Cobalt diphosphonate with a new double chain structure exhibiting field-induced magnetic transition

2007 ◽  
pp. 4681 ◽  
Author(s):  
Zai-Chao Zhang ◽  
Song Gao ◽  
Li-Min Zheng
2021 ◽  
Author(s):  
Junjun Hou ◽  
Shitai Zhu ◽  
Ziwei Zhao ◽  
Jianlei Shen ◽  
Jie Chao ◽  
...  

The DNA nanoswitchs on cell surface could respond to the changes of pH under physiological conditions by switching from a three-chain structure to a double-chain structure, thus connecting another set...


2006 ◽  
Vol 62 (7) ◽  
pp. m1686-m1688 ◽  
Author(s):  
Guang-Bo Che

In the title complex, [Mn2(C8H4O4)2(C19H12N4O)2] n , the MnII atom is six-coordinated by two N atoms from the substituted phenanthroline ligand and four O atoms from three different benzene-1,3-dicarboxylate (1,3-BDC) ligands. Adjacent MnII atoms are bridged by the 1,3-BDC ligands to form a double-chain structure which, in turn, is linked to neighboring double chains via π–π contacts to form a two-dimensional supramolecular structure.


2012 ◽  
Vol 68 (6) ◽  
pp. o1920-o1920
Author(s):  
Chuan Chen ◽  
Hong-Xing Li ◽  
Guang-Feng Hou ◽  
Guang-Ming Li

In the title molecular salt, C14H13N2O2 +·ClO4 −, the ring systems in the cation are almost coplanar [dihedral angle = 5.53 (13)°]. Intramolecular N—H...O and O—H...O hydrogen bonds generate S(6) and S(5) rings, respectively. In the crystal, the two H atoms involved in the intramolecular hydrogen bonds also participate in intermolecular links to acceptor O atoms of the perchlorate anions. A simple intermolecular N—H...O bond also occurs. Together, these form a double-chain structure along [101].


2005 ◽  
Vol 8 (4) ◽  
pp. 335-338 ◽  
Author(s):  
Sujittra Youngme ◽  
Pongthipun Phuengphai ◽  
Chaveng Pakawatchai ◽  
Gerard A. van Albada ◽  
Stefania Tanase ◽  
...  

ChemInform ◽  
2004 ◽  
Vol 35 (45) ◽  
Author(s):  
Ronald Stief ◽  
Werner Massa
Keyword(s):  

2017 ◽  
Vol 72 (6) ◽  
pp. 397-401 ◽  
Author(s):  
Long Tang ◽  
Juan Zhang ◽  
Xiao-Xia Liu ◽  
Ji-Jiang Wang ◽  
Feng Fu

AbstractThe reaction of CoCl2·6H2O with mixed ligands of 2,2′-oxybis(benzoic acid) (2,2′-H2oba) and trans-1,2-bis(4-pyridyl)ethylene (bpe) under hydrothermal conditions produced a new 3D cobalt(II) supramolecular architecture {[Co(oba)(bpe)(H2O)]·1/2bpe}n (1), which was structurally characterized by elemental analysis, infrared spectroscopy, thermogravimetric analyses, and single-crystal X-ray diffraction. The results show that the Co(II) ions are connected to form an infinite polymeric chain by bpe ligands in complex 1. Due to strong intermolecular O–H···O hydrogen bonds, the adjacent chains are connected to generate a double-chain structure. These double chains are joined by O–H···N hydrogen bonding to produce a 2D supramolecular architecture. Furthermore, through intermolecular C–H···O hydrogen bonds, the layers are linked into a 3D supramolecular structure. Magnetic susceptibility measurements have indicated that complex 1 shows weak antiferromagnetic interactions between adjacent Co(II) ions.


2020 ◽  
Vol 75 (6-7) ◽  
pp. 545-552
Author(s):  
Juan Shi ◽  
Zhen-Xiang Xia ◽  
Sheng-Chun Chen ◽  
Ming-Yang He ◽  
Qun Chen

AbstractMicrowave-assisted hydrothermal reaction of 2-fluoro-3,5,6-tri(1H-1,2,4-triazol-1-yl)-1,4-benzenedicarbonitrile (L1) with silver(I) nitrate yields a coordination polymer [Ag3(L2)2(NO3)]n (1), in which the L2 ligand (HL2 = 2-hydroxy-3,5,6-tri(1H-1,2,4-triazol-1-yl)terephthalonitrile) is obtained by in situ ligand transformation from the L1 precursor. HL2 monohydrate has also been isolated by the microwave-mediated hydrolysis of L1 and structurally characterized. Single-crystal X-ray diffraction reveals that HL2 monohydrate comprises a zwitterionic HL2 moiety, while complex 1 displays an infinite L2-bridged double-chain structure. Given that the HL2 molecule has a large conjugated π system, complex 1 exhibits strong blue luminescence in the solid state at room temperature.


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