Microwave activation of the electro-oxidation of glucose in alkaline media

2005 ◽  
Vol 7 (20) ◽  
pp. 3552 ◽  
Author(s):  
Mohamed A. Ghanem ◽  
Richard G. Compton ◽  
Barry A. Coles ◽  
Antonio Canals ◽  
Anne Vuorema ◽  
...  
2013 ◽  
Vol 04 (02) ◽  
pp. 162-169 ◽  
Author(s):  
Marek Wojnicki ◽  
Magdalena Luty-Błocho ◽  
Iwona Dobosz ◽  
Justyna Grzonka ◽  
Krzysztof Pacławski ◽  
...  

Electrochem ◽  
2021 ◽  
Vol 2 (2) ◽  
pp. 347-389
Author(s):  
Wan-Ting Chiu ◽  
Tso-Fu Mark Chang ◽  
Masato Sone ◽  
Hideki Hosoda ◽  
Agnès Tixier-Mita ◽  
...  

A comprehensive review of the electroactive materials for non-enzymatic glucose sensing and sensing devices has been performed in this work. A general introduction for glucose sensing, a facile electrochemical technique for glucose detection, and explanations of fundamental mechanisms for the electro-oxidation of glucose via the electrochemical technique are conducted. The glucose sensing materials are classified into five major systems: (1) mono-metallic materials, (2) bi-metallic materials, (3) metallic-oxide compounds, (4) metallic-hydroxide materials, and (5) metal-metal derivatives. The performances of various systems within this decade have been compared and explained in terms of sensitivity, linear regime, the limit of detection (LOD), and detection potentials. Some promising materials and practicable methodologies for the further developments of glucose sensors have been proposed. Firstly, the atomic deposition of alloys is expected to enhance the selectivity, which is considered to be lacking in non-enzymatic glucose sensing. Secondly, by using the modification of the hydrophilicity of the metallic-oxides, a promoted current response from the electro-oxidation of glucose is expected. Lastly, by taking the advantage of the redistribution phenomenon of the oxide particles, the usage of the noble metals is foreseen to be reduced.


2009 ◽  
Vol 08 (01n02) ◽  
pp. 203-207 ◽  
Author(s):  
J. L. LU ◽  
CHANGWEI XU ◽  
SAN PING JIANG

Nanocrystalline Pd electrocatalyst promoted with transition metal oxide ( Co 3 O 4, NiO , and CoNiO x) is successfully synthesized on high surface carbon support by using intermittent microwave heating (IMH) method. The physical properties of the catalysts are characterized by XRD, TEM, and EDX. The results show that there is no significant microstructure change between Pd and Pd -oxide electrocatalysts and the particle sizes are in the range 5.8–3.9 nm. The linear sweep voltammogram and chronoamperometry results for the electro-oxidation of ethanol show that Pd -oxide/ C electrocatalysts exhibit much better electrochemical activity and stability as compared with pure Pd / C electrocatalyst. The results show that Pd – CoNiO x/ C exhibits the best stability and highest electro-oxidation activity, indicating the promising potential as an alternative electrocatalysts for the direct ethanol fuel cells.


2013 ◽  
Vol 1 (11) ◽  
pp. 3620 ◽  
Author(s):  
Zhonghua Zhang ◽  
Chi Zhang ◽  
Junzhe Sun ◽  
Tianyi Kou ◽  
Qingguo Bai ◽  
...  

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