Photochromism of a diarylethene charge-transfer complex: photochemical control of intermolecular charge-transfer interaction

2006 ◽  
pp. 2656 ◽  
Author(s):  
Masakazu Morimoto ◽  
Seiya Kobatake ◽  
Masahiro Irie
Keyword(s):  
Charge Transfer ◽  
Charge Transfer Complex ◽  
Charge Transfer Interaction ◽  
Intermolecular Charge Transfer

Raman spectroscopy of intermolecular charge transfer complex between a conjugated polymer and an organic acceptor molecule

2007 ◽  
Vol 127 (10) ◽  
pp. 104905 ◽  
Author(s):  
V. V. Bruevich ◽  
T. Sh. Makhmutov ◽  
S. G. Elizarov ◽  
E. M. Nechvolodova ◽  
D. Yu. Paraschuk
Keyword(s):  
Raman Spectroscopy ◽  
Charge Transfer ◽  
Conjugated Polymer ◽  
Charge Transfer Complex ◽  
Acceptor Molecule ◽  
Intermolecular Charge Transfer ◽  
Organic Acceptor

INTERMOLECULAR CHARGE TRANSFER ENHANCED RESONANCE RAMAN SCATTERING OF CHARGE TRANSFER COMPLEX

2012 ◽  
Vol 11 (02) ◽  
pp. 273-282 ◽  
Author(s):  
YUANZUO LI ◽  
XIUMING ZHAO ◽  
YONGQING LI ◽  
PENG SONG ◽  
YONG DING ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Raman Scattering ◽  
Charge Transfer Complex ◽  
Resonance Raman ◽  
Resonance Raman Scattering ◽  
Intermolecular Charge Transfer ◽  
Scattering Spectrum ◽  
Charge Difference Density ◽  
Target Molecules ◽  
Resonant Raman

Intermolecular charge transfer (ICT) enhanced resonance Raman scattering of charge transfer complex is investigated experimentally and theoretically. The evidence for intermolecular charge transfer on resonance electronic transition is visualized with charge difference density. The resonant Raman spectra reveal that the intensity of Raman peaks are strongly enhanced on the order of 104, by comparing with the normal Raman scattering spectrum. ICT complexes can be used in fluorescence-, photoluminescence-, and electrochemistry-based techniques for sensing target molecules. These strong charge-transfer Raman peaks would enable discrimination of important target molecules from interferants that is normal Raman scattering for the isolated target molecules.

Computational study on intermolecular charge transfer complex of 2,2′-bipyridine with picric acid: TD-DFT, NBO and QTAIM analysis

2019 ◽  
Vol 6 (7) ◽  
pp. 075104 ◽  
Author(s):  
Samia Amirat ◽  
Fatiha Madi ◽  
Mohamed Bououdina ◽  
Abdelhak Gheid ◽  
Amal Zaboub ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Charge Transfer Complex ◽  
Computational Study ◽  
Picric Acid ◽  
Qtaim Analysis ◽  
Intermolecular Charge Transfer ◽  
Td Dft
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