Electronic communication in “chain-like” trimetallic ruthenium complexes with two C7carbon-rich conjugated bridges

2007 ◽  
pp. 3100-3102 ◽  
Author(s):  
Céline Olivier ◽  
Sylvie Choua ◽  
Philippe Turek ◽  
Daniel Touchard ◽  
Stéphane Rigaut
2004 ◽  
Vol 689 (21) ◽  
pp. 3308-3326 ◽  
Author(s):  
Michael I. Bruce ◽  
Mark A. Buntine ◽  
Karine Costuas ◽  
Benjamin G. Ellis ◽  
Jean-François Halet ◽  
...  

2009 ◽  
Vol 87 (1) ◽  
pp. 134-138 ◽  
Author(s):  
Quan Yuan Hu ◽  
Guochen Jia

Treatment of RuCl(dppm)(η5-C9H7) with alkynes HC≡C(C6H4)nC≡CH (n = 1, 2) in the presence of TlPF6 and t-BuONa affords the bimetallic ruthenium acetylide complexes [(η5-C9H7)(dppm)Ru]2(µ-C≡C(C6H4)nC≡C). Reactions of the hydride complex RuH(dppm)(η5-C9H7) with HC≡C(C6H4)nC≡CH (n = 1, 2) in refluxing toluene give the bimetallic ruthenium alkenyl complexes [(η5-C9H7)(dppm)Ru]2(µ-CH=CH(C6H4)nCH=CH). The electrochemical properties of the new complexes have been investigated by cyclic voltammetry, which reveals that the organic spacer –CH=CHC6H4CH=CH– is more effective than –C≡CC6H4C≡C– in mediating electronic communication between the two ruthenium moieties.Key words: ruthenium, bimetallic, acetylide, insertion, electrochemistry.


In recent decades, the phenomenon of mass electronic communication has been studied by various sciences. The right also turned out to be included in a similar discourse. Communication in the digital environment is the reason for the interaction of previously distant segments of society. In modern law, the concept of electronic communication remains in a certain sense debatable, it is often identified with legal communication. At the same time, electronic communication has an additional «dimension». The globalization of the information space encourages legal scholars to study electronic communication as the action and interaction of various actors, based on Internet technologies using web services, portals, blogs, websites, social networks. There is a need for re- levant legal regulation of the informational interaction between the authorities and society in the Republic of Belarus, in connection with which a new «field» is opening up for activities in various areas of law. The meaning of electronic communication is constantly expanding and, depending on the specialization, even varies. For an adequate understanding of electronic communication, law must take into account the tools of other humanities. In contact with the digital environment, legal science is called upon to reformat research tasks to explain the new empirical and theoretical experience associated with the transformation of the paradigm of interaction between the state and society in the network structures. The author comprehends these issues in relation to the conditions of development of e-government in the Republic of Belarus and the need for more active involvement of the public in the government.


2016 ◽  
pp. 120-125
Author(s):  
Yuliya Aleksandrovna Miheeva ◽  

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