Experimental and theoretical studies of the reaction of the OH radical with alkyl sulfides: 2. Kinetics and mechanism of the OH initiated oxidation of methylethyl and diethyl sulfides; observations of a two channel oxidation mechanism

2007 ◽  
Vol 9 (31) ◽  
pp. 4370 ◽  
Author(s):  
M. B. Williams ◽  
P. Campuzano-Jost ◽  
A. J. Pounds ◽  
A. J. Hynes
Keyword(s):  
Oxidation Mechanism ◽  
Kinetics And Mechanism ◽  
Theoretical Studies ◽  
Oh Radical ◽  
Experimental And Theoretical Studies

Experimental and theoretical studies of the nanostructured {Fe3O4@SiO2@(CH2)3Im}C(CN)3 catalyst for 2-amino-3-cyanopyridine preparation via an anomeric based oxidation

RSC Advances ◽  
2016 ◽  
Vol 6 (55) ◽  
pp. 50100-50111 ◽  
Author(s):  
Mohammad Ali Zolfigol ◽  
Mahya Kiafar ◽  
Meysam Yarie ◽  
Avat(Arman) Taherpour ◽  
Mahdi Saeidi-Rad
Keyword(s):  
Oxidation Mechanism ◽  
Theoretical Studies ◽  
Synthetic Pathway ◽  
Experimental And Theoretical Studies

2-Amino-4,6-diphenylnicotinonitriles were prepared by using Fe3O4@SiO2@(CH2)3Im}C(CN)3 as a catalyst. Experimental and theoretical studies confirmed that the final step of the synthetic pathway is proceeded via an anomeric based oxidation mechanism.

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