scholarly journals Biaryl synthesis with control of axial chirality

2006 ◽  
Vol 4 (17) ◽  
pp. 3197 ◽  
Author(s):  
Timothy W. Wallace
Keyword(s):  
Axial Chirality ◽  
Biaryl Synthesis

scholarly journals Biaryl Synthesis with Control of Axial Chirality

ChemInform ◽  
2007 ◽  
Vol 38 (1) ◽  
Author(s):  
Timothy W. Wallace
Keyword(s):  
Axial Chirality ◽  
Biaryl Synthesis

Sterically Crowded Heterocycles. VII. Reduction of Some (Z)-1,3-Diphenyl-3-(2-phenylimidazo[1,2-a]pyridin-3-yl)prop-2-en-1-ones as Their Axial Chirality Probe

1996 ◽  
Vol 61 (7) ◽  
pp. 1018-1026 ◽  
Author(s):  
Richard Kubík ◽  
Stanislav Böhm ◽  
Josef Kuthan
Keyword(s):  
Hydroxy Derivative ◽  
Borohydride Reduction ◽  
Axial Chirality ◽  
Pm3 Calculations

Borohydride reduction of titled ketones 1a-1g gave diastereoisomeric mixtures of (Z)-1,3-diphenyl-3-(2-phenylimidazo[1,2-a]pyridin-3-yl)prop-2-en-1-ols 2a-2g and 3a-3g in which the former ones prevailed. Only individual racemic products were obtained after borohydride reduction of (E)-1,3-diphenyl-3-(2-phenylimidazo[1,2-a]pyridin-3-yl)-prop-2-en-1-one 4 to corresponding 1-hydroxy derivative 5 and by conversion of (Z)-1-oxo derivative 1a to 1,3-diphenyl-3-(2-phenylimidazo[1,2-a]pyridin-3-yl)propan-1-one (6) with sodium hydrogenselenide. Diastereoselectivity of the borohydride reduction is discussed using the PM3 calculations of the molecules 1a, 2a, 2b, 3a, 3b, 4, 5, and 6.

N‐Heterocyclic Carbene‐Catalyzed Atroposelective Annulation for Access to Thiazine Derivatives with C−N Axial Chirality

2021 ◽  
Vol 60 (17) ◽  
pp. 9362-9367
Author(s):  
Tingting Li ◽  
Chengli Mou ◽  
Puying Qi ◽  
Xiaolin Peng ◽  
Shichun Jiang ◽  
...  
Keyword(s):  
Axial Chirality

scholarly journals Asymmetric Alkenyl Catellani Reaction for the Construction of C–N Axial Chirality

2021 ◽  
Author(s):  
Qianghui Zhou ◽  
Chenggui Wu ◽  
Yong Shang ◽  
Chang Liu ◽  
Ze-Shui Liu ◽  
...  
Keyword(s):  
Axial Chirality

Oxovanadium(V)-Catalyzed Oxidative Biaryl Synthesis from Organoborate under O2.

ChemInform ◽  
2007 ◽  
Vol 38 (16) ◽  
Author(s):  
Hidenori Mizuno ◽  
Hidehiro Sakurai ◽  
Toru Amaya ◽  
Toshikazu Hirao
Keyword(s):  
Biaryl Synthesis

scholarly journals Remote Central-to-Axial Chirality Conversion: Direct Atroposelective Ester to Biaryl Transformation

2018 ◽  
Vol 130 (24) ◽  
pp. 7254-7257 ◽  
Author(s):  
Achim Link ◽  
Christof Sparr
Keyword(s):  
Axial Chirality

Horseradish peroxidase: An effective but unselective biocatalyst for biaryl synthesis

1998 ◽  
Vol 39 (19) ◽  
pp. 2945-2946 ◽  
Author(s):  
Marko M Schmitt ◽  
Ellen Schüler ◽  
Myriam Braun ◽  
Dietmar Häring ◽  
Peter Schreier
Keyword(s):  
Horseradish Peroxidase ◽  
Biaryl Synthesis

Biaryl Synthesis via Electrooxidative Transition Metal Catalyzed C−H Activation

Synthesis ◽  
2021 ◽  
Author(s):  
Jonas Felix Goebel ◽  
Zhongyi Zeng ◽  
Lukas Goossen
Keyword(s):  
Transition Metal ◽  
Recent Advances ◽  
Biaryl Synthesis ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

The use of electricity as an inexpensive and waste-free oxidant opens up new opportunities for the development of sustainable C–H functionalization reactions. Herein we summarize recent advances in the synthesis of biaryls through electrooxidative processes involving transition metal catalyzed ortho-directed C−H activation. A particular focus is set on electrooxidative C−H/C−M couplings and dehydrogenative couplings.

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