08) ◽  
pp. 1629-1639 ◽  
Author(s):  
Shengming Ma ◽  
Xingguo Jiang
Keyword(s):  
Carboxylic Acids ◽  
Large Scale ◽  
Aerobic Oxidation ◽  
Catalytic Amount ◽  
Steric Effects ◽  
Benzylic Alcohols ◽  
Academic Laboratory ◽  
Electron Donating Groups ◽  
Electronic And Steric Effects ◽  
Comprehensive Study

A comprehensive study on aerobic oxidation of benzylic alcohols­ to carboxylic acids with a catalytic amount each of Fe(NO3)3·9H2O, TEMPO, and KCl is conducted. Various synthetically useful functional groups are well tolerated in the reaction. Distinct electronic and steric effects are observed in the reaction: electron-withdrawing groups accelerate the reaction while electron-donating groups make the reaction slower, and ortho-substituted substrates react slower than meta-substituted substrates. Several large-scale reactions (100 mmol) are conducted using a slow air flow of 30 mL/min to demonstrate the practicality of this method in an academic laboratory.

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