Multifunctional catalysis by Pd-polyoxometalate: one-step conversion of acetone to methyl isobutyl ketone

2006 ◽  
pp. 782 ◽  
Author(s):  
Robert D. Hetterley ◽  
Elena F. Kozhevnikova ◽  
Ivan V. Kozhevnikov
Keyword(s):  
Methyl Isobutyl Ketone ◽  
Methyl Isobutyl ◽  
Isobutyl Ketone ◽  
One Step ◽  
Multifunctional Catalysis

Synthesis, characterization of MCM-22 and catalytic activity in one-step synthesis of methyl isobutyl ketone

2005 ◽  
Vol 84 (1) ◽  
pp. 129-135 ◽  
Author(s):  
Piaoping Yang ◽  
Jianfeng Yu ◽  
Zhenlü Wang ◽  
Meiping Xu ◽  
Qingsheng Liu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Methyl Isobutyl Ketone ◽  
Methyl Isobutyl ◽  
Isobutyl Ketone ◽  
One Step

Progress in One-Pot Synthesis of Methyl Isobutyl Ketone Using Multifunctional Layered Based Catalysts

2013 ◽  
Vol 571 ◽  
pp. 169-196
Author(s):  
Nigamananda Das
Keyword(s):  
Methyl Isobutyl Ketone ◽  
Single Step ◽  
Methyl Isobutyl ◽  
Isobutyl Ketone ◽  
One Pot ◽  
Catalytic Systems ◽  
Step Process ◽  
One Pot Synthesis ◽  
Multifunctional Catalysts ◽  
One Step

Methyl isobutyl ketone (MIBK) is one of the most widely produced and used aliphatic ketones worldwide. The one-step MIBK process with no intermediate separation steps using multifunctional catalysts is an important development towards greener organic synthesis and generates tremendous interest among the researcher across the globe. The single step process is facile and more economically viable and has provided opportunity to develop new and improved catalyst systems capable of operating under mild conditions. A widely variety of catalytic systems have been used in one-step process during last three to four decades. The progress in one-pot synthesis of MIBK using different multifunctional catalysts with special reference to layered based catalysts was critically reviewed in this article.

One-Step Synthesis of Methyl Isobutyl Ketone from Acetone and Hydrogen over Cu-on-MgO Catalysts

1999 ◽  
Vol 184 (1) ◽  
pp. 134-143 ◽  
Author(s):  
Viktor Chikán ◽  
Árpád Molnár ◽  
Katalin Balázsik
Keyword(s):  
Methyl Isobutyl Ketone ◽  
Methyl Isobutyl ◽  
Isobutyl Ketone ◽  
One Step

One-Step Synthesis of Methyl Isobutyl Ketone from Acetone Catalysed by Ni-Zirconia

2011 ◽  
Vol 391-392 ◽  
pp. 908-911 ◽  
Author(s):  
Chang Hai Du ◽  
Zhuo Min Yang ◽  
Guo Bin Zhao ◽  
Li Jie Zhu
Keyword(s):  
Liquid Phase ◽  
Methyl Isobutyl Ketone ◽  
Nickel Content ◽  
Reduction Temperature ◽  
Methyl Isobutyl ◽  
Isobutyl Ketone ◽  
Preparation Conditions ◽  
Zirconia Catalyst ◽  
One Step ◽  
The One

The one-step synthesis of methyl isobutyl ketone from acetone (MIBK) and H2 in liquid phase was studied over Ni-zirconia catalyst prepared by precipitation. The performances of Ni/ZrO2 catalysts were evaluated by the conversion of acetone and the selectivity of MIBK. The effect of different preparation conditions such as aging temperature, calcination temperature, nickel content and reduction temperature was investigated. The results showed that high acetone conversions of up to 33% and MIBK selectivities of up to 85% were recorded at a nickel content of 13.0 wt % and the reduction temperature of 400°C.

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