Reducing charge recombination losses in solid state dye sensitized solar cells: the use of donor–acceptor sensitizer dyes

2007 ◽  
pp. 1725-1727 ◽  
Author(s):  
Samantha Handa ◽  
Helga Wietasch ◽  
Mukundan Thelakkat ◽  
James R. Durrant ◽  
Saif A. Haque
Keyword(s):  
Solar Cells ◽  
Solid State ◽  
Dye Sensitized Solar Cells ◽  
Charge Recombination ◽  
Dye Sensitized ◽  
Donor Acceptor ◽  
Sensitized Solar Cells

Orthogonally Functionalized Donor/Acceptor Homo- and Heterodimeric Dyes for Dye-Sensitized Solar Cells: An Approach to Introduce Panchromaticity and Control the Charge Recombination

2017 ◽  
Vol 9 (40) ◽  
pp. 34875-34890 ◽  
Author(s):  
Manik Chandra Sil ◽  
Vediappan Sudhakar ◽  
Munavvar Fairoos Mele Kavungathodi ◽  
Vellimalai Punitharasu ◽  
Jayaraj Nithyanandhan
Keyword(s):  
Solar Cells ◽  
Dye Sensitized Solar Cells ◽  
Charge Recombination ◽  
Dye Sensitized ◽  
Donor Acceptor ◽  
And Control ◽  
Sensitized Solar Cells

scholarly journals Efficiency-limiting processes in cyclopentadithiophene-bridged donor-acceptor-type dyes for solid-state dye-sensitized solar cells

2018 ◽  
Vol 148 (4) ◽  
pp. 044703 ◽  
Author(s):  
Felix Hinkel ◽  
Yoojin M. Kim ◽  
Yulian Zagraniarsky ◽  
Florian Schlütter ◽  
Denis Andrienko ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solid State ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized ◽  
Donor Acceptor ◽  
Sensitized Solar Cells

scholarly journals Reduced charge recombination by the formation of an interlayer using a novel dendron coadsorbent in solid-state dye-sensitized solar cells

RSC Advances ◽  
2012 ◽  
Vol 2 (8) ◽  
pp. 3467 ◽  
Author(s):  
Young Soo Kwon ◽  
In Young Song ◽  
Jongchul Lim ◽  
Sung-Hae Park ◽  
Ayyanar Siva ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solid State ◽  
Dye Sensitized Solar Cells ◽  
Charge Recombination ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

Review of recent progress in solid-state dye-sensitized solar cells

2006 ◽  
Vol 90 (5) ◽  
pp. 549-573 ◽  
Author(s):  
Bin Li ◽  
Liduo Wang ◽  
Bonan Kang ◽  
Peng Wang ◽  
Yong Qiu
Keyword(s):  
Solar Cells ◽  
Solid State ◽  
Recent Progress ◽  
Dye Sensitized Solar Cells ◽  
Dye Sensitized ◽  
Sensitized Solar Cells

scholarly journals In Depth Analysis of Photovoltaic Performance of Chlorophyll Derivative-Based “All Solid-State” Dye-Sensitized Solar Cells

Molecules ◽  
2020 ◽  
Vol 25 (1) ◽  
pp. 198 ◽  
Author(s):  
Michèle Chevrier ◽  
Alberto Fattori ◽  
Laurent Lasser ◽  
Clément Kotras ◽  
Clémence Rose ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solid State ◽  
Density Functional ◽  
Photovoltaic Performance ◽  
Dye Sensitized Solar Cells ◽  
Hole Transport ◽  
Tio2 Electrode ◽  
Dye Sensitized ◽  
Depth Analysis ◽  
Sensitized Solar Cells

Chlorophyll a derivatives were integrated in “all solid-state” dye sensitized solar cells (DSSCs) with a mesoporous TiO2 electrode and 2′,2′,7,7′-tetrakis[N,N-di(4-methoxyphenyl)amino]-9,9′-spirobifluorene as the hole-transport material. Despite modest power conversion efficiencies (PCEs) between 0.26% and 0.55% achieved for these chlorin dyes, a systematic investigation was carried out in order to elucidate their main limitations. To provide a comprehensive understanding of the parameters (structure, nature of the anchoring group, adsorption …) and their relationship with the PCEs, density functional theory (DFT) calculations, optical and photovoltaic studies and electron paramagnetic resonance analysis exploiting the 4-carboxy-TEMPO spin probe were combined. The recombination kinetics, the frontier molecular orbitals of these DSSCs and the adsorption efficiency onto the TiO2 surface were found to be the key parameters that govern their photovoltaic response.

Quasi-Solid-State Dye-Sensitized Solar Cells for Efficient and Stable Power Generation under Room Light Conditions

2019 ◽  
Vol 7 (7) ◽  
pp. 7403-7411 ◽  
Author(s):  
Shanmuganathan Venkatesan ◽  
I-Ping Liu ◽  
Chiao-Wei Li ◽  
Chih-Mei Tseng-Shan ◽  
Yuh-Lang Lee
Keyword(s):  
Power Generation ◽  
Solar Cells ◽  
Solid State ◽  
Dye Sensitized Solar Cells ◽  
Light Conditions ◽  
Dye Sensitized ◽  
Room Light ◽  
Sensitized Solar Cells

scholarly journals Pyran-Squaraine as Photosensitizers for Dye-Sensitized Solar Cells: DFT/TDDFT Study of the Electronic Structures and Absorption Properties

2014 ◽  
Vol 2014 ◽  
pp. 1-11 ◽  
Author(s):  
Reda M. El-Shishtawy ◽  
Shaaban A. Elroby ◽  
Abdullah M. Asiri ◽  
Rifaat H. Hilal
Keyword(s):  
Solar Cells ◽  
Dye Sensitized Solar Cells ◽  
Nbo Analysis ◽  
Basis Set ◽  
Absorption Properties ◽  
Charge Delocalization ◽  
Squaraine Dyes ◽  
Dye Sensitized ◽  
Donor Acceptor ◽  
Sensitized Solar Cells

In an effort to provide, assess, and evaluate a theoretical approach which enables designing efficient donor-acceptor dye systems, the electronic structure and optical properties of pyran-squaraine as donor-acceptor dyes used in dye-sensitized solar cells were investigated. Ground state properties have been computed at the B3LYP/6-31+G**level of theory. The long-range corrected density functionals CAM-B3LYP, PBEPBE, PBE1PBE (PBE0), and TPSSH with 6-311++G**were employed to examine absorption properties of the studied dyes. In an extensive comparison between experimental results and ab initio benchmark calculations, the TPSSH functional with 6-311++G**basis set was found to be the most appropriate in describing the electronic properties for the studied pyran and squaraine dyes. Natural transition orbitals (NTO), frontier molecular orbitals (FMO), LUMO, HOMO, and energy gaps, of these dyes, have been analyzed to show their effect on the process of electron injection and dye regeneration. Interaction between HOMO and LUMO of pyran and squaraine dyes was investigated to understand the recombination process and charge-transfer process involving these dyes. Additionally, we performed natural bond orbital (NBO) analysis to investigate the role of charge delocalization and hyperconjugative interactions in the stability of the molecule.

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